Ferrocene-based hyperbranched polymers: a synthetic strategy for shape control and applications as electroactive materials and precursor-derived magnetic ceramics

Ferrocene-based hyperbranched polymers were prepared with different shapes of spheres and hollow polyhedra, and the 3D topological structures were studied as electroactive materials and precursor-derived magnetic ceramics, respectively.

CHITOSAN-TEMPLATED LIGHTWEIGHT SPINEL CoAl2O4 NANOFIBRIL AEROGELS

We present lightweight macro-mesoporous spinel CoAl2O4 nanostructured aerogels derived from water-soluble aluminum-chitosan complexes. Chitosan nanofibrils interact with aluminum ions to swell into hydrogels. The aluminum-induced swelling is extended to dissolve the hydrogels in water to form a homogeneous aluminum-chitosan aqueous solution. The addition of cobalt ions in the aluminum-chitosan liquids which are solidified by lyophilization to generate cotton-like aerogel composites. Uniform incorporation of cobalt-aluminum hydroxide ions onto chitosan leads nanofibrils to serve as a hierarchical template to support mixed metal hydroxides in the aerogel composites. We investigated the thermal removal of chitosan template in the composites to obtain spinel CoAl2O4 aerogels that truly replicate spider web-like fibrillar networks of chitosan template. Enlarged porosity, high crystallinity, and lightweight make the CoAl2O4 aerogels useful as a colorful nano-pigment for magnetic ceramics.

Tunable room-temperature soft ferromagnetism in magnetoceramics of organometallic dendrimers

This article represents an introduction of new dendrimeric precursors to magnetic ceramics, and homometallic and heterometallic dendrimers with tunable magnetic properties.

One for all: cobalt-containing polymethacrylates for magnetic ceramics, block copolymerization, unexpected electrochemistry, and stimuli-responsiveness

Functional cobalt-containing homo and block polymers are probed with respect to their redox-induced switchability and as preceramic materials.