Infrared spectra of pyroxenes (crystalline chain silicates) at room temperature

ABSTRACT Crystals of pyroxene are common in meteorites but few compositions have been recognized in astronomical environments due to the limited chemistries included in laboratory studies. We present quantitative room-temperature spectra of 17 Mg-, Fe-, and Ca-bearing ortho- and clinopyroxenes, and a Ca-pyroxenoid in order to discern trends indicative of crystal structure and a wide range of composition. Data are produced using a diamond anvil cell: our band strengths are up to six times higher than those measured in KBr or polyethylene dispersions, which include variations in path length (from grain size) and surface reflections that are not addressed in data processing. Pyroxenes have varied spectra: only two bands, at 10.22 and 15.34 μm in enstatite (En99), are common to all. Peak wavelengths generally increase as Mg is replaced by Ca or Fe. However, two bands in MgFe-pyroxenes shift to shorter wavelengths as the Fe component increases from 0 to 60 per cent. A high-intensity band shifts from 11.6 to 11.2 μm and remains at 11.2 μm as Fe increases to 100 per cent; it resembles an astronomical feature normally identified with olivine or forsterite. The distinctive pyroxene bands between 13 and 16 μm show promise for their identification in Mid-Infrared-Instrumentspectra obtained with the James Webb Space Telescope. The many pyroxene bands between 40 and 80 μm could be diagnositic of silicate mineralogy if data were obtained with the proposed Space Infrared Telescope for Cosmology and Astrophysics. Our data indicate that comparison between room-temperature laboratory bands for enstatite and cold ∼10 − K astronomical dust features at wavelengths $\gtrsim 28~\mu$m can result in the identification of (Mg,Fe)- pyroxenes that contain 7–15 per cent less Fe– than their true values because some temperature shifts mimic some compositional shifts. Therefore some astronomical silicates may contain more Fe, and less Mg, than previously thought.

Rapid grain growth in post-AGB disc systems from far-infrared and sub-millimetre photometry

ABSTRACT The time-scales on which astronomical dust grows remain poorly understood, with important consequences for our understanding of processes like circumstellar disc evolution and planet formation. A number of post-asymptotic giant branch (AGB) stars are found to host optically thick, dust- and gas-rich circumstellar discs in Keplerian orbits. These discs exhibit evidence of dust evolution, similar to protoplanetary discs; however, since post-AGB discs have substantially shorter lifetimes than protoplanetary discs, they may provide new insights on the grain-growth process. We examine a sample of post-AGB stars with discs to determine the far-infrared and sub-millimetre spectral index by homogeneously fitting a sample of data from Herschel, the Submillimeter Array (SMA), and the literature. We find that grain growth to at least hundreds of micrometres is ubiquitous in these systems, and that the distribution of spectral indices is more similar to that of protoplanetary discs than debris discs. No correlation is found with the mid-infrared colours of the discs, implying that grain growth occurs independently of the disc structure in post-AGB discs. We infer that grain growth to ∼millimetre sizes must occur on time-scales <<105 yr, perhaps by orders of magnitude, as the lifetimes of these discs are expected to be ≲105 yr and all objects have converged to the same state. This growth time-scale is short compared to the results of models for protoplanetary discs including fragmentation and may provide new constraints on the physics of grain growth.

Systematic errors in dust mass fits: The role of dust opacity

The estimation of interstellar dust masses is an important pursuit in our understanding of both local and early Universe – see e.g. the “dust budget crisis”. One of the most used methods of estimating dust masses – dust emission fitting – requires an estimate of the dust opacity at far-infrared and submillimeter wavelengths, but in most models this quantity is based on extrapolation rather than on actual measurements. It is becoming more and more evident that the opacity in typical dust models differs from that of dust analogs measured in the lab, meaning that astronomical dust mass estimations may need to be revised. To estimate the systematic errors introduced by this mismatch, we calculated dust emission for a model where dust far-infrared opacity is the same as that measured in lab samples, then we fit the synthetic emission with a typical (modified blackbody) dust model. Our results show that, if interstellar dust is indeed similar to the lab dust analogs, most fits may overestimate dust masses by as much as an order of magnitude.

The Question of Presolar Components within Interplanetary Dust Particles (IDPs) Collected in the Stratosphere

Interplanetary dust particles (IDPs) are from asteroids and comets, and they are the smallest and most fine-grained meteoritic objects available for laboratory investigation. Cometary IDPs are of special significance because they are presently the only samples of comets, and comets are expected to be enriched in preserved solar nebula and presolar components. These components may include not only cosmically rare refractory circumstellar grains(e.g. SiC) that are recovered from meteorites but also cosmically abundant interstellar silicates and carbonaceous grains that were the fundamental building blocks of the Solar System. D/H ratios measured in IDPs are consistent with the survival of interstellar carbonaceous material, and some IDPs contain glassy grains with properties similar to those of interstellar “amorphous silicates”. Submicrometer forsterite and enstatite crystals in IDPs resemble circumstellar silicates detected by the Infrared Space Observatory (ISO). ISO also detected a broad ~ 23 µm feature around several stars, and a similar feature observed in IDP spectra is due to submicrometer FeNi sulfide grains, suggesting that sulfide grains may be a significant constituent of astronomical dust.