The Effect of Excited Species on the Collisional Energy of Argon Inductively Coupled Plasmas: A Global Model Study

Global modeling of inductively coupled plasma (ICP) reactors is a powerful tool to investigate plasma parameters. In this article, the argon ICP global model is revisited to explore the effect of excited species on collisional energy through the study of different approaches to particle and energy balance equations. The collisional energy loss is much more sensitive to modifications in the balance equations than the electron temperature. According to the simulations, the multistep ionization reduces the collisional energy loss in all investigated reaction sets and the inclusion of heavy species reactions has negligible influence. The plasma parameters obtained, such as total energy loss and electron temperature, were compared with experimental results from the literature. The simulated cases that have more excited species and reactions in the energy balance are in better agreement with the experimental measurements.

Vector Resolved Energy Fluxes and Collisional Energy Losses in Magnetic Nozzle Radiofrequency Plasma Thrusters

Energy losses in a magnetic nozzle radiofrequency plasma thruster are investigated to improve the thruster efficiency and are calculated from particle energy losses in fully kinetic simulations. The simulations calculate particle energy fluxes with a vector resolution including the plasma energy lost to the dielectric wall, the plasma beam energy, and the divergent plasma energy in addition to collisional energy losses. As a result, distributions of energy losses in the thruster and the ratios of the energy losses to the input power are obtained. The simulation results show that the plasma energy lost to the dielectric is dramatically suppressed by increasing the magnetic field strength, and the ion beam energy increases instead. In addition, the divergent ion energy and collisional energy losses account for approximately 4%–12% and 30%–40%, respectively, regardless of the magnetic field strength.

The Dynamics of the S(1D)+H2/D2 Reactions at Low Temperature via Statistical Simulations

Two different statistical approaches, the statistical quantum model (SQM) and the mean potential phase space theory (MPPST), have been employed to calculate the integral cross sections for the reactive collisions between S(1D) and H2/ D2 in the low energy regime (below 0.3 eV collisional energy). The rate constant for the S(1D) + H2 → SH + H reaction has been also obtained and compared with previously reported experimental and theoretical results. The good agreement shows the capability of these two methods to study the dynamics of these complex-forming atom-diatom processes in the present energy regime.

Simplified Representation of Multichannel Thermal Unimolecular Reactions. II. Refined Parametrization of Formaldehyde Dissociation

Simplified representations of branching fractions for thermal unimolecular two-channel reactions are discussed. The dissociation of formaldehyde serves as an illustrative example. Quantum-corrected classical trajectory calculations on an ab initio potential energy surface are combined with master equation calculations for collisional energy transfer. The treatment accounts for roaming atom dynamics. The dependence of the channel branching fractions on the bath gas pressure and temperature, on the collision efficiencies, and on the difference of channel threshold energies, are explored. It is discussed to what extent the derived simplified representations of channel branching fractions can be generalized.