Greenhouse Effect in the Standard Atmosphere

The “line-by-line” method is used for the evaluation of thermal emission of the standard atmosphere toward the Earth. Accounting for thermodynamic equilibrium of the radiation field with air molecules and considering the atmosphere as a weakly nonuniform layer, we reduce the emission at a given frequency for this layer containing molecules of various types to that of a uniform layer, which is characterized by a certain radiative temperature Tω, an optical thickness uω and an opaque factor g(uω). Radiative parameters of molecules are taken from the HITRAN database, and an altitude of cloud location is taken from the energetic balance of the Earth. Within the framework of this model, we calculate the parameters of the greenhouse effect, including the partial radiative fluxes due to different greenhouse components in the frequency range up to 2600 cm−1. In addition, the derivations are determined from the radiative flux from the atmosphere to the Earth over the concentration logarithm of greenhouse components. From this, it follows that the observed rate of growth of the amount of atmospheric carbon dioxide accounts for a contribution of approximately 30% to the observed increase in the global atmosphere during recent decades. If we assume that the basic part of the greenhouse effect is determined by an increase in the concentration c(H2O) of water atmospheric molecules, it is approximately dlnc(H2O/dt)=0.003 yr−1. This corresponds to an increase in the average moisture of the atmosphere of 0.2%/yr.

Optimization investigation of vacuum air-intake for atmosphere-breathing electric propulsion system

An atmosphere-breathing electric propulsion system uses the rarefied atmospheric molecules as the propellant for the electric thruster. In the best case, it can allow spacecraft complete a long-time mission in the lower Earth orbit without carrying any propellant. In this article, the intake geometry is designed, analysed and optimized to improve the performance of atmospheric particles capture, including collection efficiency and compression ratio. The orthogonal method is used in the simulation test to analyse the sensitivities of main parameters, including the configuration of grid ducts, the configuration of tapered chamber, the length-to-diameter ratio of tapered chamber and the diameter of tube. The results show that the performance of air-intake can be optimized with different parameter combinations. Compared with different intake designs of previous studies, the optimal design in this article shows the better particle capture performance under the same boundary conditions. The particles compression ratio is over 100, and the collection efficiency can reach 81.08%.

Computational Infrared Spectroscopy of 958 Phosphorus-Bearing Molecules

Phosphine is now well-established as a biosignature, which has risen to prominence with its recent tentative detection on Venus. To follow up this discovery and related future exoplanet biosignature detections, it is important to spectroscopically detect the presence of phosphorus-bearing atmospheric molecules that could be involved in the chemical networks producing, destroying or reacting with phosphine. We start by enumerating phosphorus-bearing molecules (P-molecules) that could potentially be detected spectroscopically in planetary atmospheres and collecting all available spectral data. Gaseous P-molecules are rare, with speciation information scarce. Very few molecules have high accuracy spectral data from experiment or theory; instead, the best current spectral data was obtained using a high-throughput computational algorithm, RASCALL, relying on functional group theory to efficiently produce approximate spectral data for arbitrary molecules based on their component functional groups. Here, we present a high-throughput approach utilizing established computational quantum chemistry methods (CQC) to produce a database of approximate infrared spectra for 958 P-molecules. These data are of interest for astronomy and astrochemistry (importantly identifying potential ambiguities in molecular assignments), improving RASCALL's underlying data, big data spectral analysis and future machine learning applications. However, this data will probably not be sufficiently accurate for secure experimental detections of specific molecules within complex gaseous mixtures in laboratory or astronomy settings. We chose the strongly performing harmonic ωB97X-D/def2-SVPD model chemistry for all molecules and test the more sophisticated and time-consuming GVPT2 anharmonic model chemistry for 250 smaller molecules. Limitations to our automated approach, particularly for the less robust GVPT2 method, are considered along with pathways to future improvements. Our CQC calculations significantly improve on existing RASCALL data by providing quantitative intensities, new data in the fingerprint region (crucial for molecular identification) and higher frequency regions (overtones, combination bands), and improved data for fundamental transitions based on the specific chemical environment. As the spectroscopy of most P-molecules have never been studied outside RASCALL and this approach, the new data in this paper is the most accurate spectral data available for most P-molecules and represent a significant advance in the understanding of the spectroscopic behavior of these molecules.

A Comprehensive Review of Atmosphere-Breathing Electric Propulsion Systems

To develop the satellites for a low-Earth-orbit environment, atmosphere-breathing electric propulsion (ABEP) systems have become more attractive to researchers in the past decade. The system can use atmospheric molecules as the propellant to provide thrust compensation, which can extend the lifetime of spacecraft (S/C). This comprehensive review reviews the efforts of previous researchers to develop concepts for ABEP systems. Different kinds of space propulsion system are analysed to determine the suitable propulsion for atmosphere-breathing S/C. Further discussion about ABEP systems shows the characteristic of different thrusters. The main performance of the ABEP system of previous studies is summarized, which provides further research avenues in the future. Results show great potential for thrust compensation from atmospheric molecules. However, the current studies show various limitations and are difficult to apply to space. The development of ABEP needs to solve some problems, such as the intake efficiency, ionization power, and electrode corrosion.

Specular meteor observations and full wave scattering modelling: observing faint meteors

<p>There is a continuous flux of meteoroids entering the Earth's atmosphere, which are decelerated and heated by collisions with atmospheric molecules, and, depending on the meteoroid kinetic energy, they vaporize and form an ambipolar diffusing plasma trail, which is easily detectable using radar remote sensing. Specular meteor observations are a widely used radar technique to measure winds at the Mesosphere and Lower Thermosphere (MLT). The altitude dependent lifetime (decay time) of the meteor plasma columns provides valuable information about the mean temperature of the atmosphere.  Part of the success of these systems is based on the efficient scattering process compared to meteor head echoes.</p><p>Here we present observations with the Middle Atmosphere Alomar Radar System to detect the faintest observable meteors using the specular geometry, but a focused beam with a beamwidth of 3.6° and the full power of 866kW of the system. We compare our observations to an orbital dynamics model of JFC comets and derive a meteor velocity distribution for the observed population.</p><p>Further, we performed extensive modeling using a full-wave scattering model based on the model presented in Poulter and Baggaley, 1977. We conducted extensive simulations with the full-wave scattering model to investigate how different plasma distributions would affect the detectability of the meteoric plasma cylinders considering the initial trail radius, diffusion, and electron line density. The obtained reflection coefficients are validated with the triple frequency CMOR (Canadian Meteor Orbit Radar) measurements convolving them with the Fresnel integrals. Our results indicate that the plasma distribution can significantly alter the detectability. Further, the model shows that the observed decay time depends on the polarization of the transmitted wave relative to the meteor trajectory, which also revealed resonance effects for certain critical plasma frequencies. </p>