Evidences for Bimodal volcanism on 4-Vesta Asteroid from impact-melt clast

<p>Silicic / acid volcanism has not been widely described either on Moon, Mars or in Asteroid 4 Vesta. The occurrence of sialic crustal rocks on the lunar surface is extremely limited. Reports on silicic (non-mare) volcanic rocks on Moon is found to be associated in Compton-Belkovich volcanic complex, Hansteen Alpha volcanic crater, Lassell massif, Gruithuisen domes and ejecta of Aristarchus crater (Clegg-Watkins et al., 2017). The occurrence of several volcanic constructs (e.g. collapse features, domes) and volatile-rich pyroclastics in association with silicic rocks further emphasize existence of viscous magmas on Moon. A localized occurrence of silicic volcanism on Mars is also envisaged by the presence of tridymite in mudstone of Gale crater (Morris et al., 2016). However, the exact formation mechanism of silicic volcanism on Moon, Mars or even in 4-Vesta has been largely hindered due to lack of silicic meteorite samples or mission-returned samples.</p> <p>The HED (Howardite, Eucrite, Diogenite) meteorites is considered to have originated from a common parent body Asteroid 4-Vesta. Recent Dawn mission also attempts to validate its geologic context and formulate a possible HED-Vesta connection (McSween et al., 2013). Based on Dawn findings, Vesta’s surface appears to be similar to a mixture of basaltic eucrite and diogenite resembling a more complex breccia howardite (De Sanctis et al., 2012; Prettyman et al., 2012). A variety of clasts are apparently common in howardite. Here, we report the petrography and major element geochemistry of a new impact-melt clast from Lohawat howardite. Our results show that the clast composition is unique and unlikely to be explained by typical impact melting of HED mafic lithologies. One of the impact melts (~20µ across) hosted in ferroaugite (Wo<sub>42</sub>En<sub>2.7</sub>Fs<sub>55.3</sub>) clast substantially differ in composition from the other impact-melt (~50µ across) hosted in ilmenite clast, specially in terms of SiO<sub>2</sub> wt%, CaO wt%, K<sub>2</sub>O wt% and K<sub>2</sub>O / (K<sub>2</sub>O + Na<sub>2</sub>O) ratio. Moreover, one appears nearly homogeneous in contrast to evolved nature with limited heterogeneity as compared to other. Both the melts are oblong-shaped, smooth textured with sharp outline and embedded in the host monomict mineral clast of different composition belonging to possible parent of cumulate eucrite.</p> <p>The average bulk composition of Lohawat is consistent with basaltic crusts (SiO<sub>2</sub> ~50.3-51.8 wt%, Al<sub>2</sub>O<sub>3</sub> ~3.5-8.2 wt%, total iron-magnesia ~31.2-38.0 wt%, CaO ~2.2-7.6 wt%) (Chattopadhyay et al. 1998; Sisodia et al. 2001; Ghosh, 2011). Supplement to basaltic volcanism, we report for the first time the incipient acid volcanism in a HED meteorite based on two impact melt inclusions of nearly rhyolitic composition (SiO<sub>2</sub> ~76-79.5 wt%, Al<sub>2</sub>O<sub>3 </sub>~11.4 - 12.8 wt%, total alkali ~3 - 8 wt% with K<sub>2</sub>O/ (Na<sub>2</sub>O + K<sub>2</sub>O) ~0.21-0.95, CaO ~ 0.8 - 4.67wt% and low total iron-magnesia ~1-2 wt%). Our study thus reinforces to conceive the idea that some rhyolitic crusts formed due to differentiation of mafic magma were exposed on Vesta and heterogeneity of Vestan surface is definitely different from one as previously thought.</p> <p>References: Clegg-Watkins, R.N. et al. 2016, Icarus 285:169-184. Morris, R.V. et al. 2016, 113:7071-7076. McSween, H.Y. et al. 2013, MAPS 48:2090-2104. De Sanctis, M.C. et al. 2012, Science 336:697-700. Prettyman, T.H. et al. 2012, Science 338:242-246. Chattopadhyay, B. et al. 1998. JGSI 51:171-174. Sisodia, M.S. et al. 2001 MAPS 36:1457-1466. Ghosh, S. IJG 65:251-264.</p>

The origin of adakite-like magmas in the modern continental ollision zone: evidence from pliocene dacitic volcanism of the Akhalkalaki lava plateau (Javakheti highland, Lesser Kaucasus)

The paper reports the isotope-geochronological and petrological-geochemical studies of the Pliocene moderately-acid volcanism of the Akhalkalaki Plateau in the central part of the Lesser Caucasus (Javakheti highland, Georgia). K-Ar dating showed that young dacitic lavas and pyroclastic rocks were formed in the Mid-Pliocene (3.28 ± 0.10 Ma) in relation with the explosive–effusive eruptions of small composite volcanic cones and formation of minor extrusive domes confined mainly to the eastern margin of the region. Isotope-geochronological data in the combination with results of structural drilling indicate that the considered short-term pulse of the volcanic activity occurred during a short gap between two phases of the Pliocene–Early Pleistocene mafic magmatism widespread within the Akhalkalaki plateau. The studied Pliocene dacites were erupted at the post-collisional stage of the evolution of the Lesser Caucasus, but bear petrological-geochemical affinity of adakitic series. They are characterized by the steady presence of amphibole phenocrysts, the elevated contents of Sr, Ba, LILE and the lowered contents of Y, Nb, Ta, and HREE, and have depleted Sr isotopic composition (87Sr/86Sr < 0.7045). Analysis of petrogenetic models earlier proposed to explain the generation of adakite-like magmas in the modern collision zones showed that the origin of the Pliocene dacitic lavas of the Akhlkalaki plateau is best described by the crystallization differentiation of watersaturated calc-alkaline basaltic melts with removal of common mafic rock-forming minerals (first of all, amphibole and pyroxene) and accessory phases (apatite, titanite, Ti-magnetite) as cumulus minerals. Crustal assimilation of evolved magmas only insignificantly contributed to the petrogenesis of the dacites.

Zircon U-Pb geochronology, Sm-Nd and Pb-Pb isotope systematics of Ediacaran post-collisional high-silica Acampamento Velho volcanism at the Tupanci area, NW of the Sul-Rio-Grandense Shield, Brazil

ABSTRACT: We present new U-Pb zircon ages and Sm-Nd-Pb isotopic data for volcanic and hypabyssal acid rocks from the northernmost exposure of the Acampamento Velho Formation in the NW portion of the Sul-Rio-Grandense Shield, Brazil. The first volcanic episode, grouped in the high-Ti rhyolites from the Tupanci hill, shows age of 579 ± 5.6 Ma, which is in agreement with the post-collisional Acampamento Velho Formation volcanism in the Bom Jardim Group of the Camaquã Basin. A poorly constrained age of 558 +/- 39 Ma was obtained for rhyolites from the low-Ti group at the Picados Hill, which may indicate a younger acid volcanism, or a greater time span for the volcanism of the Acampamento Velho Formation in southernmost Brazil. Regarding magmatic sources, Sm/Nd isotopic data coupled to Pb isotopes and a review of trace element geochemistry indicate different amounts of Paleoproterozoic (Dom Feliciano, Pinheiro Machado Suite) to Neoproterozoic (Rio Vacacaí terrane) lower crust melting. Our data, coupled with literature data, contribute to a better understanding of the stratigraphic evolution for the Neoproterozoic post-collisional volcanic successions of the Camaquã Basin in the Sul-Rio-Grandense Shield.

Provenance of Permian Malužiná Formation sandstones (Hronicum, Western Carpathians): evidence from monazite geochronology

The Permian Malužiná Formation and the Pennsylvanian Nižná Boca Formation are Upper Paleozoic volcano- sedimentary complexes in the Hronicum nappe system. Sandstones, shales and conglomerates are the dominant lithological members of the Malužiná Formation sequence. Detrital monazites were analysed by electron microprobe, to obtain Th-U-Pb ages of the source areas. The majority of detrital monazites showed Devonian-Mississippian ages, ranging from 330 to 380 Ma with a weighted average of 351 ± 3.3 (2σ), that correspond well with the main phase of arcrelated magmatic activity in the Western Carpathians. Only a small portion of detrital monazites displayed Permian ages in the range of 250-280 Ma, with a significant maximum around 255 Ma. The weighted average corresponds to 255 ± 6.2 Ma. These monazites may have been partially derived from the synsedimentary acid volcanism that was situated on the margins of the original depositional basin. However, some of the Triassic ages (230-240 Ma), reflect, most likely, the genetic relationship with the overheating connected with Permian and subsequent Triassic extensional regime. Detrital monazite ages document the Variscan age of the source area and also reflect a gradual development of the Hronicum terrestrial rift, accompanied by the heterogeneous cooling of the lithosphere.

Volcanism and stratigraphy of the Neoproterozoic Campo Alegre Basin, SC, Brazil

The depositional succession of the Campo Alegre Basin (Santa Catarina - southern Brazil) was investigated having the evolution of the volcanic activity as background. The different stratigraphic units are interpreted as belonging to different volcanic stages: Bateias Formation, conglomerates and sandstones, related with a pre-volcanic stage; Campo Alegre Group, at the main volcanic stage, with each different formation corresponding to different episodes of volcanism - Rio Negrinho Formation, corresponding to the basic volcanism, Avenca Grande Formation to ignimbritic event, Serra de São Miguel Formation to the acid volcanism and Fazenda Uirapuru Formation, related to an explosive event; Rio Turvo and Arroio Água Fria formations correspond respectively to inner and extra-caldera deposits.