Natural and anthropogenic impacts reflected by paleoclimate proxy parameters in a lake-forest system in Bukovina, Romania

The research area is located in the Eastern Carpathians, Romania. This region is rich in various formations and indicates significant potential for paleo-environmental reconstruction. The present research was carried out on sediment cores collected at lake Bolătău-Feredeu, Feredeului Mountains (Eastern Carpathians, Romania). Preliminary examination of the sediment confirmed the possibility for data analysis with high temporal resolution. The aim of the research was to clarify and supplement the findings of previous research at this site, to explore the relationships between proxy parameters and to elucidate the cause for the changes. Core dating was carried out using 210Pb and radiocarbon isotopes and indicated that sediment cores span the past 500 years. The research uses a wide range of methodologies, including organic geochemistry with calculated n alkane indices (Phw and Pwax). Based on these proxies, the changes of woody and herbaceous coverage in the catchment can be estimated. Moreover, element concentration, weathering indices and particle size distribution assist to detect climate changes in the catchment area. The data and conclusions yielded by the analysis were compared with the regional modelled temperature profile, based on which five periods were separated. In addition to natural and anthropogenic events, the main factor among the natural processes is the change in annual temperature. Based on the obtained data, several parameters were found to be suitable for monitoring past temperature changes.

GEMAS: Adaptation of weathering indices for European agricultural soil derived from carbonate parent materials

Carbonate rocks are very soluble and export elements in dissolved form, and precipitation of secondary phases can occur at a large scale. They leave a strong chemical signature in soil that can be quantified and classified by geochemical indices, which are useful for evaluating chemical weathering trends (e.g., the Chemical Index of Alteration CIA or the Mafic Index of Alteration MIA). Due to contrasting chemical compositions and high Ca content, a special adaptation of classical weathering indices is necessary to interpret weathering trends in carbonate-derived soil. In fact, this adaptation seems to be a good tool for distinguishing weathering grades of source rock types at the continental-scale, and allows a more robust interpretation of soil parent material weathering grade and its impact on the current chemical composition of soil. Increasing degree of weathering results in Al enrichment and Mg loss in addition to Fe loss and Si enrichment, leaching of mobile cations such as Ca and Na and precipitation of Fe-oxides and hydroxides. Relation between soil weathering status and its spatial distribution in Europe provides important information on the role played by climate and terrain. Geographical distribution of soil chemistry contributes to a better understanding of soil nutritional status, element enrichment, degradation mechanisms, desertification, soil erosion and contamination.

Geochemical Maturity and Paleo-Weathering Indices of Sedimentary Succession in JV Field Greater Ughelli Depo-Belt Niger Delta Basin

This study evaluates the geochemical maturity and paleo weathering indices of X well JV-Field, Greater UghelliDepo belt Niger Delta Basin, using reflected light microscope and geochemical proxies. The data obtained identified three lithofacies units as Sand, Shale, and Shaly sand facies .The application of source area weathering using Chemical index of alteration (CIA) and Chemical index of weathering (CIW) values for the sampled intervals ranges from (48.6-94.9%) and (60.6-96.7%), and have median values of (83.2 and 90.3) % respectively which is an indication of high weathering at the source. The values are variable and it may be as a result of multiple provenances of the sediments which have variable proportions of source area weathering and related processes or may be due to low concentrations of the alkalis and alkaline earth elements. However, all the samples excluding one with depth (12430ft) show CIA and CIW values greater than 70% indicating high (intensive) weathering either at the source or during transportation before deposition .From the high alteration indices value recorded from the sampled intervals, it can be inferred that the sediments are geochemically and texturally mature.

Geochemistry and Weathering Indices of Yedoma and Alas Deposits beneath Thermokarst Lakes in Central Yakutia

Ice- and organic-rich deposits of late Pleistocene age, known as Yedoma Ice Complex (IC), are widespread across large permafrost regions in Northeast Siberia. To reconstruct Yedoma IC formation in Central Yakutia, we analyzed the geochemistry, sedimentology, and stratigraphy of thawed and frozen deposits below two thermokarst lakes in different evolutionary stages (a mature alas lake and a initial Yedoma lake) from the Yukechi site in the Lena-Aldan interfluve. We focused on inorganic geochemical characteristics and mineral weathering in two ∼17 m long sediment cores to trace syngenetic permafrost aggradation and degradation over time. Geochemical properties, element ratios, and specific weathering indices reflect varying sedimentation processes and seasonal thaw depths under variable environmental conditions. Deeper thaw during the interstadial Marine Isotope Stage (MIS) 3 enabled increasing mineral weathering and initial thermokarst processes. Sedimentological proxies reflect high transport energy and short transport paths and mainly terrestrial sediment supply. The Yedoma formation resulted from fluvial, alluvial and aeolian processes. Low mean TOC contents in both cores contrast with Yedoma deposits elsewhere. Likely, this is a result of the very low organic matter content of the source material of the Yukechi Yedoma. Pronounced cryostructures and strongly depleted pore water stable isotopes show a perennially frozen state and preserved organic matter for the lower part of the Yedoma lake core, while changing permafrost conditions, conditions promoting weathering, and strong organic matter decomposition are suggested by our proxies for its middle and upper parts. For the alas lake core, less depleted water stable isotopes reflect the influence of recent precipitation, i.e. the infiltration of rain and lake water into the unfrozen ground. The FENG, MIA(R), and ICV weathering indices have proven to be promising proxies for the identification of conditions that promote mineral weathering to different degrees in the stratigraphy of the thawed and frozen Yedoma deposits, for which we assume a rather homogeneous chemical composition of the parent material. Our study highlights that the understanding of environmental conditions during Yedoma formation and degradation processes by specific geochemical proxies is crucial for assessing the potential decomposition and preservation of the frozen and unfrozen Yedoma inventories.

Major element geochemistry of European agricultural soil: weathering processes of silicate parent materials

<p>Collection of agricultural soil samples in Europe (0–20 cm, 33 countries, 5.6 million km<sup>2</sup>) during the GEMAS (GEochemical Mapping of Agricultural and grazing land Soil) continental-scale project allowed the study of geochemical behaviour of major elements during weathering (SiO<sub>2</sub>, TiO<sub>2</sub>, Al<sub>2</sub>O<sub>3</sub>, Fe<sub>2</sub>O<sub>3</sub>, MgO, CaO, Na<sub>2</sub>O, K<sub>2</sub>O, P<sub>2</sub>O<sub>5</sub>) using their total concentrations (XRF data). The chemical composition of soil represents to a large extent the primary mineralogy of the source bedrock, the effects of pre- and post-depositional weathering and element mobility, either by leaching or mineral sorting with the addition of formation of secondary products such as clays.</p><p>Bulk geochemistry is used to calculate a set of weathering indices such as chemical index of alteration CIA, reductive and oxidative mafic index of alteration MIA, the change in mass balance t (calculation relative to immobile Nb) for soil derived from silicate parent materials defined as granite, gneiss and schist at the European continental-scale. Silicate minerals of soil parent materials can be either very resistant to weathering or very soluble and export of elements in dissolved form and precipitation of secondary phases can occur at a large scale. Either way, they leave a strong chemical signature in derived soil, which can be quantified and classified with help of geochemical indices that are useful tools to evaluate chemical weathering trends. Weathering indices and gain-loss mass transfer coefficients were applied to agricultural soil to provide an insight into the weathering processes affecting three silicate parent rocks and their impact on soil development at the European scale. Distinct chemical composition and weathering patterns has been evidenced in silicate derived soil. The interpretation of geographical distribution of soil types with silicate substrate allows better understanding of soil nutritional status, metal enrichments, degradation mechanisms under various climate conditions.</p>