Behaviors of Wet Plume Controlled by Olivine-Wadsleyite Phase Transition and Water Distribution

<p>Quaternary Intraplate volcanoes are sparsely distributed in Northeast Asia including Northeast China and Korean Peninsula and roles of the stagnant Pacific plate in the volcanoes have been studied. Recent geochemical studies suggest that the hydrated mantle in the mantle transition zone was incorporated in the wet plumes that were generated from the hydrated layer atop the stagnant slab, and the ascending wet plumes experienced partial melting in the shallow asthenosphere. To quantitatively evaluate the incorporation of the mantle in the transition zone into the wet plumes and their partial melting in the asthenosphere, we conducted a series of two-dimensional thermochemical numerical models by including the olivine-wadsleyite phase transition at the 410km discontinuity. The buoyancy is controlled by temperature, bound-water content and mineral phase. Viscosity reduction by the bound-water is added to the temperature-dependent viscosity. Particle tracers are used to track the incorporation of the mantle in the transition zone into the wet plumes. We vary the Clapeyron slope of the phase transition and water distributions in the mantle transition zone and hydrated layer of the stagnant slab to evaluate their effects on the behavior of the wet plumes. Results show that multiple wet plumes generated from atop the stagnant slab incorporate the hydrated mantle in the transition zone. Due to the endothermic phase transition at the 410 km discontinuity, the ascending wet plumes are retarded and laterally migrated beneath the 410 km discontinuity for several million years, and enter the overlying asthenosphere as merged large wet plumes. The ascending merged wet plumes laterally spread beneath the thermal lithosphere and experience partial melting, consistent with the interpretation based on the geochemical studies. The spacing of the merged wet plumes (~440 km) caused by the phase transition at the 410 km discontinuity is consistent with the sparse volcano distribution in Northeast China and Korean Peninsula.</p>

Spatiotemporal Analysis of Hydration Mechanism in Sodium Alginate Matrix Tablets

Methods of spatiotemporal characterization of nonequilibrated polymer based matrices are still immature and imperfect. The purpose of the study was to develop the methodology for the spatiotemporal characterization of water transport and properties in alginate tablets under hydration. The regions of low water content were spatially and temporally sampled using Karl Fisher and Differential Scanning Callorimetry (spatial distribution of freezing/nonfreezing water) with spatial resolution of 1 mm. In the regions of high water content, where sampling was infeasible due to gel/sol consistency, magnetic resonance imaging (MRI) enabled characterization with an order of magnitude higher spatial resolution. The minimally hydrated layer (MHL), infiltration layer (IL) and fully hydrated layer (FHL) were identified in the unilaterally hydrated matrices. The MHL gained water from the first hour of incubation (5–10% w/w) and at 4 h total water content was 29–39% with nonfreezing pool of 28–29%. The water content in the IL was 45–47% and at 4 h it reached ~50% with the nonfreezing pool of 28% and T2 relaxation time < 10 ms. The FHL consisted of gel and sol layer with water content of 85–86% with a nonfreezing pool of 11% at 4 h and T2 in the range 20–200 ms. Hybrid destructive/nondestructive analysis of alginate matrices under hydration was proposed. It allowed assessing the temporal changes of water distribution, its mobility and interaction with matrices in identified layers.

Evidence for different behaviors of atmospheric glass alteration as a function of glass composition

The glass composition is a determining parameter that influences the glass chemical durability, particularly in atmospheric conditions (defined by the relative humidity, RH, < 100%). This is obvious in the field of the cultural heritage (CH), where some glass compositions qualified as unstable show advanced signs of degradation under atmosphere, while others seem, on the contrary, stable. This study investigates the differences between stable and unstable glass compositions regarding the phenomenology of the atmospheric glass alteration, by means of accelerated ageing of three glass replicas followed by the characterization of their alteration layers at different scales. Over the same ageing period and experimental conditions, the two glass compositions qualified as unstable develop thick hydrated layers and a thin top layer of carbonate precipitates. Their hydrated layers are depolymerized, and they remarkably retain alkalis and non-bridging oxygens in a dense network of hydrogen bonds, as demonstrated by 29Si and 1H MAS NMR. On the contrary, the stable glass composition shows a considerably thinner hydrated layer and, relatively, a higher amount of carbonates on the surface. In unstable glasses, the retention of a significant proportion of alkalis and NBOs, probably by maintaining a basic character to the hydrated layer, seems comparatively a destabilizing factor sustaining hydration by fast network hydrolysis.

Thermal transitions in hydrated layer-by-layer assemblies observed using electrochemical impedance spectroscopy

Layer-by-layer assemblies exhibit increased conductivity and decreased charge transfer resistance upon heating through the thermal transition.

The effect of nanoparticle location and shape on thermal transitions observed in hydrated layer-by-layer assemblies

When nanoparticles are inserted at different locations within a layer-by-layer (LbL) assembly, a second higher temperature thermal transition appears under select conditions.