Petrographic, geochemical, and isotopic evidence of crustal assimilation processes in the Indaiá-II kimberlite, Alto Paranaíba Province, southeast Brazil

ABSTRACT The Indaiá-I and Indaiá-II intrusions are hypabyssal, small-sized ultrabasic bodies belonging to the Cretaceous magmatism of the Alto Paranaiba Alkaline Province (southeast-central western Brazil). While Indaiá-I is classified as an archetypal group-I kimberlite, Indaiá-II (its satellite intrusion) presents several petrographic and chemical distinctions: (1) an ultrapotassic composition (similar to kamafugites), (2) lower volumes of olivine macrocrysts, (3) diopside as the main matrix phase (in contrast with the presence of monticellite in Indaiá-I), (4) high amounts of phlogopite, and (5) abundant felsic boudinaged and stretched microenclaves and crustal xenoliths. Disequilibrium features, such as embayment and sieve textures in olivine and clinopyroxene grains, are indicative of open-system processes in Indaiá-II. Mineral reactions observed in Indaiá-II (e.g., diopside formed at the expense of monticellite and olivine; phlogopite nearby crustal enclaves and close to olivine macrocrysts) point to an increase in the silica activity of the kimberlite magma; otherwise partially melted crustal xenoliths present kalsilite, generated by desilification reactions. The high Contamination Index (2.12–2.25) and the large amounts of crustal xenoliths (most of them totally transformed or with evidence of partial melting) indicate a high degree of crustal assimilation in the Indaiá-II intrusion. Calculated melts (after removal of olivine xenocrysts) of Indaiá-II have higher amounts of SiO2, Al2O3, K2O, slightly higher Rb/Sr ratios, lower Ce/Pb and Gd/Lu ratios, higher 87Sr/86Sr, and lower 143Nd/144Nd than those calculated for Indaiá-I. Crustal contamination models were developed considering mixing between the calculated melts of Indaiá-I and partial melts modeled from the granitoid country rocks. Mixing-model curves using major and trace elements and isotopic compositions are consistent with crustal assimilation processes with amounts of crustal contribution of ca. 30%. We conclude that (1) Indaiá-II is representative of a highly contaminated kimberlitic intrusion, (2) this contamination occurred by the assimilation of anatectic melts from the main crustal country rocks of this area, and (3) Indaiá-I and Indaiá-II could have had the same parent melt, but with different degrees of crustal contamination. Our petrological model also indicates that Indaiá-II is a satellite blind pipe linked to the main occurrence of Indaiá-I.

Preliminary geochemical characterization of gas manifestations in North Macedonia

<p>Like most of the Balkan Peninsula, North Macedonia is a geodynamically active area. As such it has many hydrothermal features and gas manifestations. Until now, no systematic study about the geochemical characterization of the geogenic gases was made before in this country. In August 2019, 24 gas samples were collected in the study area. All, except one collected at Duvalo (soil gas), are gases bubbling or dissolved in thermomineral waters (temperatures from 12 to 66 °C). They were analysed in the laboratory for their chemical (He, Ne, Ar, O<sub>2</sub> , N<sub>2</sub> , H<sub>2</sub> , H<sub>2</sub>S, CH<sub>4</sub> and CO<sub>2</sub>) and isotopic composition (δ<sup>13</sup>C-CO<sub>2</sub>, δ<sup>13</sup>C-CH<sub>4</sub>, δ<sup>2</sup>H-CH<sub>4</sub> and R/R<sub>A</sub>). Most of the gases have CO<sub>2</sub> as the main component (400-998,000 ppm) while the remaining are enriched in N<sub>2</sub> (1300-950,000 ppm). Helium ranges from 0.3 to 2560 ppm while CH<sub>4</sub> from 1.6 to 20,200 ppm. R/R<sub>A</sub> and <sup>4</sup>He/<sup>20</sup>Ne ratios indicate a generally low atmospheric contamination, a prevailing crustal contribution and mantle contributions between 1 and 20% considering a MORB endmember. The highest mantle contributions are found in the SE part of the country very close to the sites that show the highest R/R<sub>A</sub> values in continental Greece [1]. This area is characterised by extensional tectonics and Plio-Pleistocene volcanism. A quite high mantle contribution (about 15%) is also found in two manifestations in the NW part of the country along a main normal fault system. With the exception of the sample of Smokvica, which has very low CO<sub>2</sub> (1400 ppm) and δ<sup>13</sup>C-CO<sub>2</sub> (-15.7 ‰ V-PDB), all free gases show a relatively narrow range in δ<sup>13</sup>C-CO<sub>2</sub> values (-4.6 to +1.0 ‰ V-PDB) indicating the mixing between a mantle and a carbonate rock source. The isotope composition allows us to assign the CH<sub>4</sub> origin to three sources. The largest group can be attributed to a hydrothermal origin (δ<sup>13</sup>C-CH<sub>4</sub> around -20 ‰ V-PDB and δ<sup>2</sup>H-CH<sub>4</sub> around -100‰). Three samples collected in the SW part of the country have a thermogenic origin (δ<sup>13</sup>C-CH<sub>4</sub> around -35 ‰ V-PDB and δ<sup>2</sup>H-CH<sub>4</sub> around -160‰ V-SMOW). Finally, one sample (Smokvica) with the highest values (δ<sup>13</sup>C-CH<sub>4</sub> -7.2 ‰ V-PDB and δ<sup>2</sup>H-CH<sub>4</sub> -80‰ V-SMOW) may be attributed to abiotic processes in a continental serpentinization environment or to methane oxidation.</p><p>This research was funded by the DCO Grant n. 10881-TDB “Improving the estimation of tectonic carbon flux”, GINOP-2.3.2-15-2016-00009 ‘ICER’ project and PO FSE Sicilia 2014 – 2020 (CUP: G77B17000200009).</p><p>References:</p><p>[1] Daskalopoulou et al., 2018 – Chemical Geology, 479, 286-301</p>

The Upper Cretaceous intrusive rocks with extensive crustal contribution in Hacımahmutuşağı Area (Aksaray/Turkey)

The Hacımahmutuşağı area (Aksaray/Turkey) is located in the western part of the Central Anatolian Crystalline Complex (CACC). Gneiss and marble compose the basement units, while intrusive rocks are gabbros and granitoids. The pegmatitic hornblende gabbros contain pegmatitic to fine-grained hornblendes, plagioclase, clinopyroxene, and accessory opaque minerals. The fine-grained gabbros, on the other hand, are composed of plagioclase, hornblende, and biotite as major components whereas the apatite and opaque minerals are present in accessory content. Granitic– granodioritic rocks are the common intrusive rock types in the area, and constitute quartz, orthoclase, plagioclase and biotite, and accessory zircon and opaque minerals. Leucogranites, comprising quartz, orthoclase, plagioclase with minor biotite, hornblende, and with accessory apatite and opaque minerals, are found as dykes intruding the marble and the granitic–granodioritic rocks. Strontium–neodymium isotope data of gabbros and granitoids have high 87Sr/86Sr(i) ratios (0.7076 to 0.7117) and low ɛNd(i) values (−5.0 to −9.8) point out enriched source and pronounced crustal contribution in their genesis. In the Hacımahmutuşağı area, it is plausible that the heat increase caused by the hot zone, which was generated by underplating mafic magma along with the hydrous mafic sills in the lower crust, might have resulted in partial melts from crystallized mafic sills and older crustal rocks. It can be suggested that these hybrid melts adiabatically rose to the shallow crust, ponded and crystallized there and formed the magma source of the intrusive rocks within the Hacımahmutuşağı area and the other hybrid granitic rocks with crustal signatures in the CACC. Geochemical data indicate that granitoids and gabbros are collision to post-collision related sub-alkaline rocks derived from an enriched source with extensive crustal inputs.

Geology, Mineralogy, Fluid Inclusion, and H–O–S–Pb Isotope Constraints on Ore Genesis of the Keyue Sb–Pb–Zn–Ag Deposit in Southern Tibet

The Keyue deposit is a medium-sized deposit similar to the Zhaxikang deposit within the North Himalayan Metallogenic Belt (NHMB). The ore formation can be divided into Pb–Zn mineralization (stages 1 and 2), Sb–Ag mineralization (stages 3 and 4), and Sb–Hg mineralization (stages 5 and 6). The fluid inclusion data show that the first two pulses of mineralization have different characteristics, but both belong to the epithermal category (stage 2: 172.9~277.2°C, 7.4~17.0 wt% NaCl eq.; stages 3 and 4: 142.1~321.0°C, 2.7~17.96 wt% NaCl eq.). The H–O isotopic compositions of stages 3 and 4 quartz (δDV-SMOW: –174‰~−120‰, δ18OH2O: 1.59‰~11.34‰) are similar to those of stages 3 and 4 minerals (δDV-SMOW: –165‰~−150‰, δ18OH2O: 6.14‰~13.03‰), whereas they are different from stage 1 and 2 (δDV-SMOW: –108.3‰~−103.6‰, δ18OH2O: 1.92‰~3.82‰) and stage 5 and 6 (δDV-SMOW: –165‰~−138‰, δ18OH2O: −12.91‰~0.82‰) minerals from the Zhaxikang deposit. Additionally, stage 2 sulfides have δ34S values of 5.4‰~11.2‰ that are similar to stage 2 sulfides in the Zhaxikang deposit (7.8‰~12.2‰), and these δ34S values overlap those of many SEDEX-type deposits. The δ34S values also show a decreasing trend from stage 2 through stages 3 and 4 to stage 5 in Keyue and Zhaxikang deposits, which may relate to the overprint by later mineralization events. The Pb isotopic data (206Pb/204Pb: 18.530~19.780, 207Pb/204Pb: 15.674~15.939, and 208Pb/204Pb: 38.618~40.559) show a significant crustal contribution. However, the minerals from different pulses of mineralization also exhibit slightly different Pb isotopic characteristics. These inferences from fluid inclusions and isotope are also demonstrated by geological and mineralogical evidence. Overall, the Keyue deposit is an epithermal deposit and has mainly experienced three pulses of mineralization.

GEOCHEMICAL CHARACTERIZATION OF NATURAL GAS MANIFESTATIONS IN GREECE

The Greek region is characterized by intense geodynamic activity with widespread volcanic, geothermal and seismic activity. Its complex geology is reflected in the large variety of chemical and isotopic composition of its gas manifestations. Basing on their chemical composition the gases can be subdivided in three groups, respectively CO2, CH4 or N2-dominated. On oxygen-free basis these three gases make up more than 97% of the total composition. The only exceptions are fumarolic gases of Nisyros that contain substantial amounts of H2S (up to more than 20%) and one sample of Milos that contains 15% of H2. CO2-dominated gases with clear mantle contribution in their He isotopic composition (R/Ra corrected for air contamination ranging from 0.5 to 5.7) are found along the subduction-related south Aegean active volcanic arc and on the Greek mainland close to recent (upper Miocene to Pleistocene) volcanic centers. These areas are generally characterized by active or recent extensive tectonic activity and high geothermal gradients. On the contrary, gases sampled in the more external nappes of the Hellenide orogen have generally a CH4- or N2-rich compositions and helium isotope composition with a dominant crustal contribution (R/Ra corr < 0.2). The chemical and isotopic characteristics of the emitted gas display therefore a clear relationshipwith the different geodynamic sectors of the region. Gas geochemistry of the area contributes to a better definition of the crust-mantle setting of the Hellenic region.