Comprehensive Assessment and Potential Ecological Risk of Trace Element Pollution (As, Ni, Co and Cr) in Aquatic Environmental Samples from an Industrialized Area

A global assessment of arsenic (As), nickel (Ni), cobalt (Co) and chromium (Cr) was performed in environmental samples from an important industrial bay. Different fractions of water, sediments and tissues from four species of fish were analysed. Samples were collected from selected sampling sites during four consecutive samplings in spring and autumn seasons, in order to evaluate concentrations and their possible correlations among the aquatic compartments. While a higher availability of Cr and Ni was found in water, Co and As were the most available elements in sediments. In fish, the liver was the tissue with the highest proportion of As and Co, and gills showed the highest concentrations of Ni and Cr. Significance differences were observed among sites showing the pollution sources. In sediments, high correlations were found between total Co content and the most available fractions. Total Ni content highly correlated with the oxidisable fraction, while Cr total content tightly correlated with the least available fractions. Quality guideline values for sediments were frequently exceeded. In sediments and biota, concentrations were slightly higher than in other ecosystems, indicating that maritime, industrial and urban activities are affecting this type of ecosystem with great anthropogenic influence.

Assessment of trace element accumulation on the Tunisian coasts using biochemical biomarkers in Perinereis cultrifera

Our study aimed to evaluate the effect of trace element pollution in the polychaete Perinereis cultrifera (Grube, 1840) from two Tunisian coasts (the port of Rades, S1; and the Punic port of Carthage, S2). To this end, we used an approach based on proximate composition, biomarker responses and trace element bioaccumulation. Our results showed a decreasing order of metals concentrations (Zn>Cu>Cd>Pb) in P. cultrifera from S1 and S2. The accumulation of Cd, Cu and Zn was significantly higher in S1 than in S2, especially in summer. Lipid, protein and glycogen content also changed significantly between S1 and S2 in relation to trace metal accumulation and environmental conditions. The results revealed a higher level of thiobarbituric acid in P. cultrifera from S1 than from S2. In addition, the enzymatic and non-enzymatic antioxidant defence system (catalase, glutathione-S-transferase, superoxide dismutase, glutathione and metallothionein) was enhanced and acetylcholinesterase activities decreased in P. cultrifera in S1 in comparison with S2. A principal component analysis showed that P. cultrifera from S1 exhibited a clear disruption of oxidative stress responses and trace element bioaccumulation among seasons. Overall, these findings revealed the sensitivity of those organisms to environmental conditions.

Trace Elements in Groundwater of Chrompet Industrial area of Tamil Nadu

The concentrations of the trace elements Fe, Cu, Pb, Mn, Zn were studied in groundwater of Chrompet Industrial area of Tamil Nadu. The degree of trace element pollution and the suitability of groundwater for drinking purpose was assessed. The concentration of Pb found to be present above maximum permissible limit. More than permissible limit of Fe was found around the industrial area. The concentrations of Zn, Cu and Mn are well below the maximum permissible limit as recommended by ISI (1983) for drinking purpose

Trace-element behaviour in sediments of Ugandan part of Lake Victoria: results from sequential extraction and chemometrical evaluation

Lake Victoria is the second largest freshwater lake and the largest tropical lake in the world. The transboundary lake has the fastest growing population in its catchment, which can impact the water and sediment quality. To determine the extent of anthropogenic effects on sediment quality in the Ugandan part of Lake Victoria, the contents and binding behaviour of trace elements were analysed, as well as organic matter and phosphorus in different sediment layers of both deep and coastal sediments near the coastal cities of Entebbe, Kampala and Jinja. The data were assessed using the German LAWA criteria for trace-element pollution, the Geo-Index, Cluster- and Factor analyses. Mostly, no critical trace-element contamination in the sediments of the investigated area was observed. However, changes in element distributions caused by anthropogenic influences from around the lake were detected, like higher contents of Cu, Ti and V in near shore sediments with urban surrounding. Near Jinja, industrial wastewaters caused particularly elevated contents of Cu in the sediments (70–121 mg/kg, 3.5–6 times the geogenic background), exceeding the LAWA criteria and potentially harming the aquatic habitat. In addition, temporally growing organic matter contents in the lake sediments near the estuary of River Nzoia (from 4.2 to 17.6% in around 60 years) due to increased soil erosion in the river’s catchment area and blooms of the water hyacinth became visible. This study demonstrates that the whole catchment area is responsible to ensure a healthy aquatic ecosystem in Lake Victoria.

Geochemistry, spatial distribution, and sources of trace element pollution in the surface sediments of Port Hacking, southern Sydney, Australia

Coastal environments are subject to trace metal pollution via a combination of industry and urbanised sources. The pollutants accumulate within surface sediments, especially in the quieter backwaters of estuaries. An environmental assessment of the Port Hacking estuary, southern Sydney, Australia, was undertaken using 233 surface samples. Trace metal concentrations (Ni, Cr, Cu, Zn, Pb, and As) in these samples indicated that most elements in Port Hacking were below the relevant ANZECC/ARMCANZ guideline low trigger value (ISQG-low), but a few sites exceeded this value. The low trace metal concentrations are mainly because the catchment areas have limited urban development and few discharge points. In contrast, one site in Gunnamatta Bay has Zn and Cu concentrations that exceeded the high trigger value (ISQG-high), due to moored vessels, boatyards, and stormwater outlets in this vicinity. Port Hacking is considered to be relatively unpolluted and healthy when compared with other Sydney estuaries.