Recent Advances on Visible Light Metal-Based Photocatalysts for Polymerization under Low Light Intensity

In recent years, polymerization processes activated by light have attracted a great deal of interest due to the wide range of applications in which this polymerization technique is involved. Parallel to the traditional industrial applications ranging from inks, adhesives, and coatings, the development of high-tech applications such as nanotechnology and 3D-printing have given a revival of interest to this polymerization technique known for decades. To initiate a photochemical polymerization, the key element is the molecule capable to interact with light, i.e., the photoinitiator and more generally the photoinitiating system, as a combination of several components is often required to create the reactive species responsible for the polymerization process. With the aim of reducing the photoinitiator content while optimizing the polymerization yield and/or the polymerization speed, photocatalytic systems have been developed, enabling the photosensitizer to be regenerated during the polymerization process. In this review, an overview of the photocatalytic systems developed for polymerizations carried out under a low light intensity and visible light is provided. Over the years, a wide range of organometallic photocatalysts has been proposed, addressing both the polymerization efficiency and/or the toxicity, as well as environmental issues.

Sulfonium salt based charge transfer complexes as dual thermal and photochemical polymerization initiators for composites and 3D printing

Charge transfer complexes (CTCs) exhibit excellent initiating abilities as safe photo, thermal, or photo/thermal dual initiators, which cannot be achieved by classical initiators.

Indole-based charge transfer complexes as versatile dual thermal and photochemical polymerization initiators for 3D printing and composites

Indole-based Charge Transfer Complexes (CTCs) are newly presented dual photo/thermal initiators for safe and robust polymerizations in high tech applications.

Solid or gel? Which one works better for [2 + 2] photochemical polymerization in pyridine appended flexible phenylene 1, 4-bis-olefins by Ag(i) templation?

Two diene molecules were shown to undergo photopolymerization reactions in their metal–organic gels and xerogels, while their respective crystalline CPs are photostable.