Dielectric properties of bionano-composites modified by fish scales

The presented work presents the results of studying the temperature dependences of the dielectric constant and the tangent of the dielectric loss angle of biocomposites modified with fish scales. It was found that with an increase in the volumetric content of the bio-filler, the dielectric constant of the biocomposites increases, and the tangent of the dielectric loss angle decreases. By varying the volumetric content of the bio-filler, it is possible to control the properties of biocomposites in the desired direction.

Determination of Transformer Oil Quality Parameters by its Color Coordinates

The service life of transformers and, as a consequence, of the electric power systems depends largely on the chemical composition and electrical insulating properties of the oil. In this regard, much attention is paid to the control of physical and chemical indicators and operational properties of transformer oils. The aim of this work is to determine the important diagnostic parameters such as the acid number and the tangent of the dielectric loss angle of the transformer oil based on the measured coordinates of the color of the transformer oil. This goal is achieved by the study of the coordinates of the transformer oils chromaticity. For this purpose, a white light source is used, which is a LED with a pumping line of 450 nm and a maximum radiation in the region of 550-560 nm, with radiation in the range from 400 to 800 nm. Sensors 1, 2, 3 allow determining the chromaticity coordinates of the measured source R, G, B (red, green, blue), due to several receivers having spectral characteristics of sensitivity in the corresponding region of the visible spectrum. The most significant result of the work was the establishment of correlations between the TM chromaticity coordinatesб their acid number and the tangent of the dielectric loss angle of TM. The significance of the results obtained was that the acid number and the tangent of the dielectric loss angle of the transformer oil could be determined by the chromaticity coordinates, and hence, by the color of the oil.

Synthesis of constructive-technological decisions of regulation of working capacitance of cables of industrial networks

Introduction. Over the past 10 years, the number of industrial networks has more than doubled. At the physical level, all industrial technology networks are based on twisted pair. Purpose. Synthesis of constructive-technological decisions of regulation of electric capacitance of the insulated conductor at a stage of manufacturing of twisted pair of cables of industrial networks. Methodology. The method of secondary charges to determine the capacitance of the insulated conductor by varying the thickness of the solid and foamed polyethylene insulation. Practical value. Effective regulation is provided on the basis of the obtained dependencies of the effective dielectric constant, the tangent of the dielectric loss angle and the capacitance of the insulated conductor on the degree of foaming and the thickness of the protective film of two-layer insulation. At a degree of porosity of 40 %, the dielectric constant decreases by 25 %, the tangent of the dielectric loss angle – by 33 %, the electrical capacitance of the insulated conductor – by 20 %.

Dielectric losses under heat treatment of dispersed media

The purpose of the paper is to study the dependence of dielectric losses of mechanically activated grain crops on example of wheat under heat treatment on temperature and external electric field frequency as well as to examine the effect of particle size of fine grain samples on grain electrophysical characteristics and dielectric losses. Experimental samples of dispersed systems with particle sizes in the range from 50 to 1000 μm are prepared by the method of mechanical activation. The temperature dependence of the dielectric loss angle tangent is measured using the dielectric method over a wide frequency range. The dependence of the dielectric loss angle tangent tgδ of mechanically activated wheat samples with the different degrees of particle dispersion in a wide temperature range from 20°C to 250°C with a heating rate of 0.7 deg/min is studied. It is found out that the external electric field frequency varies in the range from 25 Hz to 106 Hz. Electric capacitance and conductivity are measured using an E7-20 immitance meter and a specially designed measuring cell. Dielectric characteristics are calculated. Experimental data are presented in the form of graphs and diagrams. We have determined the correlation of the tangent of the dielectric loss angle tgδ with the frequency of the external electric field and temperature, which is most characteristic for fine samples. The most finely dispersed samples with a particle size of less than 50 microns are shown to have high electrical activity. Increase in the dielectric permittivity and the tangent of the dielectric loss angle is most noticeable at the frequencies below 100 Hz. The study of dielectric characteristics allows to choose an effective energy-saving drying mode of the crop under study.

Nondestructive method of measurement of laminated plates dielectric parameters

The methods for measuring the parameters of dielectric materials of foil plates have been considered. It has been shown that for “non-destructive measurements” (i.e., without removing the metal foil from the dielectric plate), a method based on the excitation of electromagnetic oscillations in a rectangular plate considered as a resonator can be used. Based on the results of measurements of their resonant frequencies and Q-factors, the relative permittivity and the tangent of the dielectric loss angle of the material can be determined. The calculated relations obtained by the authors of the article in one of the early works using the electrodynamic model of a resonator with “magnetic walls” at the ends have been presented. The Q-factor of the resonator has been calculated by the perturbation method, taking into account the losses in the plate dielectric and metallization layers. The results of measurements for four samples from different dielectrics in the frequency range 200...1000 MHz have been presented. The experimental method has been described, in particular, the method of identifying the type of oscillation, the procedure for processing the measurement results. Due to the high sensitivity of the vector analyzer, measurements have been made with a possible small connection of the resonator (metallized plate) with the measuring circuit. This made it possible to minimize the influence of the coupling elements on the measured Qfactor of the oscillations and to consider this Q-factor close to its own. The presented results are in good agreement with the reference data for the materials. The conducted studies have shown the possibility of using a resonator model with “magnetic walls” at the ends for the analysis of electromagnetic oscillations in a foil dielectric plate and, accordingly, using the relations obtained in this case to determine the parameters of the dielectric plate. The conditions for using this model are the small thickness of the plate in comparison with its transverse dimensions and relatively low operating frequencies. The method, which is based on the calculated ratios of the electrodynamic model of the resonator with “magnetic” walls at the ends, provides a sufficiently high accuracy of determining the relative permittivity of the plate material, which led to the use of it (the method) in practice to control the parameters of foil dielectric plates intended for the manufacture of microwave and UHF-band microcircuits. The studies, the results of which have been presented in this paper, allow us to conclude that this method can also be recommended for determining the tangent of the dielectric loss angle of the plate material.

The molecular mobility of the epoxy binder in a modified composites by electric-hammer

In this work, the study of molecular mobility in the surface layers by the method of determining the dielectric characteristics of materials modified by electrospark hydraulic shock, determined the optimal content of the dispersed filler. Comparative data of the tangent of the dielectric loss angle of treated and untreated composite materials are presented.

The estimation of ship cable condition by the means of measuring its insulation characteristics

Timely detection of defects in electrical equipment and cable network is required for the ensuring the fire safety of a modern marine vessel. The method of continuous monitoring of the resistance value of cable insulation is not very informative and is not applicable for assessing the service life of cables and predicting their replacement during operation and repair. Currently the problem of developing modern non-destructive methods of insulation control is very urgent in order to determine the operability of the cable, search for diagnostic parameters characterizing the state of insulation during prolonged aging, as well as the introduction of traditional methods of diagnostics of electrical equipment that have shown their effectiveness at the facilities of the coastal infrastructure. A promising solution for this problem is a method for monitoring the values of the tangent of the dielectric loss angle tgδ of cable insulation using devices that allow registering parameters with high accuracy. In this study the determination of changes in the parameters of a ship cable subjected to accelerated thermal aging at temperatures 120-130 °C has been made. The tgδ measurements of the cable sheath have been carried out using the Tangent-2000 insulation meter. The tests have shown that aging of cable hose insulation is accompanied by a non-linear change in tgδ; at certain values of the tangent of dielectric loss angle, visible cracks appear indicating the onset of an emergency condition of the cable. The nature of the change in the parameter tgδ is explained by the occurrence of reactions of oxidative dehydrochlorination of polychloroprene in the process of thermal aging of insulation and changes in its mass. Thus, the tangent of the dielectric loss angle can be one of the diagnostic parameters for assessing the state of the insulation of the ship's cable and predicting its service life.

Rubber-ceramic composites applicable in flexible antennas

Glass ceramics from the CaO–P2O5–SiO2 system were synthesized. They were characterized by XRD, SEM and EDX methods. It was found that they contain two crystalline [Whitlockite, Ca3 (PO4)2 and Hydroxylapatite, Ca5 (PO4)3 (OH)] and one residual amorphous phase. The ceramics are composed of porous aggregates of fine particles with predominant macro- and mesopores in it. The ceramics were used as a functional filler in natural rubber based composites, as the filling is in the range of 5–50 phr. The influence of the chemical nature and structure of the ceramics and the degree of filling on the vulcanization characteristics, physicomechanical parameters, dielectric and dynamic properties, the coefficient of thermal conductivity and the volume resistivity, including external pressure or bending on the specimens were investigated. An influence of the filler and the degree of filling on all studied properties was found. All tested composites have dielectric parameters (ε′, real part of complex permittivity; ε′′, imaginary part of complex permittivity; σ, conductivity; tanδɛ, tangent from dielectric loss angle) suitable for use as substrates and insulating layers of flexible antennas. Particularly impressive are composites containing 30 and 50 phr fillers, which have the lowest tangent from dielectric loss angle values.