Non-equilibrium metal oxides via reconversion chemistry in lithium-ion batteries

Binary metal oxides are attractive anode materials for lithium-ion batteries. Despite sustained effort into nanomaterials synthesis and understanding the initial discharge mechanism, the fundamental chemistry underpinning the charge and subsequent cycles—thus the reversible capacity—remains poorly understood. Here, we use in operando X-ray pair distribution function analysis combining with our recently developed analytical approach employing Metropolis Monte Carlo simulations and non-negative matrix factorisation to study the charge reaction thermodynamics of a series of Fe- and Mn-oxides. As opposed to the commonly believed conversion chemistry forming rocksalt FeO and MnO, we reveal the two oxide series topotactically transform into non-native body-centred cubic FeO and zincblende MnO via displacement-like reactions whose kinetics are governed by the mobility differences between displaced species. These renewed mechanistic insights suggest avenues for the future design of metal oxide materials as well as new material synthesis routes using electrochemically-assisted methods.

Current Trends of Arsenic Adsorption in Continuous Mode: Literature Review and Future Perspectives

Arsenic is a toxic element for humans and a major pollutant in drinking water. Natural and anthropogenic sources can release As into water bodies. The countries with the greatest arsenic contamination issues lack the affordable technology to attain the maximum permitted concentrations. Adsorption can be a highly efficient and low-cost option for advanced water treatment, and the development of new cheap adsorbents is essential to expand access to water with a safe concentration of arsenic. This paper aims to review the state of the art of arsenic adsorption from water in continuous mode and the latest progress in the regeneration and recovery of arsenic. The disposal of the exhausted bed is also discussed. Fixed-bed column tests conducted with novel adsorbents like binary metal oxides and biosorbents achieved the highest adsorption capacities of 28.95 mg/g and 74.8 mg/g, respectively. Iron-coated materials presented the best results compared to adsorbents under other treatments. High recovery rates of 99% and several cycles of bed regeneration were achieved, which can aggregate economic value for the process. Overall, further pilot-scale research is recommended to evaluate the feasibility of novel adsorbents for industrial purposes.

Transparent Photodetector Based on Polyoxometalates Modified Electrospun ZnO Homojunction Nanowires Intersection Array

Transparent photodetectors (PDs) based on binary metal oxides have become a hot topic in the field of photodetection because of their ability to absorb and detect ultraviolet (UV) light. However,...