Crystallization Conditions and Petrogenetic Characterization of Metaluminous to Peraluminous Calc-Alkaline Orogenic Granitoids from Mineralogical Systematics: The Case of the Cambrian Magmatism from the Sierra de Guasayán (Argentina)

The Sierra de Guasayán (Eastern Sierras Pampeanas, Argentina) is formed by low to medium grade metamorphic rocks intruded by Cambrian metaluminous (La Soledad quartz-diorite), slightly peraluminous (Guasayán, El Escondido and El Martirizado granodiorite plutons), and strongly peraluminous (Alto Bello granodiorite) granitoids of the Pampean magmatic arc. Chemical compositions of amphibole, plagioclase, biotite, and titanite indicate that these granitoids were emplaced at low pressure (mostly <3 kbar) and temperature (<770 °C) under oxidizing conditions (QFM + 1 and QFM + 2), which are similar to the emplacement conditions reported for other granites of the Pampean magmatic arc. Mineral assemblages and whole-rock and mineral chemistry of the granitoids from the Sierra de Guasayán indicate an I-type affinity for the La Soledad quartz-diorite (amphibole, biotite, and titanite), S-type affinity for the Alto Bello granodiorite (biotite, muscovite, cordierite, and sillimanite), and a hybrid nature for the main Guasayán and El Escondido plutons (biotite, monazite, and magnetite). This hybrid nature is supported by the presence of abundant mafic microgranular enclaves and rapakivi texture and by published zircon Hf-isotope data (εHfi ranging from −4.76 to −0.12). This suggests, in turn, the involvement of hybridization in the genesis of these granitoids, which seems to be a common mechanism operating in the Pampean magmatic arc.

Exhumation history and landscape evolution of the Sierra de San Luis (Sierras Pampeanas, Argentina) - new insights from low - temperature thermochronological data

This paper presents low-temperature thermochronological data and K‑Ar fault gouge ages from the Sierra de San Luis in the Eastern Sierras Pampeanas in order to constrain its low-temperature thermal evolution and exhumation history. Thermal modelling based on (U-Th)/He dating of apatite and zircon and apatite fission track dating point to the Middle Permian and the Triassic/Early Jurassic as main cooling/exhumation phases, equivalent to ca. 40-50% of the total exhumation recorded by the applied methods. Cooling rates are generally low to moderate, varying between 2-10 °C/Ma during the Permian and Triassic periods and 0.5-1.5 °C/Ma in post-Triassic times. Slow cooling and, thus, persistent residence of samples in partial retention/partial annealing temperature conditions strongly influenced obtained ages. Thermochronological data indicate no significant exhumation after Cretaceous times, suggesting that sampled rocks were already at or near surface by the Cretaceous or even before. As consequence, Cenozoic cooling rates are low, generally between 0.2-0.5 °C/Ma which is, depending on geothermal gradient used for calculation, equivalent to a total Cenozoic exhumation of 0.6-1.8 km. K-Ar fault gouge data reveal long-term brittle fault activity. Fault gouge ages constrain the end of ductile and onset of brittle deformation in the Sierra de San Luis to the Late Carboniferous/Early Permian. Youngest K-Ar illite ages of 222-172 Ma are interpreted to represent the last illite formation event, although fault activity is recorded up to the Holocene.