Lewis acid-surfactant complex catalyzed polymerization in aqueous dispersed media: cationic or radical polymerization?

Evidence is presented that shows Lewis acid-surfactant complex catalyzed polymerization proceeds via a radical, not a cationic, mechanism.

Tuning photosensitized singlet oxygen production from microgels synthesized by polymerization in aqueous dispersed media

Miniemulsion copolymerization of vinyl acetate, N-vinylcaprolactam, vinyl benzyl Rose Bengal and divinyl adipate to synthesize switchable photosensitizer-grafted polymer colloids for interfacial photooxygenation reactions.

Radical polymerization of biobased monomers in aqueous dispersed media

This review highlights the synthesis of biobased monomers from renewable resources for the preparation of polymers by (mini)emulsion and suspension polymerizations.

One-pot synthesis of hyperstar polymers via sequential ATRP of inimers and functional monomers in aqueous dispersed media

A one-pot synthesis was reported to produce hyperstar polymers with high molecular weight, low polydispersity and no detectable star coupling reactions.

Atom transfer radical polymerization in aqueous dispersed media

During the last decade, atom transfer radical polymerization (ATRP) received significant attention due to its exceptional capability of synthesizing polymers with pre-determined molecular weight, well-defined molecular architectures and various functionalities. It is economically and environmentally attractive to adopt ATRP to aqueous dispersed media, although the process is challenging. This review summarizes recent developments of conducting ATRP in aqueous dispersed media. The issues related to retaining “controlled/living” character as well as colloidal stability during the polymerization have to be considered. Better understanding the ATRP mechanism and development of new initiation techniques, such as activators generated by electron transfer (AGET) significantly facilitated ATRP in aqueous systems. This review covers the most important progress of ATRP in dispersed media from 1998 to 2009, including miniemulsion, microemulsion, emulsion, suspension and dispersed polymerization.