Using Molding to Fabricate Stable Salt Structures for Thermochemical Energy Storage

The present work investigates using a molding technique to fabricate stable salt structures for thermochemical energy storage. Two type of salts were investigated: pure MgSO4 and a blend of 53% CaCl2 with 47% MgSO4. These salts were mixed with two common binders and hot pressed. Various post-hot-pressing conditions were considered including the debinding temperature, whether the sample was sintered, and the sintering temperature. The samples were subjected to combined hydration and thermal cycling. The hydration reaction was monitored by measuring the relative humidity. The samples were visibly inspected for changes between each half cycle. The results indicate that molding can result in stable structures. All the samples of 53wt%CaCl2+47%wtMgSO4 and one sample of pure MgSO4 retained their integrity through the course of cycling. Of the samples that did not retain their integrity through cycling, the results show that fabrication parameters can be used to improve the cycle stability of the molded sample. The hydration data shows that, for the samples that retained their structure, stable hydration rates were achieved. This indicates that the structure stabilized. These results show the feasibility of using molding or similar manufacturing techniques to fabricate a stable structure of hygroscopic salts for thermochemical-based, thermal energy storage.

Dehumidification Effect of Polymeric Superabsorbent SAP-LiCl Composite Desiccant-Coated Heat Exchanger with Different Cyclic Switching Time

This study investigated a composite polymer desiccant material’s performance, which is prepared by impregnating solid desiccant such as sodium polyacrylate (SAP) on to hygroscopic salts such as lithium chloride (LiCl). Dehumidification performance of the proposed composite polymer desiccant (SAP-LiCl) was analyzed by coating the suitable weight percentage (wt %) of the desiccant onto a single fin-tube heat exchanger (FTHE) system and testing the desiccant-coated heat exchanger (DCHE) in a testing tunnel under various operating conditions. Net dehumidification efficacy of DCHE in terms of sorption and desorption amount and thermal performance (COPth) were analyzed. For instance, with processed air inflow temperature, relative humidity and regeneration temperature setting of 30 °C, 80% RH and 70 °C, DCHE’s sorption, desorption amount and COPth were recorded as high as 945.1 g, 1115.1 g, and 0.39, respectively. It was further realized that the performance of the DCHE could be enhanced by modulating the cyclic switching time for dehumidification and regeneration processes. For instance, with the aforementioned processed airflow conditions, when the cyclic switching time tuned as 60 min instead of 10 min for a total time period of 120 min, there is a net 58% improvement to the COPth of the system. It was further observed that, under the same time period corresponding to the increase in cyclic switching time, the overall COPth can be enhanced; however, the water vapor sorption and desorption amounts of desiccant were decreased.

Inherent protection of bacteria from beta-lactam antibiotics by wet-dry cycles with microscopic surface wetness

A large portion of bacterial life occurs on surfaces that are not constantly saturated with water and experience recurrent wet-dry cycles. While soil, plant leaves and roots, and many indoor surfaces may appear dry when not saturated with water, they are in fact often covered by thin liquid films and microdroplets, invisible to the naked eye, known as microscopic surface wetness (MSW). Such MSW, resulting from the condensation of water vapor to hygroscopic salts, is ubiquitous yet largely underexplored. A wide variety of antibiotics are abundant in environments where MSW occurs, yet little is known about bacterial response to antibiotics in wet-dry cycles and under MSW conditions. Using E. coli as a model organism, we show, through a combination of experiments and computational modeling, that bacteria are considerably more protected from beta-lactams under wet-dry cycles with MSW phases, than they are under constantly wet conditions. This is due to the combined effect of several mechanisms, including tolerance triggered by inherent properties of MSW, i.e., high salt concentrations and slow cell growth, and the deactivation of antibiotics due to physicochemical properties of MSW. Remarkably, we also find evidence for a cross-protection effect, where addition of lethal doses of antibiotic before drying significantly increases cells’ survival under MSW. As wet-dry cycles with MSW and beta-lactams, as well as other antibiotics, are common in vast terrestrial microbial habitats, our findings are expected to have significant implications for how we understand antibiotic response, population dynamics, and interspecies interactions in these globally important microbial ecosystems.

The Influence of Salts’ Presence in the Materials on their Moisture and Thermal Conductivity

Energy saving in buildings is largely determined by the energy efficiency of the external building envelopes. The latter, as a rule, are the multilayer and incorporate structural and heat-insulating layers. The presence of individual hygroscopic salts and their mixtures in building materials changes their physical and chemical properties. Due to the increase in the sorption properties of building materials and changes in the inter-pore substance composition, humidity increases and the heat-protective properties decrease. This paper presents the results of the experimental and theoretical studies on the salts’ effect assessment on the change in moisture content and thermal conductivity of building materials due to the salt solutions and crystals’ presence in the pore space. To study the saline building materials’ thermal conductivity, the mathematical modeling methods using the theory of flow and bringing the materials’ structure to a unit cell are used. It is shown that the change in thermal conductivity occurs due to the crystalline salt precipitation from the solutions in the material’s pores, to the changes in their initial chemical properties, to the changes in the properties of the vapor-air mixture above the salt solutions due to diffusion. The results obtained make it possible to establish the hygroscopic salts’ influence significance in solid and liquid phases on the building materials’ thermal conductivity. A scheme for determining the thermal conductivity of building materials is proposed, taking into account salt effects, including the determination of: the components’ volume concentrations; sequentially the thermal conductivity of the material’s shell; salt crystals, a solid phase consisting of the material’s shell and crystalline salt, a binary and multicomponent saline solution, the pore space and the pore substance inside. The general formula for determining the thermal conductivity of a saline building material is given.

Charged Particle (Negative Ion)-Based Cloud Seeding and Rain Enhancement Trial Design and Implementation

China has been suffering from water shortage for a long time. Weather modification and rainfall enhancement via cloud seeding has been proved to be effective to alleviate the problem. Current cloud seeding methods mostly rely on solid carbon dioxide and chemicals such as silver iodide and hygroscopic salts, which may have negative impacts on the environment and are expensive to operate. Lab experiments have proved the efficiency of ion-based cloud seeding compared with traditional methods. Moreover, it is also more environmentally friendly and more economical to operate at a large scale. Thus, it is necessary to carry out a field experiment to further investigate the characteristics and feasibility of the method. This paper provides the design and implementation of the ion-based cloud seeding and rain enhancement trial currently running in Northwest China. It introduces the basic principle of the trial and the devices developed for it, as well as the installation of the bases and the evaluation method design for the trial.

Bacterial growth in saturated and eutectic solutions of magnesium sulphate and potassium chlorate with relevance to Mars and the ocean worlds

Liquid water on Mars might be created by deliquescence of hygroscopic salts or by permafrost melts, both potentially forming saturated brines. Freezing point depression allows these heavy brines to remain liquid in the near-surface environment for extended periods, perhaps as eutectic solutions, at the lowest temperatures and highest salt concentrations where ices and precipitates do not form. Perchlorate and chlorate salts and iron sulphate form brines with low eutectic temperatures and may persist under Mars near-surface conditions, but are chemically harsh at high concentrations and were expected to be incompatible with life, while brines of common sulphate salts on Mars may be more suitable for microbial growth. Microbial growth in saturated brines also may be relevant beyond Mars, to the oceans of Ceres, Enceladus, Europa and Pluto. We have previously shown strong growth of salinotolerant bacteria in media containing 2M MgSO4 heptahydrate (~50% w/v) at 25°C. Here we extend those observations to bacterial isolates from Basque Lake, BC and Hot Lake, WA, that grow well in saturated MgSO4 medium (67%) at 25°C and in 50% MgSO4 medium at 4°C (56% would be saturated). Psychrotolerant, salinotolerant microbes isolated from Basque Lake soils included Halomonas and Marinococcus, which were identified by 16S rRNA gene sequencing and characterized phenetically. Eutectic liquid medium constituted by 43% MgSO4 at −4°C supported copious growth of these psychrotolerant Halomonas isolates, among others. Bacterial isolates also grew well at the eutectic for K chlorate (3% at −3°C). Survival and growth in eutectic solutions increases the possibility that microbes contaminating spacecraft pose a contamination risk to Mars. The cold brines of sulphate and (per)chlorate salts that may form at times on Mars through deliquescence or permafrost melt have now been demonstrated to be suitable microbial habitats, should appropriate nutrients be available and dormant cells become vegetative.

Differentiating between particle formation and growth events in an urban environment

Small aerosols at a given location in the atmosphere often originate in situ from new particle formation (NPF). However, they can also be produced and then transported from a distant location to the point of observation where they may continue to grow to larger sizes. This study was carried out in the subtropical urban environment of Brisbane, Australia, in order to assess the relative occurrence frequencies of NPF events and particle growth events with no NPF. We used a neutral cluster and air ion spectrometer (NAIS) to monitor particles and ions in the size range 2–42 nm on 485 days, and identified 236 NPF events on 213 days. The majority of these events (37 %) occurred during the daylight hours with just 10 % at night. However, the NAIS also showed particle growth with no NPF on many nights (28 %). Using a scanning mobility particle sizer (SMPS), we showed that particle growth continued at larger sizes and occurred on 70 % of nights, typically under high relative humidities. Most particles in the air, especially near coastal locations, contain hygroscopic salts such as sodium chloride that may exhibit deliquescence when the relative humidity exceeds about 75 %. The growth rates of particles at night often exceeded the rates observed during NPF events. Although most of these night time growth events were preceded by day time NPF events, the latter was not a prerequisite for growth. We conclude that particle growth in the atmosphere can be easily misidentified as NPF, especially when they are monitored by an instrument that cannot detect them at the very small sizes.

Differentiating between particle formation and growth events in an urban environment

Small aerosols at a given location in the atmosphere often originate in-situ from new particle formation (NPF). However, they can also be produced and then transported from a distant location to the point of observation where they may continue to grow to larger sizes. This study was carried out in the subtropical urban environment of Brisbane, Australia, in order to assess the relative occurrence frequencies of NPF events and particle growth events with no NPF. We used a neutral cluster and air ion spectrometer (NAIS) to monitor particles and ions in the size range 2–42 nm on 485 days, and identified 236 NPF events on 213 days. The majority of these events (37 %) occurred during the daylight hours with just 10 % at night. However, the NAIS also showed particle growth with no NPF on many nights (28 %). Using a scanning mobility particle sizer (SMPS), we showed that particle growth continued at larger sizes and occurred on 70 % of nights, typically under high relative humidities. Most particles in the air, especially near coastal locations, contain hygroscopic salts such as sodium chloride that may exhibit deliquescence when the relative humidity exceeds about 75 %. The growth rates of particles at night often exceeded the rates observed during NPF events. Although most of these night time growth events were preceded by daytime NPF events, the latter was not a prerequisite for growth. We conclude that particle growth in the atmosphere can be easily misidentified as NPF, especially when they are monitored by an instrument that cannot detect them at the very small sizes.