Melting of subducted slab dictates trace element recycling in global arcs

Temperature-dependent trace element fractionation during melting of subducted slab can explain the composition of arc magmas.

Diversification of Archean tonalite-trondhjemite-granodiorite suites in a mushy middle crust

Tonalite-trondhjemite-granodiorite (TTG) suites are the dominant component of Earth’s first continents, but their origins are debated. The trace element concentrations of these rocks are conventionally linked to their source depths and inferred geodynamic settings with the implicit assumption that TTG compositions are source-controlled. Alternatively, their variable compositions may be caused by fractional crystallization in TTG plutons after emplacement and less clearly linked to source depth. Most TTGs in Archean mid-crustal exposures are the dominant component of igneous gray gneiss complexes; the processes that influence the evolution of TTG magmas in this setting are poorly understood. We present a petrological–geochemical model that explains the coexistence of TTGs in the middle crust with low-pressure and high-pressure geochemical trends, irrespective of tectonic setting or depth of the TTG source. We propose that mid-crustal TTGs were long-lived crystal mushes with compositions controlled by the separation of early-crystallizing plagioclase and melt. Using phase equilibrium modeling, we demonstrate that a suite of TTGs from the southern Superior Province in Canada represents variably plagioclase-rich and melt-rich fractions from a common parent magma. The behavior of plagioclase may have a strong influence on the geochemical trends of TTGs, including the degree of rare earth element fractionation. Our results suggest that trace element compositions of TTGs may not primarily reflect the depth of the source and cannot be used alone to infer Archean geodynamic settings.

Recognising Mineral Deposits from Cover; A Case Study Using Zircon Chemistry in the Gawler Craton, South Australia

Detrital zircon grains preserved within clasts and the matrix of a basal diamictite sequence directly overlying the Carrapateena IOCG deposit in the Gawler Craton, South Australia are shown here to preserve U–Pb ages and geochemical signatures that can be related to underlying mineralisation. The zircon geochemical signature is characterised by elevated heavy rare-earth element fractionation values (GdN/YbN ≥ 0.15) and high Eu ratios (Eu/Eu* ≥ 0.6). This geochemical signature has previously been recognised within zircon derived from within the Carrapateena orebody and can be used to distinguish zircon associated with IOCG mineralisation from background zircon preserved within stratigraphically equivalent regionally unaltered and altered samples. The results demonstrate that zircon chemistry is preserved through processes of weathering, erosion, transport, and incorporation into cover sequence materials and, therefore, may be dispersed within the cover sequence, effectively increasing the geochemical footprint of the IOCG mineralisation. The zircon geochemical criteria have potential to be applied to whole-rock geochemical data for the cover sequence diamictite in the Carrapateena area; however, this requires understanding of the presence of minerals that may influence the HREE fractionation (GdN/YbN) and/or Eu/Eu* results (e.g., xenotime, feldspar).

Fractionation and Distribution of Rare Earth Elements in Marine Sediment and Bioavailability in Avicennia marina in Central Red Sea Mangrove Ecosystems

Rare earth element fractionation and distribution in the coastal ecosystem have been of significant concern and are recognized worldwide as emerging micro-pollutants. However, unlike other metals such as trace elements, little is known about their uptake by aquatic plants such as the mangrove Avicennia marina, especially in the central Red Sea. We investigated the fractionation of rare earth elements in six mangrove ecosystems in the central Red Sea and bioavailability in mangrove A. marina. The concentrations of rare earth elements, sediment grain sizes, multi-elemental ratios, geo-accumulation index (Igeo) and bioconcentration factor (BCF) vary significantly (p < 0.05) across the six mangrove ecosystems. Higher concentrations of rare earth elements were recorded at Al Lith (LT) (101.53 mg/kg) and South Jeddah (SJ) (73.38 mg/kg) mangrove ecosystems. However, multi-elemental ratio R(M/L) reveals positive values. In contrast, multi-elemental ratio R(H/M) reveals negative values corresponding to fractionation patterns enriched with medium rare earth elements and heavy rare earth elements depletion across the six mangrove ecosystems. BCF values for rare earth elements were <1, but Lutetium (0.32) had the highest BCF among the rare earth elements, suggesting an efficient accumulation of Lutetium than any other rare earth elements. The scale of Igeo revealed strong contamination (4 ≤ Igeo ≥ 5) of sediment with Lanthanum, Cerium, Praseodynium, Samarium, Godolinium, Holmium, Erbium, Ytterbium, and moderate contamination with Thulium, Terbium, and Dysprosium (1 ≤ Igeo ≤ 3). Principal component analysis showed that clay silt sediment grain size influences rare earth element concentrations in the central Red Sea. Our results provide new evidence for rare earth element fractionation and accumulation in sediment and the potential use of mangrove A. marina for rare earth element monitoring in mangrove ecosystems in the central Red Sea.