electron deficient dienes
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Diastereo-, Enantio-, and Z-Selective α,δ-Difunctionalization of Electron-Deficient Dienes Initiated by Rh-Catalyzed Conjugate Addition

2021 ◽  
Author(s):  
Christopher J. C. Cooze ◽  
Wesley McNutt ◽  
Markus D. Schoetz ◽  
Bohdan Sosunovych ◽  
Svetlana Grigoryan ◽  
...  
Keyword(s):  
Conjugate Addition ◽  
Electron Deficient Dienes

Regioselective Synthesis of 2-Acylbutadienes from β,γ-Unsaturated Ketones

Synthesis ◽  
2019 ◽  
Vol 51 (20) ◽  
pp. 3825-3833 ◽  
Author(s):  
Dmitrii A. Shabalin ◽  
Elena V. Ivanova ◽  
Igor A. Ushakov ◽  
Elena Yu. Schmidt ◽  
Boris A. Trofimov
Keyword(s):  
Acetic Acid ◽  
Regioselective Synthesis ◽  
Unsaturated Ketones ◽  
Boiling Toluene ◽  
Electron Deficient Dienes

2-Acylbuta-1,3-dienes have been synthesized regioselectively from aromatic and heteroaromatic β,γ-unsaturated ketones (readily accessible via base-catalyzed addition of ketones to acetylenes) and aldehydes. The reaction smoothly proceeds with piperidine (10 mol%)/acetic acid (10 mol%) catalytic pair in boiling toluene to provide synthetically attractive polyconjugated electron-deficient dienes in up to 94% yield.

Direct Sulfide-Catalyzed Enantioselective Cyclopropanations of Electron-Deficient Dienes and Bromides

2018 ◽  
Vol 20 (12) ◽  
pp. 3700-3704 ◽  
Author(s):  
Qing-Zhu Li ◽  
Xiang Zhang ◽  
Rong Zeng ◽  
Qing-Song Dai ◽  
Yue Liu ◽  
...  
Keyword(s):  
Electron Deficient Dienes

PPh3 Mediated Reductive Annulation Reaction between Isatins and Electron Deficient Dienes to Construct Spirooxindole Compounds

2017 ◽  
Vol 82 (11) ◽  
pp. 5782-5789 ◽  
Author(s):  
Lei Zhang ◽  
Hong Lu ◽  
Guo-Qiang Xu ◽  
Zhu-Yin Wang ◽  
Peng-Fei Xu
Keyword(s):  
Electron Deficient Dienes

ChemInform Abstract: Synthesis of Electron-Deficient Dienes Bearing a Chromonyl Moiety via the Reaction of 3-Formylchromones with Ylidenemalononitriles and Ethyl α-Cyano-β-methylcinnamate.

ChemInform ◽  
2014 ◽  
Vol 45 (44) ◽  
pp. no-no
Author(s):  
Vladislav Yu. Korotaev ◽  
Alexey Yu. Barkov ◽  
Igor B. Kutyashev ◽  
Alexander V. Safrygin ◽  
Vyacheslav Ya. Sosnovskikh
Keyword(s):  
Electron Deficient Dienes

Synthesis of electron-deficient dienes bearing a chromonyl moiety via the reaction of 3-formylchromones with ylidenemalononitriles and ethyl α-cyano-β-methylcinnamate

Tetrahedron ◽  
2014 ◽  
Vol 70 (22) ◽  
pp. 3584-3589 ◽  
Author(s):  
Vladislav Yu. Korotaev ◽  
Alexey Yu. Barkov ◽  
Igor B. Kutyashev ◽  
Alexander V. Safrygin ◽  
Vyacheslav Ya. Sosnovskikh
Keyword(s):  
Electron Deficient Dienes

ChemInform Abstract: Conjugate Addition Reactions of Carbon Nucleophiles to Electron-Deficient Dienes.

ChemInform ◽  
2011 ◽  
Vol 42 (7) ◽  
pp. no-no
Author(s):  
Aurelio G. Csaky ◽  
Gabriela de la Herran ◽  
M. Carmen Murcia
Keyword(s):  
Conjugate Addition ◽  
Addition Reactions ◽  
Carbon Nucleophiles ◽  
Electron Deficient Dienes
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