librational mode
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2019 ◽  
Vol 21 (38) ◽  
pp. 21205-21212 ◽  
Author(s):  
Giuseppe Cassone ◽  
Jiri Sponer ◽  
Sebastiano Trusso ◽  
Franz Saija

IR and Raman spectra of bulk liquid water under intense electric fields reveal the contraction of both spectra and the onset of a novel high-frequency librational mode band. Moreover, the water structure evolves toward “ice-like” arrangements.


2010 ◽  
Vol 24 (08) ◽  
pp. 817-824 ◽  
Author(s):  
D. KAVRUK ◽  
H. YURTSEVEN

We study here the temperature dependence of the Raman frequencies for the overtone 2ν6 of the librational mode ν6 in phase III of NH 4 I . By using the experimental infrared frequencies of the 2ν6 mode, we predict the Raman frequencies of this overtone 2ν6 mode as a function of temperature at atmospheric pressure in phase III of NH 4 I . Our calculations indicate that the Raman frequencies of 2ν6 exhibit anomalous behavior at around 110 K (P = 0) in phase III of NH 4 I , as observed experimentally.


2003 ◽  
Vol 67 (3) ◽  
pp. 555-562 ◽  
Author(s):  
I. P. Swainson ◽  
R. P. Hammond

AbstractIkaite is a metastable hexahydrate of calcium carbonate, forming in aqueous conditions near freezing conditions. Neutron powder diffraction data of synthetic deuterated ikaite, collected at seven temperatures from 4 to 270 K, were refined. The linear thermal expansion coefficients are quite anisotropic, being smaller in the direction of the C—O bond. A review of the hydrogen-bonding scheme around the (CaCO03) ion pair is given and an additional weak potential hydrogen bond is suggested. Temperature-dependent growth of the atomic displacement factors of the carbonate O1 atom agrees with the previous suggestion of a possible low-frequency, hindered librational mode of the carbonate group.


2003 ◽  
Vol 790 ◽  
Author(s):  
Fouad M. Aliev ◽  
Manuel Rivera Bengoechea

ABSTRACTBroadband dielectric spectroscopy was used to study the influence of boundary conditions and layer thickness of liquid crystal (LC) confined to cylindrical pores on low frequency and high frequency relaxation processes. Low frequency measurements provided information on the relaxation of surface polarization that arose at LC – pore wall interface. The dynamics of molecular reorientations were investigated in high frequency experiments. In samples with axial orientation of molecules, the dielectric mode due to reorientation of molecules around their short axis was investigated. The homeotropic alignment of molecules facilitated the investigation of the librational mode. The behavior of this mode was different from the behavior observed in investigations of relaxation due to reorientation of molecules around their short axis. Broadening of the dielectric spectra was observed in confined LC. The broadening increases with decreasing liquid crystal layer thickness.


2001 ◽  
Vol 699 ◽  
Author(s):  
Fouad M. Aliev

AbstractBroadband dielectric spectroscopy has been applied for investigations of the dynamic behavior of liquid crystals (LCs) confined in porous matrices with random pores as well as in parallel cylindrical pores. We observed deep supercooling of LC in random pores. The relaxation times of the process due to the molecular rotation in deeply supercooled state are slower than at the temperatures corresponding to nematic phase by a factor of 106. This slowing down is accompanied by anomalous broadening of the dielectric spectra. For LC confined in cylindrical pores with homeotropic orientation on the pore walls we have investigated the relaxation of the librational mode. The dynamics of this mode is different from the behavior observed in investigations of relaxation due to reorientation of molecules around their short axis. The interpretation of the temperature dependencies of relaxation times of the librational mode needs the involvement of the temperature dependence of orientational order parameter. The investigations of the relaxation in thin LC layers formed on cylindrical pore walls show that the process due to rotation of molecules around their short axis (with single relaxation time for bulk LC) is the process with a distribution of relaxation times in thin layers and this process broadens with decreasing thickness of the layers.


2000 ◽  
Vol 651 ◽  
Author(s):  
Z. Nazario ◽  
G. P. Sinha ◽  
F.M. Aliev

AbstractDielectric spectroscopy was applied to investigate the dynamic properties of liquid crystal octylcyanobiphenyl (8CB) confined in 2000 Å cylindrical pores of Anopore membranes with homeotropic and axial (planar) boundary conditions on the pore walls. Homeotropic boundary conditions allow the investigation of the librational mode in 8CB by dielectric spectroscopy. We found that the dynamics of the librational mode is totally different from the behavior observed in investigations of relaxation due to reorientation of molecules around their short axis. The interpretation of the temperature dependence of relaxation times and of the dielectric strength of the librational mode needs the involvement of the temperature dependence of orientational order parameter. For samples with axial boundary conditions, layers of LCs with different thickness were obtained on the pore walls as a result of controlled impregnation of porous matrices with 8CB from solutions of different liquid crystal concentration. The process due to rotation of molecules around their short axis with single relaxation time observed for bulk 8CB is replaced by a process with a distribution of relaxation times in thin layers. This relaxation process broadens with decreasing layer thickness.


1996 ◽  
Vol 186 (1) ◽  
pp. 177-180 ◽  
Author(s):  
A. Grone ◽  
S. Kapphan
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