Technical note: High-accuracy weighing micro-lysimeter system for long-term measurements of non-rainfall water inputs to grasslands

Non-rainfall water (NRW), defined here as dew, hoar frost, fog, rime, and water vapour adsorption, might be a relevant water source for ecosystems, especially during summer drought periods. These water inputs are often not considered in ecohydrological studies, because water amounts of NRW events are rather small and therefore difficult to measure. Here we present a novel micro-lysimeter (ML) system and its application which allows us to quantify very small water inputs from NRW during rain-free periods with an unprecedented high accuracy of ±0.25 g, which corresponds to ±0.005 mm water input. This is possible with an improved ML design paired with individual ML calibrations in combination with high-frequency measurements at 3.3 Hz and an efficient low-pass filtering to reduce noise level. With a set of ancillary sensors, the ML system furthermore allows differentiation between different types of NRW inputs, i.e. dew, hoar frost, fog, rime, and the combinations among these, but also additional events when condensation on leaves is less probable, such as water vapour adsorption events. In addition, our ML system design allows one to minimize deviations from natural conditions in terms of canopy and soil temperatures, plant growth, and soil moisture. This is found to be a crucial aspect for obtaining realistic NRW measurements in short-statured grasslands. Soil temperatures were higher in the ML compared to the control, and thus further studies should focus on improving the thermal soil regime of ML. Our ML system has proven to be useful for high-accuracy, long-term measurements of NRW on short-statured vegetation-like grasslands. Measurements with the ML system at a field site in Switzerland showed that NRW input occurred frequently, with 127 events over 12 months with a total NRW input of 15.9 mm. Drainage-water flow of the ML was not measured, and therefore the NRW inputs might be conservative estimates. High average monthly NRW inputs were measured during summer months, suggesting a high ecohydrological relevance of NRW inputs for temperate grasslands.

Factors Influencing the Kinetics of Water Vapour Adsorption on Activated Carbons

The performance of porous carbon materials as sorbents is often compromised by the presence of humidity. Studying the kinetics of water vapour adsorption on activated carbons will undeniably help to overcome this issue. This has been approached in this work by evaluating the influence of several operational factors on the dynamic adsorption of water vapour in these materials. Specifically, different carbon types, particle sizes, air flows and ambient conditions (temperature and relative humidity (RH)) were systematically investigated. The impact of each isolated parameter on both the maximum water uptake and the uptake rate was analyzed by fitting the experimental data to the Linear Driving Force (LDF) kinetic model. The results show that except for the particle size, the studied variables play a role in the water sorption kinetics, although to a different extent. It was also confirmed that the LDF model can adequately describe the kinetics of water vapour adsorption independently of the experimental conditions. Finally, the complete water vapour adsorption process can be described by this model, obtaining a different value of the kinetic constant for the sequential stages, involving different adsorption mechanisms.

Recent progress on hygroscopic materials for indoor moisture buffering

Once in contact with the indoor air, hygroscopic materials can moderate the indoor humidity fluctuation by adsorbing or releasing water vapour, and then improve the moisture regulation and thermal management of buildings. It is desirable to explore the characterized properties of these materials about moisture buffering behaviour. In this regard, we review various hygroscopic materials used for the built environment control. The hygrothermal properties of hygroscopic materials often can be characterized by some parameters, such as water vapour adsorption/desorption capacity, water vapour adsorption/desorption rate, water vapour diffusion coefficient, and so on. To provide an insight on the existing research on humidity control materials, different research studies and the recent progress on humidity control materials have been summarized. The materials include traditional and conventional building materials, some natural materials, and novel humidity control materials. Besides, the relevant parameters are considered as well as the improvement suggestions to enhance the application of humidity control materials in building environments. Finally, new multifunctional materials and intelligent moisture control materials together with the corresponding systems are collated to summarize the latest research trends. The overview of the application of hygroscopic materials can provide current and future researchers guidelines for the science-oriented design of moisture control systems for new energy-efficient buildings.

Evolution of Pore Characteristics for Bentonite Modified by an Ionic Soil Stabilizer during Hydration Processes

An ionic soil stabilizer (ISS) is used to reinforce clay soils because the ISS can regulate the hydration processes and microstructures of clays. To evaluate the regulation of ISS, natural bentonite was modified by ISS at different concentrations in this research. Water vapour adsorption and X-ray diffraction (XRD) were carried out to interpret the hydration mechanism of bentonite. Meanwhile, an associated analysis between hydration pore structures and hydration mechanisms was implemented through variation of pore characteristic tests at different relative humidities (RHs) to distinguish multiscale pore adsorption of water during the corresponding hydration process. In addition, the pore characteristics were studied via XRD, nitrogen adsorption, and mercury injection tests. Finally, the origins that adsorbed water and pore structures changed by adding ISS were discussed. The results showed that for calcium bentonite, the cations hydrated first in the range of 0 < RH < 0.45 ~ 0.55 , accompanied by the expansion of micropores. Then, adsorption occurred on the basal surface of the crystal layer in the range of 0.45 ~ 0.55 < RH < 0.8 ~ 0.9 , with water mainly adsorbed into the mesopores. With further hydration when RH > 0.8 ~ 0.9 , diffused double layer (DDL) water ceaselessly entered the macropores. Both adsorbed water and multiscale pore size decreased when ISS was added to bentonite. The origins of the reduction were the regulation of ISS to exchangeable cations and the basal surface of the crystal layer.

Recyclability, durability and water vapour adsorption of unstabilised and stabilised compressed earth bricks

This paper investigates the recyclability, liquid water durability and water vapour adsorption of both unstabilised and stabilised compressed earth bricks. Stabilised bricks were manufactured by adding either cement or the biopolymer guar gum to the base earth. Unconfined compressive strength tests were then performed on both unstabilised and stabilised earth bricks manufactured with recycled material (i.e. material taken from the failed compressed earth bricks after the compressive strength tests). These tests enabled to assess the influence of recycling on the stiffness, strength and strain energy of all compressed earth bricks. Immersion and drip tests were subsequently performed to investigate the effect of cement and biopolymer stabilisation on the durability of the compressed earth bricks against the weathering action of water. An additional set of laboratory experiments was finally conducted by means of a Dynamic Vapour Sorption (DVS) system to study the effect of earth stabilisation on the capacity of adsorbing/releasing water vapour as the ambient humidity changes. Outcomes from this experimental campaign showed that both unstabilised and biopolymer stabilised earth bricks maintained a similar mechanical performance after recycling, while cement stabilised bricks showed a remarkable reduction of both stiffness and strength. Finally, both cement and biopolymer stabilised bricks improved the liquid water durability while reducing the water vapour adsorption compared with the unstabilised earth bricks. Results from this experimental work will be useful for life cycle assessments, especially for modelling the end-of-life of the material as well as its potential reuse.

Studies of Water-Vapour Adsorption Dynamics of High-Efficiency Desiccant Based on Aluminium Oxide and NaX Zeolite

The dynamic capacity of the commercial desiccant (NaX zeolite) and the adsorbent, synthesised based on low-temperature modifications of aluminium oxide, obtained from bayerite-containing hydroxide, was determined with respect to water vapour. Experimental studies were carried out using a pilot installation at the atmospheric pressure and increased pressure (up to 0.6 MPa) and high humidity. The increase in the height of the layer of the adsorbents leads to an increase of their dynamic capacity with respect to water vapour and the protective power (action) time of the layer. It was shown that at the atmospheric pressure and the pressure of up to 0.3 MPa, the dynamic capacity of NaX is greater; at a higher pressure, the adsorption capacity of the developed adsorbent Al2O3 becomes greater than the zeolite capacity, which allows recommending it as a desiccant at increased pressure.

Nanoparticle Size Effect on Water Vapour Adsorption by Hydroxyapatite

Handling and properties of nanoparticles strongly depend on processes that take place on their surface. Specific surface area and adsorption capacity strongly increase as the nanoparticle size decreases. A crucial factor is adsorption of water from ambient atmosphere. Considering the ever-growing number of hydroxyapatite nanoparticles applications, we decided to investigate how the size of nanoparticles and the changes in relative air humidity affect adsorption of water on their surface. Hydroxyapatite nanoparticles of two sizes: 10 and 40 nm, were tested. It was found that the nanoparticle size has a strong effect on the kinetics and efficiency of water adsorption. For the same value of water activity, the quantity of water adsorbed on the surface of 10 nm nano-hydroxyapatite was five times greater than that adsorbed on the 40 nm. Based on the adsorption isotherm fitting method, it was found that a multilayer physical adsorption mechanism was active. The number of adsorbed water layers at constant humidity strongly depends on particles size and reaches even 23 layers for the 10 nm particles. The amount of water adsorbed on these particles was surprisingly high, comparable to the amount of water absorbed by the commonly used moisture-sorbent silica gel.