hydrogen defects
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2021 ◽  
Vol 48 (2) ◽  
Author(s):  
Harald Behrens

AbstractHydrogen defects can strongly affect mechanical and chemical properties of feldspars. To get insight into the behavior of such defects, alkali feldspar and plagioclase of igneous origin were studied combining IR spectroscopy with heating experiments under well-controlled conditions. Near-infrared spectra show that OH groups are the predominant hydrous species in these feldspars but presence of minor amounts of molecular H2O cannot be excluded. Short-term annealing at 400–800 °C produces a small but significant irreversible change in the OH stretching vibration band which is attributed to relaxation of the feldspar structure. Polarized mid-infrared spectra of sanidine, adularia, and plagioclase recorded in situ at temperatures up to 600 °C show reversible shifts of maxima toward higher wavenumber and an overall decrease in integrated intensities. The pleochroic features of the OH vibration bands, i.e., the predominant orientation of OH dipoles along the crystallographic a axis in all feldspars and the additional band component perpendicular to the (010) plane in sanidine are still present in the high-temperature spectra. Different behavior during long-term annealing at high temperature was found for the alkali feldspars and the plagioclases. At 900–1000 °C, the Eifel sanidines rapidly lost about one quarter of the initial water content which is attributed to a weakly bound hydrogen species in the feldspar structure. The remaining hydrogen is very strongly bound and was still detectable in 0.7–0.9 mm thick sections after annealing for 108 days at 1000 °C in air dried by phosphorus pentoxide. In contrast, a 1-mm-thick section of plagioclase completely lost hydrogen during heating in air within 8 days at 1000 °C. After partial dehydration, the pleochroic behavior of the OH absorption bands of the feldspars was basically preserved except that the 3050 cm−1 band of the sanidine, oriented perpendicular to (010), becomes more pronounced than the 3400 cm−1 band, oriented parallel to the a direction. Annealing experiments at 1000 °C under controlled water pressures indicate equilibrium solubilities of several tens of ppm H2O in the plagioclases and more than 100 ppm H2O in the alkali feldspars already at 1 bar water pressure. The variation of the water content with H2O pressure and spectroscopic observations indicates that the water content in the feldspars is determined not only by the water pressure but also by already existing defects. Vacancies on alkali sites (VA1) may accommodate H2O molecules, possibly with subsequent hydrolysis of network bonds to minimize local stress. A likely explanation for the strongly bound hydrogen in the sanidine is a coupled substitution of H+  + Al3+ for Si4+ (AlOH defect) where the protons are located on interstitial sites. This incorporation model is supported by the complete recovery of the defects in H2O vapor after previous proton/alkali exchange in alkali chloride vapor at 1000 °C.


2021 ◽  
Author(s):  
Alexandra Demers-Roberge ◽  
Michael Jollands ◽  
Peter Tollan ◽  
Othmar Müntener

Author(s):  
Mohammad Abu-Shams ◽  
Jeffery Moran ◽  
Ishraq Shabib

Abstract The effects of radiation damage on bcc tungsten with preexisting helium and hydrogen clusters have been investigated in a high-energy environment via a comprehensive molecular dynamics simulation study. This research determines the interactions of displacement cascades with helium and hydrogen clusters integrated into a tungsten crystal generating point defect statistics. Helium or hydrogen clusters of atoms~0.1% of the total number of atoms have been randomly distributed within the simulation model and primary knock-on-atom (PKA) energies of 2.5, 5, 7.5 and 10 keV have been used to generate displacement cascades. The simulations quantify the extent of radiation damage during a simulated irradiation cycle using the Wigner-Seitz point defect identification technique. The generated point defects in crystals with and without pre-existing helium/hydrogen defects exhibit a power relationship with applied PKA energy. The point defects are classified by their atom type, defect type, and distribution within the irradiated model. The presence of pre-existing helium and hydrogen clusters significantly increases the defects (5 - 15 times versus pure tungsten models). The vacancy composition is primarily tungsten (e. g., ~70% at 2.5 keV) in models with pre-existing helium, but the interstitials are primarily He (e. g., ~89% at 10 keV). On the other hand, models with pre-existing hydrogen have a vacancy composition that is primarily tungsten (more than 90% irrespective of PKA energy), and the interstitial composition is more balanced between tungsten (average 46%) and hydrogen (average 54%) interstitials across the PKA range. The distribution of the atoms reveals that the tungsten point defects prefer to reside close to the position of cascade initiation, but helium or hydrogen defects reside close to the positions where clusters are built.


Minerals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 499 ◽  
Author(s):  
Xi Liu ◽  
Zhaoyang Sui ◽  
Hongzhan Fei ◽  
Wei Yan ◽  
Yunlu Ma ◽  
...  

Three batches of Mg2SiO4-ringwoodites (Mg-Rw) with different water contents (CH2O = ~1019(238), 5500(229) and 16,307(1219) ppm) were synthesized by using conventional high-P experimental techniques. Thirteen thin sections with different thicknesses (~14–113 μm) were prepared from them and examined for water-related IR peaks using unpolarized infrared spectra at ambient P-T conditions, leading to the observation of 15 IR peaks at ~3682, 3407, 3348, 3278, 3100, 2849, 2660, 2556, 2448, 1352, 1347, 1307, 1282, 1194 and 1186 cm−1. These IR peaks suggest multiple types of hydrogen defects in hydrous Mg-Rw. We have attributed the IR peaks at ~3680, 3650–3000 and 3000–2000 cm−1, respectively, to the hydrogen defects [VSi(OH)4], [VMg(OH)2MgSiSiMg] and [VMg(OH)2]. Combining these IR features with the chemical characteristics of hydrous Rw, we have revealed that the hydrogen defects [VMg(OH)2MgSiSiMg] are dominant in hydrous Rw at high P-T conditions, and the defects [VSi(OH)4] and [VMg(OH)2] play negligible roles. Extensive IR measurements were performed on seven thin sections annealed for several times at T of 200–600 °C and quickly quenched to room T. They display many significant variations, including an absorption enhancement of the peak at ~3680 cm−1, two new peaks occurring at ~3510 and 3461 cm−1, remarkable intensifications of the peaks at ~3405 and 3345 cm−1 and significant absorption reductions of the peaks at ~2500 cm−1. These phenomena imply significant hydrogen migration among different crystallographic sites and rearrangement of the O-H dipoles in hydrous Mg-Rw at high T. From the IR spectra obtained for hydrous Rw both unannealed and annealed at high T, we further infer that substantial amounts of cation disorder should be present in hydrous Rw at the P-T conditions of the mantle transition zone, as required by the formation of the hydrogen defects [VMg(OH)2MgSiSiMg]. The Mg-Si disorder may have very large effects on the physical and chemical properties of Rw, as exampled by its disproportional effects on the unit-cell volume and thermal expansivity.


2020 ◽  
Author(s):  
Yan Yang ◽  
Qunke Xia

<p>Water in the form of hydrogen defects in olivine strongly influences the physical properties of olivine, thereby being responsible for physical/chemical processes in the deep Earth. Knowledge of hydrogen defects in olivine is fundamental to understand water distribution and its impact on the upper mantle. However, the current explanations of water effects on processes in the deep Earth are mainly based on hydrogen defects observed at ambient conditions. Since hydrogen is highly mobile, the migration of hydrogen between lattice sites at high temperature and high pressure may not be quenchable. Therefore, there arises a question: whether the hydrogen defects in olivine obtained from infrared spectra at ambient conditions are the same as those at the temperature and pressure conditions of the upper mantle? Here, we carry out <em>in situ</em> high-temperature and high-pressure infrared spectroscopic investigations on hydrogen defects in the natural olivine and synthetic Fe-free forsterite. We find that hydrogen defects exhibit disordering at temperature-pressure conditions of the upper mantle, and hydrogen defects corresponding to pure Si vacancies display re-configuration under compression. Interestingly, dehydrogenation experiments of the natural olivine indicate interactions of hydrogen defects. The lost hydrogen of the titanium-clinohumite defects does not completely release out of the crystal. It can migrate to pure Si vacancies and, also, can move to Mg vacancies coupling with trivalent cations. Thus, dehydrogenation and interactions of hydrogen storage sites may be very complex. There may be other reactions among storage sites during dehydrogenation, depending on the chemical compositions, hydrogen storage sites, and the annealing conditions. In conclusion, we report disordering and reconfiguration of hydrogen storage sites at high temperature and high pressure, and also interactions of hydrogen storage sites during dehydrogenation. These are vital for understanding water distribution and processes in the deep Earth.</p>


2020 ◽  
Vol 127 (9) ◽  
pp. 095702 ◽  
Author(s):  
J. S. Lord ◽  
K. Yokoyama ◽  
P. W. Mengyan ◽  
M. R. Goeks ◽  
R. L. Lichti ◽  
...  

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