analogous transition
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Polyhedron ◽  
2020 ◽  
Vol 176 ◽  
pp. 114272 ◽  
Author(s):  
José M. Méndez-Arriaga ◽  
Antonio Rodríguez-Diéguez ◽  
Manuel Sánchez-Moreno

1981 ◽  
Vol 59 (11) ◽  
pp. 1635-1639 ◽  
Author(s):  
W. Goetz ◽  
D. C. Moule ◽  
D. A. Ramsay

The Stark effect on the [Formula: see text] system of H2CS has been investigated. An analysis of the Stark broadening of the lines in the pP3 branch with J″ = 3–8 yields a value of μ′ = −2.2 ± 0.3 D. The large decrease in dipole moment on excitation (μ′ = −3.85 D) is consistent with the large change in dipole moment which has been predicted for the analogous transition in H2CO.


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