dimetal units
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A Magic Equation: Delta Bonds Plus Bicyclic Guanidinates Equals Strong Reducing Agents

2014 ◽  
Vol 67 (7) ◽  
pp. 972 ◽  
Author(s):  
Carlos A. Murillo
Keyword(s):  
Electronic Configuration ◽  
Reducing Agents ◽  
Oxidation States ◽  
Stable Species ◽  
High Oxidation ◽  
Dimetal Units

Reactions of bicyclic guanidinates with dimolybdenum and ditungsten precursors having quadruple bonded units with a σ2π4δ2 (Q) electronic configuration have generated the most easily ionized, chemically stable species and very strong reducing agents. Analogous rhenium compounds have led to the formation of species having dimetal units in unusually high oxidation states. Here we review this chemistry and the accounts that explain such behaviour that has been attributed to the interaction of the π electrons of the guanidinate C(N)3 core with the electrons that give rise to the delta bond of the dimetal units.

Quadruply Bonded Dimetal Units Supported by 2,4,6-Triisopropylbenzoates MM(TiPB)4(MM = Mo2, MoW, and W2): Preparation and Photophysical Properties

2009 ◽  
Vol 48 (10) ◽  
pp. 4394-4399 ◽  
Author(s):  
Brian G. Alberding ◽  
Malcolm H. Chisholm ◽  
Yi-Hsuan Chou ◽  
Judith C. Gallucci ◽  
Yagnaseni Ghosh ◽  
...  
Keyword(s):  
Photophysical Properties ◽  
Dimetal Units

Coaxial alkaline-earth dimetal units sandwiched between hydrosilver compounds: A DFT Study

2007 ◽  
Vol 808 (1-3) ◽  
pp. 163-166 ◽  
Author(s):  
Jia Zhou ◽  
Fei Xiao ◽  
Zhi-Pan Liu ◽  
Kang-Nian Fan
Keyword(s):  
Alkaline Earth ◽  
Dft Study ◽  
Dimetal Units

Channel-containing structures generated from linear coordination polymer chains containing -bidentate ligands and Cu–Cu dimetal units

2005 ◽  
Vol 7 (9) ◽  
pp. 1083-1095 ◽  
Author(s):  
Andrea M. Goforth ◽  
Kathrine Gerth ◽  
Mark D. Smith ◽  
Sandra Shotwell ◽  
Uwe H.F. Bunz ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Polymer Chains ◽  
Bidentate Ligands ◽  
Dimetal Units ◽  
Linear Coordination

The Dichotomy of Dimetallocenes:  Coaxial versus Perpendicular Dimetal Units in Sandwich Compounds

2005 ◽  
Vol 127 (9) ◽  
pp. 2818-2819 ◽  
Author(s):  
Yaoming Xie ◽  
Henry F. Schaefer ◽  
R. Bruce King
Keyword(s):  
Sandwich Compounds ◽  
Dimetal Units

9,10-Anthracene dicarboxylate bridged complexes with M2quadruply bonded dimetal units: [{M2(O2CtBu)3}2(μ-9,10-An(CO2)2)], where M = Mo or W

2004 ◽  
pp. 523-529 ◽  
Author(s):  
Matthew J. Byrnes ◽  
Malcolm H. Chisholm ◽  
David F. Dye ◽  
Christopher M. Hadad ◽  
Brian D. Pate ◽  
...  
Keyword(s):  
Dimetal Units

Calixarenes as ligands for dimetal units: the state of the art. Structure of a new quadruply-bonded dimolybdenum compound

2003 ◽  
Vol 347 ◽  
pp. 1-8 ◽  
Author(s):  
F.Albert Cotton ◽  
Lee M Daniels ◽  
Chun Lin ◽  
Carlos A Murillo
Keyword(s):  
State Of The Art ◽  
The State ◽  
Dimetal Units

New coordination polymers generated from oxadiazole-containing bidentate ligands and CuCu dimetal units

2002 ◽  
Vol 4 (10) ◽  
pp. 1313-1320 ◽  
Author(s):  
Yu-Bin Dong ◽  
Jian-Ping Ma ◽  
Mark D Smith ◽  
Ru-Qi Huang ◽  
Bo Tang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Bidentate Ligands ◽  
Dimetal Units
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