Elastohydrodynamic Lubrication

The development of EHL theory from its tentative beginnings is outlined, with an account of how Ertel explained its relation to Hertz contact theory. The problems caused by the failure of the early numerical analysts to understand that the film thickness depends on only two variables are emphasised, and answers of the form H = F ( P , S ) given. Early methods of measuring the film thickness are described, but these became archaic with the development of optical EHL. The behaviour of surface roughness as it passes through the high pressure region and suffers elastic deformation is described, and the implication for the traditional Λ -ratio noted. In contrast, the understanding of traction is far from satisfactory. The oil in the high pressure region must become non-Newtonian: the early explanation that the viscosity reduction is the effect of temperature proved inadequate. There must be some form of shear thinning (perhaps according to the Eyring theory), but also a limiting shear stress under which the lubricant shears as an elastic solid. It seems that detailed, and difficult, measurements of the high pressure, high shear-rate behaviour of individual oils are needed before traction curves can be predicted.

The physicochemical and thermodynamic properties of the choline chloride-based deep eutectic solvents

This paper reports the physicochemical (density, dynamic viscosity, electrical conductivity and refractive index) and the thermodynamic (thermal expansion coefficient, molecular volume, lattice energy and heat capacity) properties of several choline chloride (ChCl) based deep eutectic solvents (DESs), with 1:2 mole ratio, respectively: ChCl:propylene glycol, ChCl:1,3-dimethylurea and ChCl:thiourea, at atmospheric pressure as a function of temperature over the range of 293.15?363.15 K. Their properties were also compared with those of some already characterized ChCl-based DESs, namely ChCl:ethylene glycol, ChCl:glycerol and ChCl:urea (1:2 mole ratio). Density, viscosity and refractive index of all DESs decrease with the increasing temperature while the electrical conductivity increases. Viscosity and conductivity of the tested DESs were fitted by both Arrhenius-type and Vogel?Tamman?Fulcher equations. The changes of molar enthalpy, entropy and Gibbs energy of activation, determined using the Eyring theory, demonstrated the interactional factor as predominant over the structural factor for all DES systems. The fractional Walden rule, used to correlate molar conductivity and viscosity, showed an excellent linear behaviour. It was shown that ChCl:propylene glycol DES had properties similar to ChCl:ethylene glycol and ChCl:glycerol DESs. However, the properties (density, viscosity and electrical conductivity) of ChCl:1,3-dimethylurea and ChCl: :thiourea DESs were inferior to those of the ChCl:urea DES.

Thermal and mechanical characterization of polymer composites filled with dispersed zeolite and oil shale

The thermal, viscoelastic, mechanical behavior of polymers filled with dispersed zeolite and oil shale is studied as a function of temperature, grain size, and filler concentration. It was found that the thermal conductivity of epoxy—zeolite composite increases with different zeolite grain sizes and takes a higher value in case of the 63 μm grain size composite. The observed enhancement in the thermal conductivity of zeolite composites correlates well with that of the electrical conductivity. The thermodynamic results exhibit a slight increase in the glass transition temperature of the polystyrene/oil shale composites, and shift in the observed relaxation peaks with increasing the oil shale content. The plastic deformation of PS/oil shale composites shows that the elastic modulus increases and the compressive yield stress decreases with oil shale content. The Eyring theory of yielding could predict the dependence of the yield stress on the applied strain rate. The predicted activation volume and activation energy showed dependence on the oil shale grains sizes and content.

Influence of Strain Rate on the Yielding Behavior and on the Self Heating of Thermoplastic Polymers Loaded under Tension

The effect of strain rate on the mechanical behavior of thermoplastic polymers (Polymethyl methacrylate, Polycarbonate and Polyamide 66) has been studied. Deformation tests in tension were conducted over the range of strain rate varying between 2.6 10-4s-1 to 1.3 10-1s-1. The Young’s Modulus E and Yield stress σST evolutions have been identified and modelled as a function of the strain rate. It has been established that, in the range of the considered strain rates, the yielding behavior of PMMA and PC is well described by the Eyring theory while for PA66 the Ree-Eyring theory is successfully used to illustrate the yielding behavior. During tensile tests the specimen surface temperatures were monitored using an infrared camera. Results reveal a significant temperature rise at large deformations for PA66 and PC. As the strain rate increases the temperature is steadily increased with deformation due to plastic work. Hence, for PC and PA66, a significant thermal softening is observed after yielding which affects the stress-strain behavior. Thermo-mechanical coupling during polymer deformation can be considered in the modeling of the mechanical behavior of polymers. No self-heating has been detected for PMMA.

A Reynolds-Eyring Equation for Elastohydrodynamic Lubrication in Line Contacts

A new Reynolds equation, based on the Eyring theory of non-Newtonian flow, is derived for flow in one dimension. It is shown that this new equation reduces to the traditional Reynolds equation as the Eyring model approaches the Newtonian model in the limit. Numerical solutions are presented for a selected oil at two different temperatures. The central film thickness decreases with increasing dimensionless viscosity parameter and slide/roll ratios. A transition zone is noted through which the ratio of minimum to central film thickness passes as the pressure distribution goes from near Hertzian to a distribution that appreciably deviates from Hertzian.