Physical and Numerical Modeling of the Slag Splashing Process

The influence of technological factors on the process of slag splashing was analyzed in the paper. The problems were solved in several stages using our own and commercial calculation programs and laboratory tests. Based on the performed calculations and simulations, factors affecting the slag splashing were determined. It was observed that the high efficiency of the process can be achieved by optimizing numerous technological parameters, e.g., flow parameters, pressure, and temperature of the nitrogen stream, height and angle of the lance position, as well as slag height into which the gas stream enters and MgO consumption. In addition, the chemical and mineralogical composition of the slag and its physicochemical parameters should be also considered. The obtained results of numerical simulations of slag splashing in the oxygen converter coincide with the results of experiments carried out using the physical model of oxygen converter. This means that the simulations well represent the real course of the slag splashing process for the studied variants.

Dephosphorization mechanism and phase change in the reduction of converter slag

In the steelmaking process, the remained converter slag with P-containing materials is harmful to the molten steel in the next furnace. By the slag-splashing process with air blowing, P in the molten slag can be reduced and separated from the slag in the form of gas. In this paper, the reduction experiments of converter slag were carried out by flowing N2 at high temperatures, and the P-containing gas formed in this process was cooled and collected in water. It is found that the P gas was mainly composed of P2, which matched well with the results predicted by the FactSage7.2 calculation. The reaction mechanism of gasification dephosphorization in molten slag was analyzed, which was mainly proceeded on the surface of the slag. SEM-EDS and XRD were used to detect and characterize the samples. The ore phase of the converter slag and the gasification dephosphorization slag was determined, and the phase change was analyzed and compared.

Fundamental Research on Gasification Dephosphorization with Coke Powder Reducing Converter Molten Slag

In order to realize the gasification dephosphorization process in converter slag splashing stage for avoiding the P enrichment, and the dephosphorized slag can be left for recycling in subsequent furnaces. The experiment of reduction of converter slag by coke powder in laboratory was carried out, The results show that with the increase of the experimental temperature, the gasification dephosphorization rate of coke powder gradually increases, and the gasification dephosphorization rate reaches up to 82.35% at 1900K. The gasification dephosphorization rate decreases with the increase of slag basicity. When the coke powder is added in a sufficient amount, increasing properly the FeO content of slag is favorable for the gasification dephosphorization reaction; when the coke particle size is between 0.5 and 2.5 mm, the gasification dephosphorization rate changed little, about 58%, but when the coke particle size between 2.5 and 3.5mm, the gasification dephosphorization rate dropped to 52%. The results provide some theoretical guidance for industrial development.

The investigation of the converter slag's phase and mineralogical properties in splashing to improve the lining resistance

The methods to improve the slag splashing operation were regarded in the article. The phase and mineralogical properties were studied for the converter slag's of one of the Europe Iron and Steel Works. The modeling results for the slags with different compositions are given on base of the earlier studies of the physical and chemical properties.Ill.8. Ref. 28. Tab.1.