Infrared Comb Spectroscopy of Buffer-Gas-Cooled Molecules: Toward Absolute Frequency Metrology of Cold Acetylene

We review the recent developments in precision ro-vibrational spectroscopy of buffer-gas-cooled neutral molecules, obtained using infrared frequency combs either as direct probe sources or as ultra-accurate optical rulers. In particular, we show how coherent broadband spectroscopy of complex molecules especially benefits from drastic simplification of the spectra brought about by cooling of internal temperatures. Moreover, cooling the translational motion allows longer light-molecule interaction times and hence reduced transit-time broadening effects, crucial for high-precision spectroscopy on simple molecules. In this respect, we report on the progress of absolute frequency metrology experiments with buffer-gas-cooled molecules, focusing on the advanced technologies that led to record measurements with acetylene. Finally, we briefly discuss the prospects for further improving the ultimate accuracy of the spectroscopic frequency measurement.

Evolution of timing and spectral characteristics of 4U 1901+03 during its 2019 outburst using the Swift and NuSTAR observatories

ABSTRACT We report the results from a detailed timing and spectral study of a transient X-ray pulsar, 4U 1901+03 during its 2019 outburst. We performed broadband spectroscopy in the 1–70 $\rm keV$ energy band using four observations made with Swift and NuSTAR at different intensity levels. Our timing results reveal the presence of highly variable pulse profiles dependent on both luminosity and energy. Our spectroscopy results showed the presence of a cyclotron resonance scattering feature (CRSF) at ∼ 30 keV. This feature at 30 keV is highly luminosity and pulse phase dependent. Phase-averaged spectra during the last two observations, made close to the declining phase of the outburst, showed the presence of this feature at around $30~\rm {keV}$. The existence of CRSF at 30 keV during these observations is well supported by an abrupt change in the shape of pulse profiles found close to this energy. We also found that 30 keV feature was significantly detected in the pulse phase-resolved spectra of observations made at relatively high luminosities. Moreover, all spectral fit parameters showed a strong pulse phase dependence. In line with the previous findings, an absorption feature at around $10~\rm {keV}$ is significantly observed in the phase-averaged X-ray spectra of all observations and also showed a strong pulse phase dependence.

Comb-locked frequency-swept synthesizer for high precision broadband spectroscopy

Frequency combs have made optical metrology accessible to hundreds of laboratories worldwide and they have set new benchmarks in multi-species trace gas sensing for environmental, industrial and medical applications. However, current comb spectrometers privilege either frequency precision and sensitivity through interposition of a cw probe laser with limited tuning range, or spectral coverage and measurement time using the comb itself as an ultra-broadband probe. We overcome this restriction by introducing a comb-locked frequency-swept optical synthesizer that allows a continuous-wave laser to be swept in seconds over spectral ranges of several terahertz while remaining phase locked to an underlying frequency comb. This offers a unique degree of versatility, as the synthesizer can be either repeatedly scanned over a single absorption line to achieve ultimate precision and sensitivity, or swept in seconds over an entire rovibrational band to capture multiple species. The spectrometer enables us to determine line center frequencies with an absolute uncertainty of 30 kHz and at the same time to collect absorption spectra over more than 3 THz with state-of-the-art sensitivity of a few 10−10 cm−1. Beyond precision broadband spectroscopy, the proposed synthesizer is an extremely promising tool to force a breakthrough in terahertz metrology and coherent laser ranging.

Electron Dynamics in Anatase TiO2 Nanoparticles by Ultrafast Broadband Deep-Ultraviolet Spectroscopy

The optical bandgap of anatase TiO2 nanoparticles is dominated by bulk absorption bands in the deep-ultraviolet due to strongly bound excitons. These spectral features can be utilized as a sensitive probe of carrier and lattice dynamics inside the TiO2 nanoparticles. Here, we implement ultrafast broadband spectroscopy tuned to the exciton resonances in order to track the electron cooling in the conduction band of bare anatase nanoparticles and monitor the electron injection dynamics from an external dye in the case of sensitized anatase nanoparticles.