Influences of Organic Volatile Compounds on the Secondary Organic Carbon of Fine Particulate Matter in the Fruit Tree Area

Three combined investigations were conducted to examine the sources of PM2.5 in agricultural areas. The first was the measurement of PM2.5 and gaseous compounds in the greenhouse, which is a relatively closed system, while the second was the analysis of pesticide components used in agricultural areas. Finally, the physical and chemical properties of PM2.5 were analyzed in an orchard area and compared with the results of the greenhouse and agricultural chemical analyses. As a result, this research was able to confirm the source of emission and characteristics of PM2.5 originating from the agricultural area. Volatile organic compounds (VOCs) in agricultural areas are emitted by agricultural chemicals, and the discharged agricultural chemicals are first absorbed into the soil, and then released into the air by evaporation. Finally, the secondary products of PM2.5 in agricultural areas were estimated to have positive relationships with the VOCs from agricultural chemicals, and NH3 from fertilizers. The photochemical reactions of VOCs and NH3 were responsible for the impact on secondary products.

Decreasing concentrations of carbonaceous aerosols in China from 2003 to 2013

Carbonaceous aerosols were characterized in 19 Chinese cities during winter and summer of 2013. Measurements of organic carbon (OC) and elemental carbon (EC) levels were compared with those from 14 corresponding cities sampled in 2003 to evaluate effects of emission changes over a decade. Average winter and summer OC and EC decreased by 32% and 17%, respectively, from 2003 to 2013, corresponding to nationwide emission control policies implemented since 2006. The extent of carbon reduction varied by season and by location. Larger reductions were found for secondary organic carbon (SOC, 49%) than primary organic carbon (POC, 25%). PM2.5 mass and total carbon concentrations were three to four times higher during winter than summer especially in the northern cities that use coal combustion for heating.

Carbonaceous Aerosols in Contrasting Atmospheric Environments in Greek Cities: Evaluation of the EC-tracer Methods for Secondary Organic Carbon Estimation

This study examines the carbonaceous-aerosol characteristics at three contrasting urban environments in Greece (Ioannina, Athens, and Heraklion), on the basis of 12 h sampling during winter (January to February 2013), aiming to explore the inter-site differences in atmospheric composition and carbonaceous-aerosol characteristics and sources. The winter-average organic carbon (OC) and elemental carbon (EC) concentrations in Ioannina were found to be 28.50 and 4.33 µg m−3, respectively, much higher than those in Heraklion (3.86 µg m−3 for OC and 2.29 µg m−3 for EC) and Athens (7.63 µg m−3 for OC and 2.44 µg m−3 for EC). The winter OC/EC ratio in Ioannina (6.53) was found to be almost three times that in Heraklion (2.03), indicating a larger impact of wood combustion, especially during the night, whereas in Heraklion, emissions from biomass burning were found to be less intense. Estimations of primary and secondary organic carbon (POC and SOC) using the EC-tracer method, and specifically its minimum R-squared (MRS) variant, revealed large differences between the sites, with a prevalence of POC (67–80%) in Ioannina and Athens and with a larger SOC fraction (53%) in Heraklion. SOC estimates were also obtained using the 5% and 25% percentiles of the OC/EC data to determine the (OC/EC)pri, leading to results contrasting to the MRS approach in Ioannina (70–74% for SOC). Although the MRS method provides generally more robust results, it may significantly underestimate SOC levels in environments highly burdened by biomass burning, as the fast-oxidized semi-volatile OC associated with combustion sources is classified in POC. Further analysis in Athens revealed that the difference in SOC estimates between the 5% percentile and MRS methods coincided with the semi-volatile oxygenated organic aerosol as quantified by aerosol mass spectrometry. Finally, the OC/Kbb+ ratio was used as tracer for decomposition of the POC into fossil-fuel and biomass-burning components, indicating the prevalence of biomass-burning POC, especially in Ioannina (77%).