The effect of carbon nanotubes on the mechanical and damping properties of macro-defect-free cements

The effect of CNTs on the mechanical and damping properties of macro-defect-free (MDF) cements was studied, and polyvinyl alcohol (PVA) fibers were also studied as a contrast. It was found that the compressive strength of MDF cements was not significantly affected by the two types of fibers. The CNTs enhanced the flexural strength of MDF, while PVA fibers made negative contribution. The strengthening mechanism of flexural strength of MDF cements by CNTs can be summarized as fiber bridging, crack deflection and fiber slippage. For the damping properties, the proper contents of CNTs and PVA fibers improved the loss factor significantly. The interface transition zone (ITZ) between the PVA fibers and matrix was large, which was favorable for fiber slippage. The damping property of MDF cements with CNTs was mainly due to the slippage between the inner tubes of the CNTs rather than the slippage between the CNTs and matrix.

MACRO DEFECT FREE CEMENTS: A REVIEW

The usage of polymers in different sectors has been increasing in recent decades, and even our current age may have been defined as polymer age. When concrete is considered polymers are also widely used to modify the properties of both mortar and concrete and the usage of polymers in concrete dates back to 1920’s. On the other hand, Macro-defect free (MDF) cements are one particular type of cement-polymer composites and developed and patented by scientists at Imperial College at the beginnings of 1980’s. MDF cements are produced by mixing cement (commonly calcium aluminate cement) with small amounts of polymer (usually polyvinyl alcohol acetate) and water. High shear, relatively low pressure (about 5 MPa) and moderate temperature (about 80-100 °C) are applied during the production of this material. MDF cements, although consist of more than 80% by weight of cement, show 20-30 times higher flexural strength comparing to ordinary Portland cements. However, MDF cements show a considerable reduction in strength when they are exposed to water even for a short time. Many studies have been conducted to solve the water sensitivity of MDF cements for over 30 years. In this study, production, basic properties and the current state of the art of MDF cements are explained, and the future research works are suggested.

Effect of Epoxy Resin Addition on the Moisture Sensitivity of Macro Defect Free Polymer-Cement Composites

Macro-defect-free (MDF) cements are cement-polymer composites and were developed by Birchall et al. three decades ago. The composites are produced by mixing small amounts of polymer and water with cement. However, they have a different production method than that of cement pastes, which was inspired by rubber production. Mixtures of cement, polymer and water are processed by using a two-roll mill. The composites are known with their high flexural strengths. Unfortunately, there are not any known commercial products using MDF cements because of their poor durability under moisture. In this study, MDF cements were prepared by using poly(vinyl alcohol--vinyl acetate) PVA, calcium aluminate cements and two different types of epoxy resins. Epoxy resins were a diglycidyl ether of bisphenol A and a mixture of a diglycidyl ethers of bisphenol A and F. Durability performance was compared with respect to biaxial flexural strengths, contact angle and atomic force microscopy (AFM) for the specimens stored in water.