lithium amides
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Bulky Lithium Amides for para-Elementation of Secondary m-Terphenylamines

2021 ◽  
pp. 122205
Author(s):  
Ping Cui ◽  
Yu Mu ◽  
Hao Gao ◽  
Rui Guo ◽  
Lingbing Kong ◽  
...  
Keyword(s):  
Lithium Amides

Combination of Aerobic/Moisture/Ambient Temperature Compatible Organolithium Chemistry with Sustainable Solvents: Selective and Efficient Synthesis of Guanidines and Amidines

2021 ◽  
Author(s):  
Joaquín García-Álvarez ◽  
David Elorriaga ◽  
Fernando Carrillo-Hermosilla ◽  
Antonio Antiñolo ◽  
Blanca Parra-Cadenas
Keyword(s):  
Ambient Temperature ◽  
Primary Amine ◽  
Efficient Synthesis ◽  
Acid Base ◽  
Highly Efficient ◽  
Lithium Amides ◽  
Sustainable Solvents ◽  
Organolithium Chemistry

Highly-efficient and selective fast addition of in-situ generated lithium amides [LiN(H)R] (obtained via acid-base reaction between n-BuLi and the desired primary amine) into carbodiimides (R-N=C=N-R) or nitriles (R-C≡N) has been...

scholarly journals Aminopotassiation by Mixed Potassium/Lithium Amides: A Synthetic Path to Difficult to Access Phenethylamine Derivates

2020 ◽  
Vol 59 (50) ◽  
pp. 22500-22504
Author(s):  
Andreas Seymen ◽  
Ulrike Opper ◽  
Andreas Voß ◽  
Lukas Brieger ◽  
Felix Otte ◽  
...  
Keyword(s):  
Lithium Amides

scholarly journals Ultrafast amidation of esters using lithium amides under aerobic ambient temperature conditions in sustainable solvents

2020 ◽  
Vol 11 (25) ◽  
pp. 6500-6509 ◽  
Author(s):  
Michael Fairley ◽  
Leonie J. Bole ◽  
Florian F. Mulks ◽  
Laura Main ◽  
Alan R. Kennedy ◽  
...  
Keyword(s):  
Ambient Temperature ◽  
Organometallic Chemistry ◽  
Room Temperature ◽  
Temperature Conditions ◽  
Lithium Amides ◽  
Sustainable Solvents

Using 2-methyl THF as solvent enables efficient and ultrafast amidation of esters by lithium amides at room temperature in air, edging closer towards reaching air- and moisture-compatible polar organometallic chemistry.

scholarly journals One-pot, modular approach to functionalized ketones via nucleophilic addition/Buchwald–Hartwig amination strategy

2019 ◽  
Vol 55 (20) ◽  
pp. 2908-2911 ◽  
Author(s):  
Jorn de Jong ◽  
Dorus Heijnen ◽  
Hugo Helbert ◽  
Ben L. Feringa
Keyword(s):  
Nucleophilic Addition ◽  
Modular Approach ◽  
One Pot ◽  
Lithium Amides ◽  
Organolithium Reagents

A one-pot procedure for 1,2-addition of organolithium reagents to amides followed by Buchwald–Hartwig amination with in situ released lithium amides is presented.

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