The 3s Rydberg state as a doorway state in the ultrafast dynamics of 1,1-difluoroethylene

The deactivation dynamics of 1,1-difluoroethylene after light excitation is studied within the surface hopping formalism in the presence of 3s and 3p Rydberg states using multi-state second order perturbation theory (MS-CASPT2).

Suppression of Intramolecular Vibrational Energy Redistribution by Intense CW-Laser Fields

We present a quantum control scheme which realizes suppression of the intramolecular vibrational energy redistribution (IVR). In this scheme, we utilize effective decomposition brought by intense CW-laser fields, which enables to exclude the doorway state coupled to background manifolds. In doing so, we introduce a helper state and make it optically coupled with the doorway state through the intense CW-laser field. We have applied the present scheme to both the Bixon-Jortner model and the SCCl2 model system.

SELECTIVE FRAGMENTATION OF VALENCE- AND CORE-ELECTRON-EXCITED CD4 and SF6 MOLECULES

Electron–ion coincidence measurements with energy-resolved electrons are a powerful tool in studies of molecular fragmentation processes, since fragmentation from a specific doorway state can be monitored while the remaining reactions are discriminated. Presently, we have applied this technique in measurements of coincidence spectra of the CD 4 and SF 6 molecules after valence and core electron excitation. The newly constructed energy-resolved electron–ion coincidence station developed for this project has been used. Our results on CD 4 are the first demonstration of a correlation between vibrations and molecular dissociation observed in this molecule. The SF 6 spectra reveal strong selectivity in dissociation following distinct electronic states of the molecule. This selectivity reflects the bonding properties of the potential surfaces involved in the studied processes. The obtained results exemplify the potential of the new multicoincidence station used in this work.

FERMION-SECTOR FRUSTRATED SU(4) AS A PREONIC PRECURSOR OF THE STANDARD MODEL

We give a model for composite quarks and leptons based on the semisimple gauge group SU(4), with the preons in the 10 representation; this choice of gauge gluon and preon multiplets is motivated by the possibility of embedding them in an N=6 supergravity multiplet, with the preons and antipreons both in the 20 of SU(6). Hypercolor singlets are forbidden in the fermionic sector of this theory; we propose that the SU(4) symmetry spontaneously breaks to SU (3)× U (1), with the binding of triality nonzero preons and gluons into composites, and with the formation of a color singlet condensate that breaks the initial Z12 vacuum symmetry to Z6. The spin ½ fermionic composites have the triality structure of a quark–lepton family, and the initial Z12 symmetry implies that there are six massless families, which mix to give three distinct families below the scale of the condensate. The spin 1 triality zero composites of the color triplet SU(4) gluons, when coupled to the condensate and with the color singlet representation of the 10 acting as a doorway state, lead to weak interactions of the fermionic composites through an SU(2) gauge algebra. The initial Z12 symmetry implies that this SU(2) gauge algebra structure is doubled, which in turn permits the corresponding independent gauge bosons to couple to chiral components of the composite fermions. Since the U(1) couples to the 10 representation as B-L, an effective SU (2)L× SU (2)R × U (1)B-L electroweak theory arises at the condensate scale, with all composites having the correct electric charge structure. Assuming a mechanism for forming composite Higgs bosons, the Z12→ Z6 symmetry breaking chain implies that below the condensate scale there can be two sets of discrete chiral Z6 triplets of Higgs doublets, as required by a phenomenological model for the CKM matrix that we have analyzed in detail elsewhere. A renormalization group analysis of the SU(4) model shows that the conversion by binding of one 10 of SU(4) to 12 triplets of SU(3) can give a very large, calculable hierarchy ratio between the SU(4) and the hadronic mass scales.