On Mechanical Properties of Welded Joint in Novel High-Mn Cryogenic Steel in Terms of Microstructural Evolution and Solute Segregation

There is a growing demand for high-manganese wide heavy steel plate with excellent welding performance for liquefied natural gas (LNG) tank building. However, studies on welding of high-Mn austenitic steel have mainly focused on the applications of automotive industry for a long time. In the present work, a high-Mn cryogenic steel was welded by multi-pass Shielded Metal Arc Welding (SMAW), and the microstructural evolution, solute segregation and its effect on the properties of welded joint (WJ) were studied. The yield strength, tensile strength and elongation of the WJ reached 804 MPa, 1027 MPa and 11.2% at −196 °C, respectively. The elongation of WJ was reduced with respect to the BM due to the poorer strain hardening capacity of weld metal (WM) at −196 °C. The WM and coarse-grained heat affected zone (CGHAZ) had the lowest cryogenic impact absorbed energy of ~55 J (at −196 °C). The inhibited twin formation caused by the higher critical resolved shear twinning stress ( τ T ) in the C-Mn-Si segregation band, the inhomogeneous microstructure caused by solute segregation, and the hardened austenite matrix deteriorated the plastic deformation capacity, finally resulting in the decreased cryogenic impact toughness of the CGHAZ. To summarize, the cryogenic toughness and tensile properties of the WJ meet the requirements for LNG tank building.

Causes and Control Mechanism of Abnormal Structure in the Center of SWRH82B Wire-Rod-Steel

The cause of drawing fracture of SWRH82B wire rods was analyzed by using optical microscopy, scanning electron microscope - energy dispersive spectrometer and electron probe micro-analyzer - wavelength dispersive spectrometer. A multivariate diffusion model was established in Thermo-Cale, and the effects of temperature and time on diffusion behavior of alloys were studied. Results show that cementite network and martensite in the center area of rod is main cause of tensile fracture. There is serious segregation of chromium and manganese in the central area. The CCT curve moves to right, and critical cooling rate of martensite decreases. With high cooling rate, time for eutectoid transition is insufficient, and martensite transformation occurs in segregation band. The segregation of phosphorus further worsen the brittleness of steel. With increase of heating temperature and duration of heating time, segregation in final product is reduced, and content of cementite network and martensite decreases. When the temperature is maintained at 1050 °C for 600 s, there is no segregation of phosphorus and carbon. The diffusion of chromium is even when temperature is maintained at 1150 °C for 5400 s, and an even diffusion of manganese is obtained when temperature is maintained at 1200 °C for 3000 s. In stelmor air cooling process, the key point is keeping cooling rate low to extend holding time, and to optimize microstructure and properties.

Study on the Soaking Condition of High Carbon Chromium Bearing Steels

In order to seek the proper soaking condition of a high carbon chromium bearing steel, 100Cr6, a new approach was investigated considering the diffusion of chromium atoms. Although it is true that the large carbides are bigger with the worse degree of center segregation of continuously cast blooms, the size of center segregation band in blooms has a more accurate relationship with the degree of center segregation. Therefore, on behalf of the large carbide size in the conventional method, the size of center segregation band in continuously cast blooms of the steel has been used for the new approach. As a result, the center segregation and large carbides in them were removed completely by the new soaking condition.

Ti (CN) Precipitation in Ultra-High Strength Ti Micro-Alloyed Steels with 700MPa Yield Strength on TSCR Process

Precipitates in ultra-high strength Ti micro-alloyed strips with 700MPa yield strength on TSCR process and in the thermal simulation experimental specimen are observed via Scanning Electronic Microscope (SEM) and Transmission Electron Microscope (TEM), the results show that: the precipitates in the Ti micro-alloyed cast slab thermal simulation experiment can be divided into three categories: 1) micron-sized liquation TiN, 2) 100-200nm sized TiC formed along original austenite grain boundaries or along the dendrite segregation band, 3) solid precipitated 50-100nm sized TiN. Deformation induced spherical TiC (about 10nm-30nm) homogeneously distributed in the matrix after the austenite deformation .After simulated coiling, dispersed TiC (about 5-15nm ) precipitated from ferrite are found in the specimen. TiN with hundreds of nanometers size are commonly found in Ti micro-alloyed strips in industrial production. Ti4C2S2and Ti (CN) are complex precipitated, Ti4C2S2size is less than 30nm; physical and chemical phase analysis shows that the nanosized TiC precipitates are characterized by high volume fraction and small dimensions.

The Skin Effect in an Mg-RE High Pressure Die Cast Alloy

Cross-sectional microhardness maps of cast-to-shape flat tensile specimens have been obtained for a binary Mg-3.44 mass% La alloy. Higher microhardness numbers were generally found near the casting surface, at the corners and along the segregation band. The higher hardness values were ascribed to the finer solidification microstructure near the surface and to localized positive macro segregation. The majority of lower hardness numbers was found at the core region. Lower hardness values were ascribed to the coarser grain size prevalent at the core and to dispersed microporosity. The non uniformity of the harder surface layer in both depth and hardness appeared related to local homogeneities in the grain size distribution caused by the scattered presence of large externally solidified grains.