Analysis of the Physicochemical Characteristics of Distillery Wastewater at Habib Sugar Mills, Nawabshah

The aim of this study is to perceive the level of significant physicochemical characteristics of Distillery Wastewater (DWW) at Habib Sugar Mills, Nawabshah, Pakistan. Five locations in the mill namely spent wash, digester tank, distillery, primary treatment, and secondary treatment were selected for analysis of pH, Total Dissolved Solids (TDS), Total Suspended Solids (TSS), and Chemical Oxygen Demand (COD) of the samples. The samples were taken on a weekly basis for four succeeding months, from January 2021 to April 2021 and the experiments were carried out in the laboratory by adopting standard procedures. The results revealed that the pH of the samples from spent wash was the lowest, whereas secondary treatment samples had the highest. On the contrary, the highest concentrations of TDS, TSS, and COD were found in the samples taken from the spent wash and the lowest from the secondary treatment. The pH values were found abruptly increasing in the digester tank due to the addition of calcium carbonate in the stream of wastewater after the spent wash. The COD concentration was found to rapidly decrease, from more than 106000mg/l in the spent wash to around 35000mg/l in the digester tank samples, and then to gradually decrease up to the final point of disposal. Overall, TDS, TSS, and COD values were higher during April, January, and February and lower during March. The level of pH was extremely low in the spent wash and did not meet the lower limits of standards and the other examined parameters exceeded the upper limits of WHO standards.

Anaerobic Co-digestion of Press mud and Molasses-based Distillery Wastewater for Enhanced Biogas Production

With goals in determining the effect of diluting the distillery wastewater (DWW) and of varying the amount of DWW and press mud (PM), anaerobic co-digestion study was carried out at mesophilic condition in a 2-L Erlenmeyer flask, with a working volume of 800 mL for Batch 1 and 1500 mL for Batch 2 experiments. For Batch 1, two different ratios of DWW and tap water, with 2:3 and 3:2, were used to assess the effect of dilution on the methane yield, where same volumetric amount of PM was added. For Batch 2, following ratio of PM and DWW were used: a) 1:0, b) 1:1, c) 1:1, d) 2:1, and e) 1:2. All samples had the same amount of inoculum, except that Batch 1 samples had bagasse. The parameters that were assessed after 42 days of digestion were: pH, COD, BOD, TSS, VS, Cu, Ca, Mg, Mn, TOC, TN, and methane yield. For the effect of dilution, a significant difference in the methane yield between samples with higher and lower dilution ratio was seen, and in the first batch, the optimal dilution ratio of DWW and H2O, with 3:2 gave higher methane yield of 78.23% (v/v). Meanwhile, optimal volumetric ratio of DWW and PM from the Batch 2 experiments, with value of 1:2, gave the highest methane yield of 79.43% (v/v).

Cultivation of Chlorella vulgaris in Membrane-Treated Industrial Distillery Wastewater: Growth and Wastewater Treatment

The alcohol industry discharges large quantities of wastewater, which is hazardous and has a considerable pollution potential. Cultivating microalgae in wastewater is an alternative way of overcoming the current high cost of microalgae cultivation and an environmentally friendly treatment method for industrial effluents. The study analyzed the growth and biochemical composition of Chlorella vulgaris cultivated in membrane-treated distillery wastewater (MTDW) and nutrients removal efficiency. The results showed biomass productivity of 0.04 g L−1 d−1 for MTDW with the contents of content of protein, carbohydrate, and lipid at 49.6 ± 1.4%, 26.1 ± 0.6%, and 10.4 ± 1.8%, respectively. The removal efficiencies of TN, TP, and COD were 80, 94, and 72.24% in MTDW, respectively. In addition, removal efficiencies of 100, 85.37, and 42.86% for Ca2+, Mg2+, and Mo2− were achieved, respectively. The study added to our growing knowledge on the cultivation of Chlorella with wastewater, suggesting that it was feasible to cultivate Chlorella with MTDW and represented an economical and environmentally friendly strategy for microalgae biomass production and reuse of wastewater resources.

Potato Starch Extrusion and Roasting with Apple Distillery Wastewater as a New Method for Resistant Starch Production

Potato starch was extruded and roasted with apple distillery wastewater to produce starch esters substituted with malic acid residues. The starch esterification degree was higher at the higher roasting temperatures. Starch modification contributed to its darker color, its increased resistance to the action of amylolytic enzymes, and its decreased solubility and heat of phase transition. The changes in the other starch properties examined depended on the extrusion and roasting temperatures. The process, which was conducted without a chemical agent—in this case, the process of starch extrusion and roasting with apple distillery wastewater—should be deemed a novel method for resistant starch production.