agostic interaction Latest Research Papers

Electronic and Steric Manipulation of the Agostic Interaction in benzo[h ]quinoline Complexes of Pd(II) and Implications for the Formation of η1 -Pd-C Bonds

European Journal of Inorganic Chemistry ◽

10.1002/ejic.202000348 ◽

2020 ◽

Vol 2020 (27) ◽

pp. 2639-2650

Author(s):

Alastair J. Nielson ◽

John A. Harrison ◽

M. Arif Sajjad ◽

Peter Schwerdtfeger

Keyword(s):

Agostic Interaction

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Theoretical Study on Adjacent Agostic Interaction in Ruthenium Complexes

Journal of Computer Chemistry Japan ◽

10.2477/jccj.2019-0019 ◽

2019 ◽

Vol 18 (3) ◽

pp. 162-163

Author(s):

Sahoko OHASHI ◽

Satomi YAMANAKA ◽

Keiko TAKANO

Keyword(s):

Theoretical Study ◽

Ruthenium Complexes ◽

Agostic Interaction

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Origin of β-agostic interaction in d0 transition metal alkyl complexes: Influence of ligands

Journal of Organometallic Chemistry ◽

10.1016/j.jorganchem.2018.01.048 ◽

2018 ◽

Vol 865 ◽

pp. 37-44 ◽

Cited By ~ 6

Author(s):

Shyama Ramakrishnan ◽

Eluvathingal D. Jemmis

Keyword(s):

Transition Metal ◽

Alkyl Complexes ◽

Agostic Interaction

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Spontaneous Bicyclometalation of a Single Cobalt(I) Complex Stabilized by a δ-C-H Agostic Interaction

European Journal of Inorganic Chemistry ◽

10.1002/ejic.201701221 ◽

2018 ◽

Vol 2018 (5) ◽

pp. 608-611 ◽

Cited By ~ 2

Author(s):

Robert Beck ◽

Sebnem Camadanli ◽

Hans-Friedrich Klein

Keyword(s):

Agostic Interaction

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Computational studies on the Rh-catalyzed carboxylation of a C(sp2)–H bond using CO2

Catalysis Science & Technology ◽

10.1039/c7cy01163f ◽

2017 ◽

Vol 7 (16) ◽

pp. 3539-3545 ◽

Cited By ~ 9

Author(s):

Xiangying Lv ◽

Linhui Zhang ◽

Beibei Sun ◽

Zhi Li ◽

Yan-Bo Wu ◽

...

Keyword(s):

Lewis Acid ◽

Computational Studies ◽

Agostic Interaction

CO2 insertion is facilitated by the critical effects of a Lewis acid and an agostic interaction.

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Chasing the agostic interaction in ligand assisted cyclometallation reactions of palladium(ii)

Dalton Transactions ◽

10.1039/c7dt03525j ◽

2017 ◽

Vol 46 (46) ◽

pp. 16126-16138 ◽

Cited By ~ 12

Author(s):

M. Arif Sajjad ◽

Kirsten E. Christensen ◽

Nicholas H. Rees ◽

Peter Schwerdtfeger ◽

John A. Harrison ◽

...

Keyword(s):

Nmr Spectroscopy ◽

Electron Density ◽

Aromatic Ring ◽

Agostic Interaction

Computations show that a possible aromatic ring agostic intermediate seen by NMR spectroscopy in a cyclometallation reaction by palladium(ii) can involve CCπ electron density close to the agostic carbon being donated to the metal.

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Investigation of agostic interaction through NBO analysis and its impact on β-hydride elimination and dehydrogenation: a DFT approach

Theoretical Chemistry Accounts ◽

10.1007/s00214-016-1939-0 ◽

2016 ◽

Vol 135 (7) ◽

Cited By ~ 3

Author(s):

Tanay Debnath ◽

Tamalika Ash ◽

Tahamida Banu ◽

Abhijit K. Das

Keyword(s):

Nbo Analysis ◽

Agostic Interaction ◽

Hydride Elimination

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η4-HBCC-σ,π-Borataallyl Complexes of Ruthenium Comprising an Agostic Interaction

Chemistry - A European Journal ◽

10.1002/chem.201600181 ◽

2016 ◽

Vol 22 (23) ◽

pp. 7871-7878 ◽

Cited By ~ 19

Author(s):

Koushik Saha ◽

Benson Joseph ◽

Rongala Ramalakshmi ◽

R. S. Anju ◽

Babu Varghese ◽

...

Keyword(s):

Agostic Interaction

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