Quantifying the Seawater Sulfate Concentration in the Cambrian Ocean

Although the earliest animals might have evolved in certain “sweet spots” in the last 10 million years of Ediacaran (550–541 Ma), the Cambrian explosion requires sufficiently high levels of oxygen (O2) in the atmosphere and diverse habitable niches in the substantively oxygenated seafloor. However, previous studies indicate that the marine redox landscape was temporally oscillatory and spatially heterogeneous, suggesting the decoupling of atmospheric oxygenation and oceanic oxidation. The seawater sulfate concentration is controlled by both the atmospheric O2 level and the marine redox condition, with sulfide oxidation in continents as the major source, and sulfate reduction and pyrite burial as the major sink of seawater sulfate. It is thus important to quantify the sulfate concentration on the eve of the Cambrian explosion. In this study, we measured the pyrite contents and pyrite sulfur isotopes of black shale samples from the Yurtus Formation (Cambrian Series 2) in the Tarim Block, northwestern China. A numerical model is developed to calculate the seawater sulfate concentration using the pyrite content and pyrite sulfur isotope data. We first calibrate some key parameters based on observations from modern marine sediments. Then, the Monte Carlo simulation is applied to reduce the uncertainty raised by loosely confined parameters. Based on the geochemical data from both Tarim and Yangtze blocks, the modeling results indicate the seawater sulfate concentration of 8.9–14 mM, suggesting the seawater sulfate concentration was already 30–50% of the present level (28 mM). High seawater sulfate concentration might be attributed to the enhanced terrestrial sulfate input and widespread ocean oxygenation on the eve of the Cambrian explosion.

Amsassia (calcareous alga) from the Lower Ordovician (Tremadocian) of western Newfoundland, and the biologic affinity and geologic history of the genus

Modular coral-like fossils from Lower Ordovician (Tremadocian) thrombolitic mounds in the St. George Group of western Newfoundland were initially identified as Lichenaria and thought to include the earliest tabulate corals. They are here assigned to Amsassia terranovensis n. sp. and Amsassia? sp. A from the Watts Bight Formation, and A. diversa n. sp. and Amsassia? sp. B from the overlying Boat Harbour Formation. Amsassia terranovensis n. sp. and A. argentina from the Argentine Precordillera are the earliest representatives of the genus. Amsassia is considered to be a calcareous alga, possibly representing an extinct group of green algae. The genus originated and began to disperse in the Tremadocian, during the onset of the Great Ordovician Biodiversification Event, on the southern margin of Laurentia and the Cuyania Terrane. It inhabited small, shallow-marine reefal mounds constructed in association with microbes. The paleogeographic range of Amsassia expanded in the Middle Ordovician (Darriwilian) to include the Sino-Korean Block, as well as Laurentia, and its environmental range expanded to include non-reefal, open- and restricted-marine settings. Amsassia attained its greatest diversity and paleogeographic extent in the Late Ordovician (Sandbian–Katian), during the culmination of the Great Ordovician Biodiversification Event. Its range included the South China Block, Tarim Block, Kazakhstan, and Siberia, as well as the Sino-Korean Block and Laurentia, and its affinity for small microbial mounds continued during that time. In the latest Ordovician (Hirnantian), the diversity of Amsassia was reduced, its distribution was restricted to non-reefal environments in South China, and it finally disappeared during the end-Ordovician mass extinction. UUID: http://zoobank.org/ef0abb69-10a6-46de-8c78-d6ec7de185fe

Analysis of Crustal Movement and Deformation in Mainland China Based on CMONOC Baseline Time Series

In this paper, we propose a method for the analysis of tectonic movement and crustal deformation by using GNSS baseline length change rates or baseline linear strain rates. The method is applied to daily coordinate solutions of continuous GNSS stations of the Crustal Movement Observation Network of China (CMONOC). The results show that: (a) The baseline linear strain rates are uneven in space, which is prominent in the Tianshan, Sichuan-Yunnan, Qinghai-Tibet Plateau, and Yanjing areas, with a maximum value of 1 × 10−7 a−1, and about two orders smaller in the South China block, the Northeast block, and the inner area of the Tarim basin, where the average baseline linear strain rates are 1.471 × 10−9 a−1, 2.242 × 10−9 a−1, and 3.056 × 10−9 a−1, respectively; (b) Active crustal deformation and strong earthquakes in the Xinjiang area are mainly located in the north and south sides of the Tianshan block; the compression deformations both inside the Tarim block and in the southern Tianshan fault zone are all increasing from east to west, and the Tarim block is not a completely “rigid block”, with the shrinkage rate in the west part at about 1~2 mm/a; (c) The principal directions of crustal deformation in the Xinjiang, Tibet, and Sichuan-Yunnan regions are generally in the north—south compression and east—west extension, indicating that the collision and wedging between the Indian and Eurasian plates are still the main source of tectonic movements in mainland China.

Mafic-ultramafic intrusion formed by multi-stage evolution of hydrous basaltic melts

The magmatic processes beneath the active continental margins are very complicated and affect structures and compositions of the arc roots. Neoproterozoic igneous rocks are widely distributed around the margins of the Tarim Block in NW China. The Xingdier mafic-ultramafic intrusion is a composite body, located at the northern margin of the Tarim Block, and consists of gabbro, pyroxenite, and peridotite units. The gabbro unit has a secondary ion mass spectrometry zircon U-Pb age of 727 ± 5 Ma. Rocks from the Xingdier intrusion have a large range of MgO (12.9−32.8 wt%) and SiO2 (43.0−57.9 wt%), and low K2O+Na2O (0.11−2.25 wt%) contents. They have right inclined chondrite-normalized rare earth element patterns with (La/Yb)N ratios of 2.2−8.6. Their primitive mantle normalized trace element patterns show arc-affinity geochemical features characterized by enrichment in Rb, Ba, Th, U, and Pb and depletion in Nb, Ta, and Ti. They have variable initial 87Sr/86Sr ratios (0.7063−0.7093), εNd(t) values (−2.9 to −7.8), 206Pb/204Pb (17.08−17.80), 207Pb/204Pb (15.42−15.49), and 208Pb/204Pb ratios (37.48−38.05), forming an evolution trend from the peridotite unit to the gabbro and pyroxenite units. Clinopyroxene in the three units is chemically similar to those formed in hydrous magmas. The spinel inclusions in olivine from the peridotite unit show unmixing texture and have high Al contents and oxygen fugacity of ∼FMQ+1. Therefore, the parental magma was probably derived from a lithospheric mantle enriched by slab-derived fluids. Rocks from the gabbro and peridotite units are proposed to have been derived from olivine-normative melts, whereas rocks from the pyroxenite unit are cumulates from the quartz-normative melts. Such contrasting parental magmas resulted from variable degrees of crustal contamination and fractional crystallization in the arc root.

Mo isotope records from Lower Cambrian black shales, northwestern Tarim Basin (China): Implications for the early Cambrian ocean

The widely developed black shales deposited during the early Cambrian recorded paleoenvironmental information about coeval seawater. Numerous studies have been conducted on these shales to reconstruct the paleomarine environment during this time period. However, most research has been conducted on stratigraphic sections in South China, and equivalent studies of sections from other cratons are relatively rare. Here, we report Mo isotopic compositions as well as redox-sensitive trace-element and iron (Fe) speciation data for black shales of the Lower Cambrian Yuertusi Formation from the Tarim block (i.e., a small craton). The Fe speciation data show high FeHR/FeT and Fepy/FeHR ratios, indicating roughly sustained euxinic bottom-water conditions during their deposition. Based on Mo isotopic compositions (δ98/95Mo), we further classified the euxinic black shales into two intervals: a lower interval (0−21.3 m) and an upper interval (21.3−32.3 m). The lower interval is characterized by variable Mo isotopic compositions (−2.12‰ to +0.57‰, mean = −0.52‰ ± 0.72‰), with an obvious negative excursion in its middle portion. The overlying upper interval has relatively heavy δ98/95Mo values up to +1.42‰ (mean = +0.62‰ ± 0.37‰). We ascribe δ98/95Mo differences in the lower and upper intervals to inadequate aqueous H2S concentrations for quantitative thiomolybdate formation under euxinic conditions. The most negative Mo isotope excursion may have been caused by upwelling hydrothermal inputs during a transgression, consistent with significantly elevated total organic carbon (TOC) contents, Mo and U enrichments, and Fe supply. Relatively positive δ98/95Mo values in the upper interval have roughly similar variations with other coeval sections, indicating such variations were common for early Cambrian euxinic deposits, and they were most likely caused by local differences in [H2S]aq. Compilation of Mo isotope data from the early Cambrian and earlier times further indicates relatively oxygenated seawater, especially the deep-marine areas during the early Cambrian before reaching a state like modern seawater.

Late Mesoproterozoic low-P/T−type metamorphism in the North Wulan terrane: Implications for the assembly of Rodinia

Regional metamorphism provides critical constraints for unravelling lithosphere evolution and geodynamic settings, especially in an orogenic system. Recently, there has been a debate on the Rodinia-forming Tarimian orogeny within the Greater Tarim block in NW China. The North Wulan terrane, involved in the Paleozoic Qilian orogen, was once part of the Greater Tarim block. This investigation of petrography, whole-rock and mineral geochemistry, phase equilibrium modeling, and in situ monazite U-Pb dating of garnetite, pelitic gneiss, and quartz schist samples from the Statherian−Calymmian unit of the North Wulan terrane provides new constraints on the evolutionary history of the Greater Tarim block at the end of the Mesoproterozoic during the assembly of Rodinia. The studied samples yielded three monazite U-Pb age groups of ca. 1.32 Ga, 1.1 Ga, and 0.45 Ga that are interpreted to be metamorphic in origin. The tectonic significance of the early ca. 1.32 Ga metamorphism is uncertain and may indicate an extensional setting associated with the final breakup of Columbia. The ca. 1.1 Ga low-pressure, high-temperature (low-P/T)−type granulite-facies metamorphism is well preserved and characterized by a clockwise P-T path with a minimum estimation of ∼840−900 °C and ∼7−11 kbar for peak metamorphism, followed by postpeak decompression and cooling. A tectonothermal disturbance occurred at ca. 0.45 Ga, but with limited influence on the preexisting mineral compositions of the studied samples. The characteristics of the metamorphism indicate an arc−back-arc environment with ongoing subduction of oceanic lithosphere at ca. 1.1 Ga. Combined with previous studies, we suggest that the Greater Tarim block probably experienced a prolonged subduction-to-collision process at ca. 1.1−0.9 Ga during the assembly of Rodinia, with a position between western Laurentia and India−East Antarctica.