Melilite-olivine neрhelinites of Mt. Tabaat (Makhtesh Ramon, Israel): Geological, petrographic and geochemical characteristics and conditions of genesis

Research subject. The melilite-olivine nephelinite subvolcanic body Tabaat, which includes melilite rocks found for the first time on the territory of Levant.Materials and methods. The chemical composition of minerals (about 400 analyzes) was determined out on a CAMECA SX-100 microanalyzer equipped with five wave spectrometers with crystal analyzers TAP, LPET and LLIF. The elemental composition was measured at an accelerating voltage of 15 kV, an electron beam current of 40 nA. The oxygen concentration was calculated from the condition of stoichiometric composition of silicate minerals and chromite. In addition, the results of earlier studies of minerals (150 analyses) and data on melt inclusions were used.Results. The Tabaat subvolcanic body, which is part of the Early Cretaceous olivine-basalt-basanite-nephelinite association Makhtesh Ramona (Negev, Israel), has a complex concentrically-zonal structure, with olivine melanephelinites in the peripheral zone, melilite-olivine melanephelinites in the central and connecting zones normative and, less often, melilite-containing melanephelinites. Prismatic separation is widely manifested in the rocks. The fold-like bending and concave-curved edges of the prisms are a reflection of the plastic state of the cooling body and its ability to compress and accommodate a high fluid pressure, which develops during the formation of melilite nephelinites.Conclusion. All mineral diversity of rocks of the Mt. Tabaat is a derivative of a single portion of magmatic melt under conditions of its adiabatic cooling at the place of stabilization. A special role in the course of crystallization of the massif belongs to minerals with a high water content – analcime, zeolites, iddingsites, bowlingites and saponite-celadonites, which indicate the deuteric stage of its development. The study of melt inclusions in olivine and clinopyroxene showed the continuity of their composition with the composition of host melilite nephelinites and the importance of incongruent melting during the formation of melilite, which is a product of the reaction of nepheline with olivine or clinopyroxene.

Island-arc augite-bytownite-labradoritic dacites of the Kara-Dag, Crimea

Island-arc calc-alcaline dacites (66,7% of SiO2, 3,4% of Na2O, 1,9% of K2O) compose a subvolcanic body among tuffs, andesites and trachyandesites in the east of the Kara-Dag volcanic massif of the Rocky Crimea. The unique features of dacites is abundance of plagioclase phenocrysts (the central zone is bytownite Ca75–72Na24–27K0,5–1; the intermediate and external zones is labradorite Ca67–52Na32–47K1) and low-Ti augite (augite Ca43–41Mg41–38Fe16–21 with 1–2% of Al2O3 composes the core; the intermediate and external zones is augite Ca43–41Mg41–38Fe16–21 with 1–2% Al2O3). Titanomagnetite, ilmenite and apatite form intergrowths with augite. Lowmagnesian titanomagnetite is enriched with manganese (up to 4,5 wt.% MnO) and zinc (up to 1,6% of ZnO); it contains from 39 to 28% of ulvospinel minal. Ilmenite, poor in Mn, contains from 10 to 25 mol.% of hematite minal that demonstrates the crystallization with the raised fO2, in other words, the water saturation of fusion. Apatite is poor in Sr, Ce and S. The trend with standard accumulation of fluorine from chlorine-hydroxyl-fluorapatite up to fluorapatite is shown. Plagioclase microlites — labradorite Ca52–50Na46–48K2–3 composes the cementing mass of rhyolitic composition (77,3% SiO2, 3,3% Na2O, 2,5% K2O) with quartz, small amounts of andesine Ca49–46Na49–52K2–3, oligoclase Ca27Na68K5 and anorthoclase in interstitions. The speciality of the described dacites is plagioclase wealth in anorthite component, what is typical for island-arc volcanites. The crystallization temperature of augite is ~1050–950 ᵒC. The crystallization temperature of associated titanomagnetite and ilmenite of early origin is ~900 ᵒC, fO2 exceed by 1 logarithmic unit the QFM buffer, their late origin crystallization temperature is ~880 ᵒC, fO2 exceed by 2 logarithmic units the QFM buffer.