Tungsten Accumulation in Hot Spring Sediments Resulting from Preferred Sorption of Aqueous Polytungstates to Goethite

Geothermal waters usually have elevated tungsten concentrations, making geothermal systems important sources of tungsten in the environment. To study the transport of tungsten in hot springs to hot spring sediment, which is one of the key processes for the release of geothermally derived tungsten to the surface environment, geochemical investigations of the hot springs and their corresponding sediments in Rehai (a representative hydrothermal area in southwestern China) and systematic laboratory experiments of tungstate and polytungstate adsorption onto typical iron-bearing minerals in hot spring sediments (i.e., pyrite and goethite) were conducted. The results demonstrate that considerable tungsten concentrations (i.e., not much less than 10 µg/L), formation of polytungstates under acidic conditions, and enrichment of iron oxide minerals represented by goethite are the prerequisites for extreme enrichment of tungsten in hot spring sediments (e.g., 991 µg/g in the ZZQ spring outflow channel). The absence of any of these conditions would weaken the immobilization of aqueous tungsten and result in higher mobility of tungsten in the hot springs and its further transport downstream, possibly polluting the other natural waters in and around Rehai that serve as local drinking water sources. This study provides an insight for identifying the key geochemical processes controlling the transport and fate of undesirable elements (in this case, tungsten) in geothermal systems.

Measurements of pitch-off diameter of gas bubbles in liquid metal

To determine the separation diameter of bubbles in a liquid metal melt, an original technique based on the conductivity method is proposed. A thin electrode is installed in the center of the outflow channel, and the separation of bubbles is determined by closing and opening the electrical circuit. In this way, the separation frequency of the bubbles and their volume can be determined. Additional studies are carried out on a transparent liquid (water). It is shown that the presence of an electrode has little effect on the process of bubble detachment. The processing data of high-speed video filming and the proposed method in a transparent liquid coincide with high accuracy. Measurements of the frequency of bubble detachment in melts of the Rose and lead alloy are carried out. The results obtained are used to tune two-phase flow models when simulating fast neutron reactors with heavy liquid metal coolants.

Efficacy of Selective Laser Trabeculoplasty after iStent Implantation in Primary Open-Angle Glaucoma

iStent implantation is thought to augment the trabecular outflow channel in the anterior segment of the eye. We hypothesized that iStent with subsequent selective laser trabeculoplasty (SLT) would better control the intraocular pressure (IOP) compared to standalone SLT in patients with primary open-angle glaucoma (POAG). We, therefore, determined if the presence of an iStent combined with SLT was statistically associated with IOP lowering compared to standalone SLT. Through retrospective electronic medical record review, records of 824 eyes from 440 patients who received primary SLT without a history of iStent were considered. Additionally, 42 eyes from 28 patients who received SLT after combined phacoemulsification and iStent implantation that failed to control intraocular pressure (IOP) and/or the progression of the disease were retrospectively reviewed. IOP and number of medications, which were tracked in each patient for up to 12 months post laser, were also examined. Successful outcome was defined as a statistically significant reduction in IOP or number of medications at 6 months. As defined in univariate analysis (p ≤ 0.01), multivariate analysis included iStent, age, sex, race, and initial IOP as variables. IOP reduction was statistically associated with patients pre-SLT IOP (p < 0.001) but not with patients with iStent (p = 0.222). Medication reduction was statistically associated with the pre-SLT number of medications (p < 0.001) and iStent (p < 0.001). In eyes that received SLT, iStent was not statistically associated with a greater reduction in IOP compared to controls, but was associated with a higher reduction in the overall number of medications used 6 months after receiving SLT. The work presented should guide clinicians to consider SLT as an effective therapy after iStent implantation, in terms of glaucoma medication reduction in iStent patients, but clinicians should know that the presence of an iStent does not necessarily make subsequent SLT more effective at lowering IOP.

The volcanic geology of Morella Crater, Ganges Cavus and Elaver Vallis, Mars

Mars contains a large number of yet unexplained collapse features, sometimes spatially linked to large outflow channels. These pits and cavi are often taken as evidence for collapse due to the release of large volumes of pressurized groundwater. One such feature, Ganges Cavus, is an extremely deep (~ 6 km) collapse structure nested on the southern rim of Morella Crater, a 78-km-diameter impact structure breached on its east side by the Elaver Vallis outflow channel. Previous workers have concluded that Ganges Cavus, and other similar collapse features in the Valles Mariners area formed due to catastrophic release of pressurized groundwater that ponded and ultimately flowed over the surface. However, in the case of Ganges Cavus and Morella Crater, I show that the groundwater hypothesis cannot adequately explain the geology. The geology of Morella Crater, Ganges Cavus and the surrounding plains including Elaver Vallis is dominantly volcanic. Morella Crater contained a large picritic to komatiitic lava lake (> 3400 km3), which may have spilled through the eastern wall of the basin. Ganges Cavus is a voluminous (> 2100 km3) collapsed caldera. Morella Crater, Ganges Cavus and Elaver Vallis illustrate a volcanic link between structural collapse, formation and potential spillover of a large lake, and erosion and transport, but in this case, the geology is volcanic from source to sink. The geologic puzzle of Morella Crater and Ganges Cavus has important implications for the origins of other collapse structures on Mars and challenges the idea of pressurized groundwater release on Mars.

P819 Outflow graft twist occlusion in the heartmate 3 left ventricular assist system in 7 cases: analysis of potential mechanisms using computed tomography

Background Twist of the outflow graft (OG) of the HeartMate 3 left ventricular (LV) assist device (HM3) with subsequent occlusion is a rare, but life-threatening complication. Purpose We evaluated if potential implantation technique dependent mechanisms of OG twist can be predicted by multislice computed tomography (MSCT). Methods We retrospectively analyzed clinical, echocardiographic and MSCT data of 7 patients with angiographically proven and surgically corrected OG twist and of 11 consecutive patients without any type of pump obstruction. MSCT parameters were: position of inflow cannula related to anatomical LV apex (1), angulation of axis of inflow cannula related to LV axis (2), orientation of outflow channel of the pump housing related to LV axis (3), OG course (4). Echocardiographic parameters were LV end-diastolic diameter (LVEDD) and aortic valve opening. Results Mean time from implantation to twist was 563 ± 161 days. Preoperative LVEDD (64.6 ± 9.8 mm vs. 67.4 ± 10.2 mm, p = 0.563) was similar. LVEDD reduction after implantation (20% vs. 28%) and prevalence of aortic valve opening was higher in the twist group (71% vs. 45%). The MSCT measurements showed a high degree of heterogeneity in both groups: (1) differed from superior to infero-lateral; (2) varied from cranial to caudal, lateral and medial; (3) varied from antero-septal to inferior. (4) showed an incidence of non-obstructive kinking of 29% and 36%, respectively. Conclusion Marked heterogeneity of the measured MSCT parameters was observed in both groups. No specific pattern or geometric relation could be attributed to the OG twist phenomenon.

Novel surgical technique and efficacy analysis of donor pancreas preparation without vascular reconstruction in pancreas transplantation

Objective Because of the complicated blood supply and vascular structure of the pancreas, blood vessel reconstruction and reshaping are generally required during pancreas transplantation. We modified the vascular preparation procedure for the donor pancreas (i.e., no vascular reconstruction was performed) based on experiences in our department and in other domestic and international transplantation centers. Methods Twelve donor pancreas preparations without vascular reconstruction were performed. The patch (Carrel patch), celiac trunk, and superior mesenteric artery were preserved as arterial inflow channels for the donor pancreas. The common hepatic artery and the gastroduodenal artery were transected at a site 0.5 cm away from the bifurcation. The bifurcated portion was preserved for the donor liver. The stumps of the gastroduodenal artery and common hepatic artery were then ligated. The portal vein was transected in the middle of the hepatoduodenal ligament during separation of the liver and pancreas. The partial portal vein preserved with the pancreas was used as the outflow channel of the donor pancreas. Results The transplanted pancreas functioned well in the recipients, and no vascular complications were reported. Conclusion The overall efficacy of pancreas transplantation without vascular reconstruction has been improved.

Assessing Hydrological and Sedimentation Effects from Bottom Topography Change in a Complex River–Lake System of Poyang Lake, China

In recent years, a dramatic decline in Poyang Lake water levels and a shrinking water surface have raised concerns about water security and the wetland ecosystem. Changes in bottom topography due to sand mining activities in the lake was supposed to be one of the influencing factors of these changes. In response to this issue, the current study analyzed the change of lake bottom topography from observed digital elevation model (DEM) data, and quantitatively assessed the spatial and temporal responses of lake hydrology based on the framework of the neural network and the sediment effect was examined afterward. Results showed a total volume of 11.54 × 108 m3/year (about 0.96 × 108 m3/year or 1.58 × 108 t/year sediment) in net change of lake bottom topography in recent years, among which 97% was directly exported by commercial sand mining. During the study period, 2000–2011, intensive sand mining extended the central part of Poyang Lake and widened and deepened the outflow channel of the northern lake. This great change of lake bottom topography caused an average annual increase of 182.74 m3/s of lake outflow and a decline of 0.23 m–0.61 m in water levels across the lake. However, lake water levels are not consistent and show remarkable spatial and seasonal differences. The effects of changes in lake bottom topography on lake hydrological processes continue to grow as sand mining activities in the lake continue. More research on the environmental impacts is required for sustainable management of the lake ecosystem.

Connections between Eocene Lakes Uinta and Gosiute with emphasis on the infilling stage of Lake Uinta in Piceance Basin

Late in its history, Eocene saline Lake Gosiute in the Greater Green River Basin, Wyoming and Colorado was progressively filled from north to south with coarse volcaniclastic sediments. During the infilling, Lake Gosiute began to drain southward across the Axial arch into saline Lake Uinta in the Piceance and Uinta Basins, Colorado and Utah (about 49 Ma) causing Lake Gosiute to freshen. Once Lake Gosiute was filled entirely (about 48 Ma), volcaniclastic sediments spilled over into Lake Uinta. The first coarse volcanic sediments entered the north part of Lake Uinta near the present-day mouth of Yellow Creek 15 miles south of the Axial arch during deposition of the Mahogany oil shale zone. There is evidence that a south-flowing river entered Lake Uinta from the Axial arch starting early in the history of the lake and prior to substantial outflow from Lake Gosiute began. A petrographic study of sandstones from this period is consistent with an Axial arch source. It is likely that the outflow channel occupied this preexisting drainage. Determining when outflow from Lake Gosiute began to move through this preexisting channel is difficult as mainly mud-sized sediments would have entered Lake Uinta from Lake Gosiute prior to infilling. In addition, reliable dates for most of the strata deposited in Lake Uinta are lacking. A partial section of Lake Uinta strata is preserved at Deep Channel Creek about 10 mi south of the Axial arch. Here, the R-6 oil shale zone, below the Mahogany zone, has graded into fluvial strata—the only place in the basin where this zone is not lacustrine. In addition, the underlying L-5 zone is atypically sandy. We propose that Lake Gosiute began to drain into Lake Uinta starting at about the beginning of deposition of the L-5 oil shale zone increasing the input of sediments into the northern part of Lake Uinta. Mud-sized sediments could have come from Lake Gosiute, but the coarser sediments likely came from the Axial arch. Volcaniclastic sediments produced a rapidly prograding deltaic complex that ultimately filled in much if not all of the eastern part of Lake Uinta. The first volcanic sediments to reach the deep depocenter were mainly finegrained turbidites but ultimately the depocenter was largely filled by slumps off the over-steepened delta front. A petrographic study of the volcaniclastic sandstones indicates that the Absaroka volcanic field in northwest Wyoming is the likely source of the volcanic fraction.

A Tough Egg to Crack

The sculpting of the Egg Nebula continues to defy a coherent explanation. Bipolar outflows from the center of the nebula have created bipolar optical lobes that are illuminated by searchlight beams; multiple bipolar outflows orthogonal to the lobes create the appearance of a dark lane; and quasi-circular arcs are imprinted on an approximately spherically-symmetric wind from the progenitorAGB-star. Here, we use archival data from ALMA to study at high angular resolution dust and molecular gas at the center of the nebula. We find that: (i) dust is concentrated in multiple blobs that outline the base of the northern optical lobe; (ii) dense molecular gas forms the wall of a channel swept up and compressed by the outflows that created the bipolar optical lobes; (iii) the expansion and illumination center of the nebula lies at or close to center of the outflow channel. We present a simple working model for the Egg Nebula, and highlight the difficulties that any model face for explaining all the features seen in this nebula.