Age, chemistry, and tectonic setting of Miramichi terrane (Early Paleozoic) volcanic rocks, eastern and east-central Maine, USA

Volcanic rocks in the Miramichi inlier in Maine occur in two areas separated by the Bottle Lake plutonic complex: the Danforth segment (Stetson Mountain Formation) north of the complex and Greenfield segment to the south (Olamon Stream Formation). Both suites are dominantly pyroclastic, with abundant andesite, dacite, and rhyolite tuffs and subordinate lavas, breccias, and agglomerates. Rare basaltic tuffs and a small area of basaltic tuffs, agglomerates, and lavas are restricted to the Greenfield segment. U–Pb zircon geochronology dates Greenfield segment volcanism at ca. 469 Ma, the Floian–Dapingian boundary between the Lower and Middle Ordovician. Chemical analyses reveal a calc-alkaline suite erupted in a continental volcanic arc, either the Meductic or earliest Balmoral phase of Popelogan arc activity. The Maine Miramichi volcanic rocks are most likely correlative with the Meductic Group volcanic suite in west-central New Brunswick. Orogen-parallel lithologic and chemical variations from New Brunswick to east-central Maine may result from eruptions at different volcanic centers. The bimodal Poplar Mountain volcanic suite at the Maine–New Brunswick border is 10–20 myr younger than the Miramichi volcanic rocks and more likely an early phase of back-arc basin rifting than a late-stage Meductic phase event. Coeval calc-alkaline arc volcanism in the Miramichi, Weeksboro–Lunksoos Lake, and Munsungun Cambrian–Ordovician inliers in Maine is not consistent with tectonic models involving northwestward migration of arc volcanism. This >150 km span cannot be explained by a single east-facing subduction zone, suggesting more than one subduction zone/arc complex in the region.

Petrographic Characteristics and Geochemistry of Volcanic Rocks in the Kyaukmyet Prospect, Monywa District, Central Myanmar

The Kyaukmyet prospect lies approximately 5 km ENE of the highsulfidation Kyisintaung copper-gold deposit, Monywa district, central Myanmar. Geologically, the research area is remarked by magmatic extrusion that occurred during the Late Oligocene to Middle Miocene of Magyigon Formation which led to the outcrops of volcanic rocks. Study detailed on petrographical and geochemical of the Kyaukmyet volcanic rocks has not been performed before the present work. The principal aim of this paper is to document the petrographical and geochemical characteristics of volcanic suite rocks exposed in the Kyaukmyet prospect. The results of this data have provided insight into the origin of the rocks and petrogenetic processes during evolution. Petrographically, all the studied volcanic rocks in the research area show that trachytic and porphyritic textures with phenocrysts of quartz, plagioclase, and K-feldspar which are embedded in a fine to medium grained groundmass. The accessory minerals of this rock consist of biotite, chlorite and opaque mineral.Geochemically, these volcanic rocks having calc-alkaline nature and classified as volcanic field (rhyolite) as well as volcanic arc setting. Based on the chondrite normalized spider diagram, LREE has enriched to HREE in this area which indicated negative Eu anomaly and subduction tectonic setting.

Geochemistry of mid- upper eocene intra-continental alkaline volcanic range, south part of central alborz mountains, north of Iran.

The Ziaran volcanic Belt (ZVB), North of Iran contains a number of intra-continental alkaline volcanic range situated on South part of central Alborz Mountains, formed along the localized extensional basins developed in relation with the compressional regime of Eocene. The mid-upper Eocene volcanic suite comprises the extracted melt products of adiabatic decompression melting of the mantle that are represented by small volume intra-continental plate volcanic rocks of alkaline volcanism and their evaluated Rocks with compositions representative of mantle-derived, primary (or near-primary) melts. Trace element patterns with significant enrichment in LILE, HFSE and REEs, relative to Primitive Mantle. Chondrite-normalized of rare earth elements and enrichment in incompatible elements and their element ratios (e. g. LREE/HREE, MREE/HREE, LREE/MREE) shown these element modelling indicates that the magmas were generated by comparably variable degrees of partial melting of garnet lherzolite and a heterogeneous asthenospheric, OIB mantle sources.

Copper-Gold Fertility of Arc Volcanic Rocks: A Case Study from the Early Permian Lizzie Creek Volcanic Group, NE Queensland, Australia

The Early Permian Lizzie Creek Volcanic Group of the northern Bowen Basin, NE Queensland, Australia, has compositions that range from basalt through andesite to rhyolite with geochemical signatures (e.g., enrichment in Cs, Rb, Ba, U, Th, and Pb, depletion in Nb and Ta) that are typical of arc lavas. In the Mount Carlton district the Lizzie Creek Volcanic Group is host to high-sulfidation epithermal Cu-Au-Ag mineralization, whereas farther to the south near Collinsville (~50 km from Mount Carlton) these volcanic sequences are barren of magmatic-related mineralization. Here, we assess whether geochemical indicators of magma fertility (e.g., Sr/Y, La/Yb, V/Sc) can be applied to volcanic rocks through study of coeval volcanic sequences from these two locations. The two volcanic suites share similar petrographic and major element geochemical characteristics, and both have undergone appreciable hydrothermal alteration during, or after, emplacement. Nevertheless, the two suites have distinct differences in alteration-immobile trace element (V, Sc, Zr, Ti, REE, Y) concentrations. The unmineralized suite has relatively low V/Sc and La/Yb, particularly in the high SiO2 rocks, which is related to magma evolution dominated by fractionation of clinopyroxene, plagioclase, and magnetite. By contrast, the mineralized suite has relatively high V/Sc but includes high SiO2 rocks with depleted HREE and Y contents, and hence high La/Yb. These trends are interpreted to reflect magma evolution under high magmatic H2O conditions leading to enhanced amphibole crystallization and suppressed plagioclase and magnetite crystallization. These rocks have somewhat elevated Sr/Y compared to the unmineralized suite, but as Sr is likely affected by hydrothermal mobility, Sr/Y is not considered to be a reliable indicator of magmatic conditions. Our data show that geochemical proxies such as V/Sc and La/Yb that are used to assess Cu-Au fertility of porphyry intrusions can also be applied to cogenetic volcanic sequences, provided elemental trends with fractionation can be assessed for a volcanic suite. These geochemical tools may aid regional-scale exploration for Cu-Au mineralization in convergent margin terranes, especially in areas that have undergone limited exhumation or where epithermal and porphyry mineralization may be buried beneath cogenetic volcanic successions.

Mid-ocean-ridge rhyolite (MORR) eruptions on the East Pacific Rise lack the fizz to pop

Eruptions on the Alarcon Rise segment of the northern East Pacific Rise (23.55°N, 108.42°W) at 2500–2200 m below sea level (mbsl) produced the most compositionally diverse volcanic suite found along the submarine mid-ocean-ridge (MOR) system, offering an opportunity to compare mafic through silicic eruption styles at the same abyssal depth. Eruption styles that formed evolved volcanic rocks on the submarine MOR have not been studied in detail. The prevalence of lava flows along the MOR indicates that most eruptions are nonexplosive, but some volcaniclastic characteristics suggest that explosive styles also occur. Higher viscosities in intermediate (103–5 Pa·s) versus mafic (101 Pa·s) lavas on Alarcon Rise correspond with larger, more brecciated pillows, while highly viscous rhyolite lavas (106–7 Pa·s) formed rugged domes mostly composed of autoclastic breccia. Although high H2O contents (1.5–2.1 wt%), abundant volcaniclasts, and vesicularities up to 53% in rhyolite might imply eruption explosivity, limited fine-grained ash production and dispersal indicate an effusive origin. Higher viscosities of MOR rhyolite (MORR) magma and small eruption volumes, compared to MOR basalt (MORB), limit bubble coalescence and rapid magma ascent, two likely prerequisites for deep-marine eruption explosivity. This idea is supported by widespread dispersal of basaltic ash, but very limited production and dispersal of silicic ash on Alarcon Rise.

Isolated alkaline basalt occurrences in the northern Spessart, Germany: Outposts of the Early Miocene Vogelsberg shield volcano?

Four isolated occurrences of Tertiary volcanic rocks in the northern Spessart at Beilstein, Hoher Berg, Madstein and Kasselgrund are relics of volcanic vents or dikes. They display alkaline basalts (s. l.) with mainly trachybasaltic composition, which, from normative mineral contents, may be designated as nepheline-bearing alkali-olivine basalts and basanites. In part, centimetre-sized xenoliths of spinel lherzolite occur. According to Ar-Ar dating, the alkaline basalts (s. l.) from Kasselgrund have erupted at 18.1 ± 0.3 or 19.3 ± 0.4 Ma, those of Hoher Berg between c. 18 and c. 21 Ma. These ages correspond to the Vogelsberg eruption stage I. A slightly younger Ar-Ar age of 16.8 ± 0.3 Ma was recorded for the Beilstein basalt, which is in chronological accordance to the turn of Vogelsberg eruption stages II and III. Samples of all four occurrences reveal major and trace element compositions, which are different from those of the Vogelsberg basalts. Compositions of basalts of the stage III from Vogelsberg coincide most with the Spessart basalts. This signals a special position of the northern Spessart volcanic rocks either as a discrete spatial part of the Vogelsberg volcanic suite or as smaller, independent eruption centres.

Late Cretaceous – early Paleogene tectonic evolution of the Central Pamir inferred from the geochemical features of the Bartang volcanics

<p>The Pamir orogen in Central Asia has formed by the amalgamation of several Gondwana-derived terranes and their accretion to the southern Eurasian margin in the Mesozoic. Later on, the crust of the Pamir orogen was strongly deformed and uplifted as a result of the Cenozoic India-Asia collision. The deformation of the Pamir orogen, which resulted in shortening, crustal thickening and exhumation of deep crustal rocks within the gneiss domes of the Central and Southern Pamir makes the area an ideal site for studying the India-Asia collision and its paleogeographic and climatic effects. To account for today’s 70-km-thick crust of the Pamir orogen and more than 400 km of convergence accommodated in the Pamir, pre- and syn-collisional processes have been proposed including, continental subduction, delamination, extrusion and oroclinal bending of the Pamir arc. However, testing these models requires constraints on the pre-collisional state of the Pamir lithosphere and its tectono-magmatic evolution. During most of the Cretaceous, the southern Pamir terrane was a site of a widespread arc-related magmatism, which resulted in the formation of many plutons and a volcanic suite of intermediate to acidic composition, whereas the central Pamir terrane lacked any sign of magmatic activity. However, in the late Cretaceous to early Paleogene (78 – 61 Ma) a less widespread magmatic activity in the western part of the Central Pamir resulted in the formation of the Bartang mafic to intermediate volcanic and volcaniclastic rocks. We report here the geochemical and Sr-Nd isotopic features of the late Cretaceous – early Paleogene Bartang volcanics. This volcanic suite bears geochemical and radiogenic isotope features that differ from the arc-related southern Pamir igneous rocks. Mafic basalts that comprise the lowest portion of the section exhibit MORB-like pattern with slightly depleted light rare earth elements (LREE) and large ion lithophile elements (LILE). Further up in the section this pattern shifts towards an arc-related pattern with enriched LREE and LILE. The 87Sr/86Sr<sub>i</sub> isotope ratios are lower (0.705335 – 0.706693) than those from the southern Pamir igneous rocks (0.706915 – 0.711105) and epsilon Nd values exhibit ratios close to mantle domain, ranging between -0.7 and -2.7, with the lower part of the section showing less negative values then the upper. In contrast to the Bartang volcanics, the southern Pamir igneous rocks exhibit more negative epsilon Nd values (from -4.7 to -13). The relatively low initial 87Sr/86Sr isotope ratios and slightly negative epsilon Nd values of the Bartang volcanic rocks together with the trace elements pattern that shifts from MORB-like to arc-related indicate mixing of two magmas derived from depleted and enriched mantle sources, with the latter inheriting the arc-related pattern from the subduction stage. Alternatively, the arc-related pattern could be derived through contamination of the primary magma by the crustal material. These features, compared to the southern Pamir arc-related igneous rocks, also indicate that the tectonic setting in the Pamir changed during the late Cretaceous from a continental arc to a within-plate extensional setting.</p>