Highly Catalytic Electrochemical Oxidation of Carbon Monoxide on Iridium Nanotubes: Amperometric Sensing of Carbon Monoxide

The nanotubular structures of IrO2 and Ir metal were successfully synthesized without any template. First, IrO2 nanotubes were prepared by electrospinning and post-calcination, where a fine control of synthetic conditions (e.g., precursor concentration and solvent composition in electrospinning solution, temperature increasing rate for calcination) was required. Then, a further thermal treatment of IrO2 nanotubes under hydrogen gas atmosphere produced Ir metal nanotubes. The electroactivity of the resultant Ir metal nanotubes was investigated toward carbon monoxide (CO) oxidation using linear sweep voltammetry (LSV) and amperometry. The anodic current response of Ir metal nanotubes was linearly proportional to CO concentration change, with a high sensitivity and a short response time. The amperometric sensitivity of Ir metal nanotubes for CO sensing was greater than a nanofibrous counterpart (i.e., Ir metal nanofibers) and commercial Pt (20 wt% Pt loading on carbon). Density functional theory calculations support stronger CO adsorption on Ir(111) than Pt(111). This study demonstrates that metallic Ir in a nanotubular structure is a good electrode material for the amperometric sensing of CO.

Metal Nanotube/Nanowire-Based Unsupported Network Electrocatalysts

Combining 1D metal nanotubes and nanowires into cross-linked 2D and 3D architectures represents an attractive design strategy for creating tailored unsupported catalysts. Such materials complement the functionality and high surface area of the nanoscale building blocks with the stability, continuous conduction pathways, efficient mass transfer, and convenient handling of a free-standing, interconnected, open-porous superstructure. This review summarizes synthetic approaches toward metal nano-networks of varying dimensionality, including the assembly of colloidal 1D nanostructures, the buildup of nanofibrous networks by electrospinning, and direct, template-assisted deposition methods. It is outlined how the nanostructure, porosity, network architecture, and composition of such materials can be tuned by the fabrication conditions and additional processing steps. Finally, it is shown how these synthetic tools can be employed for designing and optimizing self-supported metal nano-networks for application in electrocatalysis and related fields.