The Study of the Influence of Matrix, Size, Rotation Angle, and Magnetic Field on the Isothermal Entropy, and the Néel Phase Transition Temperature of Fe2O3 Nanocomposite Thin Films by the Monte-Carlo Simulation Method

In this paper, the study of the influence of the matrix structure (mxm) of thin-film, rotation angle (α), magnetic field (B), and size (D) of Fe2O3 nanoparticle on the magnetic characteristic quantities such as the magnetization oriented z-direction (MzE), z-axis magnetization (Mz), total magnetization (Mtot), and total entropy (Stot) of Fe2O3 nanocomposites by Monte-Carlo (MC) simulation method are studied. The applied MC Metropolis code achieves stability very quickly, so that after 30 Monte Carlo steps (MCs), the change of obtained results is negligible, but for certainty, 84 MCs have been performed. The obtained results show that when the mxm and α increase, the magnetic phase transition appears with a very small increase in temperature Néel (TNtot). When B and D increase, TNtot increases very strongly. The results also show that in Fe2O3 thin films, TNtot is always smaller than with Fe2O3 nano and Fe2O3 bulk. When the nanoparticle size is increased to nearly 12 nm, then TNtot = T = 300 K, and between TNtot and D, there is a linear relationship: TNtot = −440.6 + 83D. This is a very useful result that can be applied in magnetic devices and in biomedical applications.

AC Susceptibility Studies under DC Fields in Superspinglass Nanomaghemite-Multiwall Carbon Nanotube Hybrid

Magnetic properties of maghemite (γ-Fe2O3) nanoparticles grown on activated multiwall carbon nanotubes have been studied by alternating current (AC) magnetic susceptibility experiments performed under different temperatures, frequencies, and applied magnetic fields. Transmission electron images have suggested that the γ-Fe2O3 nanoparticles are not isolated and have an average size of 9 nm, but with a relatively broad size distribution. The activation energies of these 9 nm γ-Fe2O3 nanoparticles, determined from the generalized Vogel–Fulcher relation, are reduced upon increasing the direct current (DC) field magnitude. The large activation energy values have indicated the formation of a superspinglass state in the γ-Fe2O3 nanoparticle ensemble, which were not observed for pure γ-Fe2O3 nanoparticles, concluding that the multiwall carbon nanotubes favored the appearance of highly concentrated magnetic regions and hence the formation of superspinglass state. Magnetic relaxation studies, using Argand diagrams recorded for DC probe fields (<20 kOe) below the magnetic blocking temperature at 100 and 10 K, have revealed the presence of more than one relaxation process. The behavior of the ensemble of γ-Fe2O3 nanoparticles can be related to the superspinglass state and is also supported by Almeida–Thouless plots.

Nano-structural effects on Hematite (α-Fe2O3) nanoparticle radiofrequency heating

Nano-sized hematite (α-Fe2O3) is not well suited for magnetic heating via an alternating magnetic field (AMF) because it is not superparamagnetic—at its best, it is weakly ferromagnetic. However, manipulating the magnetic properties of nano-sized hematite (i.e., magnetic saturation (Ms), magnetic remanence (Mr), and coercivity (Hc)) can make them useful for nanomedicine (i.e., magnetic hyperthermia) and nanoelectronics (i.e., data storage). Herein we study the effects of size, shape, and crystallinity on hematite nanoparticles to experimentally determine the most crucial variable leading to enhancing the radio frequency (RF) heating properties. We present the synthesis, characterization, and magnetic behavior to determine the structure–property relationship between hematite nano-magnetism and RF heating. Increasing particle shape anisotropy had the largest effect on the specific adsorption rate (SAR) producing SAR values more than 6 × greater than the nanospheres (i.e., 45.6 ± 3 W/g of α-Fe2O3 nanorods vs. 6.89 W/g of α-Fe2O3 nanospheres), indicating α-Fe2O3 nanorods can be useful for magnetic hyperthermia.

Room Temperature Magnetic Memory Effect in Nanodiamond/γ-Fe2O3 Composites

We report a room temperature magnetic memory effect (RT-MME) from magnetic nanodiamond (MND) (ND)/γ-Fe2O3 nanocomposites. The detailed crystal structural analysis of the diluted MND was performed by synchrotron radiation X-ray diffraction, revealing the composite nature of MND having 99 and 1% weight fraction ND and γ-Fe2O3 phases, respectively. The magnetic measurements carried out using a DC SQUID magnetometer show the non-interacting superparamagnetic nature of γ-Fe2O3 nanoparticles in MND have a wide distribution in the blocking temperature. Using different temperature, field, and time relaxation protocols, the memory phenomenon in the DC magnetization has been observed at room temperature (RT). These findings suggest that the dynamics of MND are governed by a wide distribution of particle relaxation times, which arise from the distribution of γ-Fe2O3 nanoparticle size. The observed RT ferromagnetism coupled with MME in MND will find potential applications in ND-based spintronics.

The modification effect of Fe2O3 nanoparticles on ZnO nanorods improves the adsorption and detection capabilities of TEA

Surface modification is a simple and efficient method to enhance gas sensing properties of semiconductor materials. In this paper, Fe2O3 nanoparticle-decorated ZnO nanorods are successfully fabricated by a facile two-step...