Unravelling the redox mechanism and kinetics of a highly active and selective Ni-based material during the oxidative dehydrogenation of ethane

Ethane oxidative dehydrogenation (ODH-C2) is a promising alternative for producing ethylene. Even if SnO2-NiO catalysts are characterized by their long-term stability and high selectivity to ethylene, also in the absence...

Oxidative dehydrogenation of ethane: catalytic and mechanistic aspects and future trends

Ethane oxidative dehydrogenation (ODH) is an attractive, low energy, alternative route to reduce the carbon footprint for ethene production, however, the commercial implementation of ODH processes requires catalysts with improved selectivity.

CO2 Assisted Ethane Oxidative Dehydrogenation Over MoOx catalysts supported on Reducible CeO2-TiO2

Supported MoOx on mixed CeO2-TiO2 were investigated for the oxidative dehydrogenation of ethane (ODHE) using CO2 as a mild oxidant. Raman spectroscopic characterization of the synthesized catalysts under dehydrated conditions...

Synthesis, properties, and activity of MoVTeNbO catalysts modified by zirconia-pillared clays in oxidative dehydrogenation of ethane

Composites comprising MoVTeNbO mixed oxide and zirconia-pillared montmorillonite clays (PilCs) were prepared. XRD and TEM with EDX studies confirmed the preservation of M1 MoVTeNbO phase in these composites responsible for high activity and selectivity in ethane oxidative dehydrogenation into ethylene. For composites with PilC content of 10 wt%, the best ethylene yield exceeding that of bulk MoVTeNbO oxide was demonstrated for clays with zirconia pillars doped with Ce and Al possessing the highest specific surface area. This is explained by optimized chemical interaction of these clays with MoVTeNbO mixed oxide improving its bulk oxygen mobility and reactivity by structure disordering while blocking surface sites responsible for combustion due to the stabilization of the reactive terminal oxygen species.

On the Promoting Effects of Te and Nb in the Activity and Selectivity of M1 MoV-Oxides for Ethane Oxidative Dehydrogenation

The pathways of ethane oxidative dehydrogenation and total combustion have been elucidated for M1 phase type Mo–V oxide catalysts with different metal composition. The ethane oxidation mechanism is not affected by the presence of Te or Nb. Conversely, the selectivity is strongly affected by stoichiometry of M1 catalysts. This is attributed to the facile oxidation of ethene to COx upon formation of unselective VOx species in the absence of Te and Nb.