The absorption spectra of monohydroxybenzene (Fen), 1,3-dihydroxybenzene
(Rez), 1,4-dihydroxybenzene (Hi), 1,2,3-trihydroxybenzene (Pg) and
1,3,5-trihydroxy-benzene (Fg) in aqueous solutions of hydrochloric acid
with different values of the Hammett acidity function(H0) have two
absorption bands in the region between 190-220 nm and 260-290 nm. This
behavior is similar in another mineral acids (H2SO4, H3PO4, HClO4). The
absorbance decreases with increasing of acidity (with decreasing of H0
values) because of O-protonation. The absorption maxima shift to longer
wave-lengths, and the graphic dependence of the absorption of the second
band as a function of H0 gives characteristic S-curves. These curves show
the different effect of the acid on the form the protonation of the
investigated hydroxybenzenes. The potonation constants of the
hydroxybenzenes were calculated: pKFen=-1.95; pKRez=-2.40; pKHi= -1.93;
pKPg=-2.95; pKFg=-1.83.