Radiogenic Pb Enrichment of Mississippi Valley-Type Metallic Ore Deposits, Southern Ozarks: Constraints Based on Geochemical Studies of Source Rocks and Their Diagenetic History

Southern Ozark Mississippi Valley-type ores are enriched in radiogenic Pb, with isotopic signatures suggesting that metals were supplied by two end-member components. While the less radiogenic component appears to be derived from various shale and sandstone units, the source of the more radiogenic component has not yet been identified. Analyses of cherts from the Early Ordovician Cotter Dolomite and tripolitic chert from the Early Mississippian Boone Formation contain highly radiogenic Pb, with isotopic ratios comparable to those of ores. However, most samples have lower 208Pb/204Pb and 207Pb/204Pb for a given 206Pb/204Pb compared to ores. These relationships demonstrate that the enriched Pb isotopic values of the ore array cannot be related to the host and regional lithologies sampled, suggesting that the source of high ratios may lay further afield. The slope of the linear trend defined by the Pb isotope ratios of ores corresponds to an age of about 1.19 Ga. Therefore, an alternative for the linear array is the involvement of Precambrian basement in supplying ore Pb. Rare earth element patterns show that diagenetic processes involving the action of groundwater and hydrothermal fluids affected the sampled lithologies to various degrees, with Cotter Dolomite having experienced the highest degree of alteration.

Mississippian Chat and Tripolite Zones in Osage County, Oklahoma: Paleokarst Interpretation based on 3D Seismic and Well Logs

Mississippian paleokarst Chat and tripolitic chert (tripolite) zones associated with the Mississippian Lime have been hydrocarbon exploration targets in Osage County for many decades. Chat is residual chert, either in place or transported, weathered out of chert-bearing Mississippian Limestone that was eroded at the Mississippian-Pennsylvanian unconformity. Thus, the formation of Chat is an epigene paleokarst process. Tripolite occurs as a highly porous, silica-rich interval within the Mississippi Lime. It is formed by in-place alteration of limestone by silica-rich surface waters or deep-seated hydrothermal fluids, making tripolite formation a mixed or hypogene paleokarst process. Here, we have studied Chat and tripolite by seismic analysis calibrated by well control with full-wave sonic and density log data. We identify that Chat and tripolite show clear separation from Mississippian Lime log-based acoustic impedance and VP/ VS, but there is no meaningful separation of Chat from tripolite, and they both exhibit total porosities greater than 20% with evidence of fracture porosity. We find that the sonic-based normal incidence wedge model for Chat bounded above by the Pennsylvanian Shale and below by the Mississippian Lime indicate that two seismic expressions are plausible: first, a strong negative amplitude when the Chat thickness is above the tuning thickness (for this survey it is 56 ft) and, second, a weak positive or negative amplitude associated with the small impedance contrast between Chat and overlying Pennsylvanian Shale. Our analysis suggests that the traditional Chat “strong response” and a new “dim-out” exploration strategy may be usefully applied in Osage County. We show that the tripolite response is consistently a negative amplitude event that strengthens with increasing tripolite thickness. We provide an interpretive framework for characterizing Chat and tripolite zones associated with the Mississippian Lime in the US Midcontinent, which may apply to regions around the world.

Characterizing a Mississippian tripolitic chert reservoir using 3D unsupervised and supervised multiattribute seismic facies analysis: An example from Osage County, Oklahoma

Seismic interpretation is based on the identification of reflector configuration and continuity, with coherent reflectors having a distinct amplitude, frequency, and phase. Skilled interpreters may classify reflector configurations as parallel, converging, truncated, or hummocky, and use their expertise to identify stratigraphic packages and unconformities. In principal, a given pattern can be explicitly defined as a combination of waveform and reflector configuration properties, although such “clustering” is often done subconsciously. Computer-assisted classification of seismic attribute volumes builds on the same concepts. Seismic attributes not only quantify characteristics of the seismic reflection events, but also measure aspects of reflector configurations. The Mississippi Lime resource play of northern Oklahoma and southern Kansas provides a particularly challenging problem. Instead of defining the facies stratigraphically, we need to define them either diagenetically (tight limestone, stratified limestone and nonporous chert, and highly porous tripolitic chert) or structurally (fractured versus unfractured chert and limestone). Using a 3D seismic survey acquired in Osage County Oklahoma, we use Kohonen self-organizing maps to classify different diagenetically altered facies of the Mississippi Lime play. The 256 prototype vectors (potential clusters) reduce to only three or four distinct “natural” clusters. We use ground truth of seismic facies seen on horizontal image logs to fix three average attribute data vectors near the well locations, resulting in three “known” facies, and do a minimum Euclidean distance supervised classification. The predicted clusters correlate well to the poststack impedance inversion result.

Rock property- and seismic-attribute analysis of a chert reservoir in the Devonian Thirty-one Formation, west Texas, U.S.A.

In west Texas, fractured-chert reservoirs of Devonian age have produced more than 700 million barrels of oil. About the same amount of mobile petroleum remains in place. These reservoirs are characterized by microporosity; they are heterogeneous and compartmented, which results in recovery of less than 30% of the oil in place. In this case study the objective was to use cores, petrophysical logs, rock physics, and seismic attributes to characterize porosity and field-scale fractures. The relations among porosity, velocity, and impedance were explored and also reactions among production, impedance, and lineaments observed in 3D attribute volumes. Laboratory core data show that Gassmann’s fluid-substitution equation works well for microporous tripolitic chert. Also, laboratry measurements show excellent linear correlation between P-wave impedance and porosity. Volumetric calculations of reflector curvature and seismic inversion of acoustic impedance were combined to infer distribution of lithofacies and fractures and to predict porosity. Statistical relations were established between P-wave velocity and porosity measured from cores, between P-wave impedance and producing zones, and between initial production rates and seismic “fracture lineaments.” The strong quantitative correlation between thick-bedded chert lithofacies and seismic impedance was used to map the reservoir. A qualitative inverse relation between the first [Formula: see text] of production and curvature lineaments was documented.