phase instabilities
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2021 ◽  
Author(s):  
Matheus Araujo Tunes ◽  
Osman El-Atwani ◽  
Graeme Greaves ◽  
Walker Boldman ◽  
Philip Rack ◽  
...  

Abstract In the field of radiation damage of crystalline solids -- where new highly-concentrated alloys (HCAs) are suitable candidate materials for next generation fission/fusion reactors -- outstanding radiation tolerance has been recently recorded. Despite the preliminarily reported extraordinary properties, the mechanisms of degradation, phase instabilities and decomposition of HCAs are still largely unexplored fields of research. Herein, we investigate the response of a nanocrystalline CoCrCuFeNi HCA to heavy ion irradiation in the temperature range from 293 to 773 K. The results led to the identification of two regimes of response to irradiation: (i) in which the alloy was observed to be tolerant under extreme irradiation conditions and (ii) in which the alloy is subject to matrix phase instabilities. The formation of FeCo monodomain nanoparticles under these conditions is also reported for the first time, which may have promising applications in new technological areas such as spintronics.


Inorganics ◽  
2019 ◽  
Vol 7 (10) ◽  
pp. 118 ◽  
Author(s):  
Grazia Accardo ◽  
Luca Spiridigliozzi ◽  
Gianfranco Dell’Agli ◽  
Sung Pil Yoon ◽  
Domenico Frattini

The reduction of the sintering temperature of doped ceria ceramics remains an open challenge for their real exploitation as electrolytes for intermediate temperature solid oxide fuel cell (IT-SOFCs) at the industrial level. In this work, we have used Bi (0.5 and 2 mol %) as the sintering aid for Gd (20 mol %)-doped ceria. Nano-sized powders of Bi/Gd co-doped ceria were easily synthesized via a simple and cheap sol-gel combustion synthesis. The obtained powders showed high sinterability and very good electrochemical properties. More importantly, even after prolonged annealing at 700 °C, both of the powders and of the sintered pellets, no trace of structural modifications, phase instabilities, or Bi segregation appeared. Therefore, the use of a small amount of Bi can be taken into account for preparing ceria-based ceramic electrolytes at low sintering temperatures.


2018 ◽  
Vol 10 (7) ◽  
pp. 1014 ◽  
Author(s):  
Muhammad Siddique ◽  
Urs Wegmüller ◽  
Irena Hajnsek ◽  
Othmar Frey
Keyword(s):  

Author(s):  
R.S. Nagymihaly ◽  
P. Jojart ◽  
A. Borzsonyi ◽  
H. Cao ◽  
K. Osvay

2016 ◽  
pp. 199-208 ◽  
Author(s):  
Stoichko Antonov ◽  
Dieter Isheim ◽  
Dieter Isheim ◽  
David N. Seidman ◽  
David N. Seidman ◽  
...  
Keyword(s):  

2016 ◽  
Vol 31 (28n29) ◽  
pp. 1645024
Author(s):  
Manuel Asorey ◽  
Alessandro Santagata

A new picture of quark confinement based on the instability of Coulomb phase at low energy was introduced by Volodya Gribov in the early nineties. In QCD the effective [Formula: see text] coupling constant can reach very large values in the infrared regime what generates Coulomb phase instabilities. In the Gribov picture the instability leads to a vacuum decay into light quarks for coupling constants [Formula: see text] larger than a critical value [Formula: see text], for SU(N) gauge theories. The instability of Coulomb phase can be derived from first principles in any non-Abelian gauge theory for [Formula: see text], a value which is larger than the Gribov critical value. In this paper we review the analytic derivation of the Gribov mechanism from first principles and analyze the effects of dynamical quarks in the instability of the Coulomb phase. The instabilities associated to light quarks turn out to appear at larger values of [Formula: see text] than the ones induced from pure gluon dynamics, unlike it is expected in the standard Gribov scenario. The analytic results confirm the consistency of the picture where quark confinement is mainly driven by gluonic fluctuations.


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