Formation Mechanism of Preferential Flow Paths and Seepage Characteristics of a Novel Growable Pile for Heap Leaching of Rare Earth

In the traditional heap leaching of rare earth minerals, the top of the rare earth pile is covered with leaching liquid. This creates trouble for vegetation restoration carried out timely on the top of the pile. In order to solve this trouble, a novel pile structure into which leaching liquid is laterally injected is proposed for heap leaching of rare earth. In this study, a laboratory test is carried out to study the formation and distribution of preferential flow paths for the rare earth pile under a horizontal liquid injection condition. Furthermore, numerical simulations based on a dual-permeability model are conducted to investigate the influence of the preferential flow paths on the seepage characteristics in the rare earth pile. The results show that, under the horizontal liquid injection condition, the fine particles of the rare earth move away from the liquid injection end and also toward the lower part of the pile. The migration of the fine particles results in the formation and connection of macropore, thereby generating preferential flow paths in the rare earth pile. The preferential flow paths are mainly distributed in the lower part of the pile near the liquid injection end. This causes the fluid in the lower part of the pile to seep faster significantly than that in the upper part. Within the region where the preferential flow paths develop, the seepage in the early stage of the horizontal liquid injection is dominated by preferential flow. The preferential flow is more significant at the locations farther away from the liquid injection end.

Feedback mechanisms between precipitation and dissolution reactions across randomly heterogeneous conductivity fields

Our study investigates interplays between dissolution, precipitation, and transport processes taking place across randomly heterogeneous conductivity domains and the ensuing spatial distribution of preferential pathways. We do so by relying on a collection of computational analyses of reactive transport performed in two-dimensional systems where the (natural) logarithm of conductivity is characterized by various degrees of spatial heterogeneity. Our results document that precipitation and dissolution jointly take place in the system, with the latter mainly occurring along preferential flow paths associated with the conductivity field and the former being observed at locations close to and clearly separated from these. High conductivity values associated with the preferential flow paths tend to further increase in time, giving rise to a self-sustained feedback between transport and reaction processes. The clear separation between regions where dissolution or precipitation takes place is imprinted onto the sample distributions of conductivity which tend to become visibly left skewed with time (with the appearance of a bimodal behavior at some times). The link between conductivity changes and reaction-driven processes promotes the emergence of non-Fickian effective transport features. The latter can be captured through a continuous-time random-walk model where solute travel times are approximated with a truncated power law probability distribution. The parameters of such a model shift towards values associated with increasingly high non-Fickian effective transport behavior as time progresses.

The impact of soil development, rainfall intensity and vegetation complexity on subsurface flow paths along a glacial chronosequence of 10 millennia

Hydrologic processes play an important role in the hydro-pedo-geomorphological feedback cycle of landscape evolution. Soil properties and subsurface flow paths change over time, but due to lack of observations important hydrologic processes such as water flow paths are often not properly considered in soil and landscape evolution studies. We investigated the evolution of subsurface flow paths during landscape development in the calcareous glacier forefield at the Griessfirn in the Swiss Alps. While the main focus was on flow path evolution and the formation of preferential flow paths with soil development, we also looked at the impact of irrigation intensity and vegetation complexity (in what way does the vegetation complexity defined by degree of vegetation cover and functional diversity at each age class relate to subsurface structures and flow path initialization?). We chose four glacial moraines of different ages (110, 160, 4 900, and 13 500 years) and conducted dye tracer experiments with Brilliant Blue (4 g l−1) on three plots at each moraine. The three plots at each age class differed by their degree of vegetation complexity (low, medium, and high) and each was further divided into three equal subplots where dyed water was applied with three different irrigation intensities (20, 40, and 60 mm h−1) and an irrigation amount of 40 mm. Dye pattern characteristics in form of volume density and surface area density were derived by digital image analysis and compared via statistical analysis.Volume density was used to classify the observed dye patterns into specific flow type categories. The effect of soil formation and thus changing soil characteristics on flow types were investigated by the analysis of structural and textural parameters in form of grain size distribution, porosity, bulk density, and loss on ignition. A change in flow types with increasing moraine age was observed from a rather homogeneous matrix flow to heterogeneous matrix and finger flow. Along the soil chronosequence, a reduction in particle sizes and an ongoing vegetation development resulted in an accumulation of organic matter in the topsoil and an increase in water storage capacity (decrease in bulk density and increase in porosity). Differences in irrigation intensity only had an effect on flow types at the oldest moraine, where the frequency of finger flow decreased with increasing irrigation intensity. A relation between vegetation complexity and flow types was only observed at the older moraines, which had a dense vegetation cover. With increasing vegetation complexity the proportion of preferential flow paths in form of finger flow also increased.

Prediction of salt release from coal mine spoils at meso-scale

<p>Open-cut coal mining operations remove enormous quantities of overburden material inorder to access coal seam. Upon interaction with atmospheric conditions, this overburden material referred to as spoils from which salts are leached, possesses the risk of affecting surface and groundwater quality around the mine sites. Due to a distinct lack of field data on leachate rates and chemistry for full-scale spoil piles, studies have relied on geochemical testing at laboratory-scale experiments such as free-draining funnels and columns. While laboratory leaching techniques under a controlled environment are a general predictor of how spoil behaves upon weathering, there remain gaps in understanding the leachate rates taking into consideration actual particle size, flow rates, water content, temperature, and oxygen supply. This study proposes and assesses a new mesoscale approach for predicting salinity release from spoils that is designed to obtain data more relevant to the closure options under consideration. 5 coal mine spoils from 3 mines located in Queensland, Australia was sampled, characterised (physical, geochemical, and mineralogical), and were subjected to weathering at mesoscale (1-2 tonnes sample volume) leaching for 11 cycles under natural conditions. Results showed that soil-like spoils with significant pockets of less permeable clayey or silty material have the ability to retain and release solute slowly with time while rock-like spoils followed a steady decay rate. The mesoscale tests produced distinctive characteristic decay curves of salt release from typical soil-like and rock-like spoils and have been useful in the calibration of flow and moisture-dependent salt kinetic parameters. The mesocosm leaching approach developed as a part of this study was close to real-sized spoil conditions such that it mimicked the water/rock ratios, preferential flow paths, and governing solute transport processes.</p>

Conceptualising the effect of preferential flow on slow-moving landslides: from experiments to concepts and models.

<p>Precipitation is one of the main causes for the initiation or reactivation of deep seated slow moving landslides. Preferential flow paths can have multiple origins, they can be due to changes in soil water content such as desiccation, due to mechanical movement or due to biological activity. The overarching characteristic is that they strongly alter the hydraulic properties of the landslide material. This results in a complex hydrological behaviour of deep-seated slow moving landslides. Research has shown that for instance the porosity of the soil, the fissure distribution and fissure connectivity are very important to predict the behaviour of the hydrological response of precipitation within a landslide body. However, due to large heterogeneity of landslide lithology and spatial and temporal variation of a landslide, it is hard to model water levels in landslides. Cracks and fissures inside the landslide are the cause of preferential flow paths, which can work as infiltration networks to the groundwater, but also as drainage networks lowering the (perched) groundwater levels.</p><p>In the last decades, both methodological progress has been made and several case studies have been published. However, most are still somewhat anecdotic examples and a more overarching conceptualisation has not been made yet. In this overview I want to highlight the progress as well as obstacles and challenges ahead of us when assessing and quantifying the impact of preferential flow paths on the mechanisms of a slow moving deep-seated landslide and to improve our understanding and modelling of complex landslides.</p>

Regional Hydrogeochemical Evolution of Groundwater in the Ring of Cenotes, Yucatán (Mexico): An Inverse Modelling Approach

The Ring of Cenotes (RC) extends along the edge of the Chicxulub crater, in the limestone platform of the Yucatan Peninsula (YP), where groundwater shows two preferential flow paths toward the coast near Celestun and Dzilam Bravo towns. The objectives of this study were to describe the regional hydrogeochemical evolution of the groundwater in the RC, and its association with the dissolution/precipitation of the minerals present along its pathway to the ocean. These objectives results were obtained by: (a) characterizing groundwater hydrogeochemistry; (b) calculating calcite, dolomite, and gypsum saturation indexes in the study area; and (c) developing a hydrogeochemical model using PHREEQC (U. S. Geological Survey) inverse modelling approach. The model predictions confirmed that there are two evolution pathways of the groundwater consistent with the preferential flow paths suggested in a previous regionalization of the RC. On the western path, where groundwater flows towards Celestun, marine intrusion influences the hydrogeochemical processes and represents a risk for the freshwater. On the eastern path, where groundwater flows toward Dzilam Bravo, rainfall has an important effect on the hydrogeochemical processes, evidenced by a higher concentration in sulfates during droughts than during rainy periods. Then, monitoring of marine intrusion and phases dissolution in the RC is highly recommended.

Characterizing Preferential Flow Paths in Texturally Similar Soils under Different Land Uses by Combining Drainage and Dye-Staining Methods

Preferential flow paths have been widely characterized by many visualization methods. However, the differences in preferential flow paths under various land uses and their relationships to hydraulic properties remain uncertain. The objectives of this study are to (1) characterize preferential flow paths under various land uses (forest and orchard) by combining drainage and dye-staining methods and to (2) build a connection between preferential flow paths and hydraulic-related parameters and extract the proportion of preferential flow paths from the compounding effects of matrix flow and preferential flow. The dye-staining experiments were conducted in five sandy soils and one sandy clay loam in situ, including four soils from forest and two soils from orchards. A total of 47 soil cores, 4 cm in height and 9 cm in diameter, were collected in each layer of the dye-stained soils for drainage experiments in the laboratory. Dye coverage and hydraulically equivalent macropore parameters (macroporosity, pore size distribution, and number of macropores) and their relationships were analyzed. The results show that the volume of preferential flow is partly affected by the total macropore volume. The effect of macropores on preferential flow varies by macropore size distribution. Dye coverage exhibited a significant (P < 0.01) correlation with macroporosity (correlation coefficient 0.83). Based on the value of macroporosity or steady effluent rates, the part of the dye coverage that was due to preferential flow on the surface dye-stained soil (resulting from both matrix and preferential flow) could be identified in this study. Compared with orchards, forestland has more preferential flow paths in both surface soil and subsoil. Further studies are needed to quantify the 3-D preferential flow paths and build a connection between preferential flow paths and hydraulic properties.

Groundwater Quality Evolution Model in the Ring of Cenotes, Yucatan, Mexico

Karst aquifers show dissolution/precipitation processes of the minerals present in the carbonate rocks. The Ring of Cenotes (RC) extends along the edge of the Chicxulub crater, in the limestone platform of the Yucatan Peninsula (YP), where groundwater shows preferential flow paths toward the coast near Celestun and Dzilam Bravo towns. This study aimed to describe the regional hydrogeochemical evolution of groundwater of the RC, and its association with the dissolution/precipitation of the minerals present along its path to the ocean. To achieve this aim, we: a) characterized groundwater's hydrogeochemistry; b) determined the calcite, dolomite, and gypsum saturation indexes (reaction phases with the groundwater) in the study area; c) proposed a hydrogeochemical model developed through PHREEQC using an inverse modelling approach. The model predictions confirmed that there are two evolution pathways of the groundwater consistent with the preferential flow paths suggested in a previous regionalization of the RC. On the western path, where groundwater flows towards Celestun, an important marine intrusion influences the hydrogeochemical processes and represents a risk for the prevalence of freshwater. On the eastern path, where groundwater flows toward Dzilam Bravo, the hydrogeochemistry in the sinkholes correlates well with rainfall, suggesting a higher vulnerability during droughts than during rainy periods.