Reliability Calculation for a Multilayered Coating Based on a Model with Independently (Sequentially) Degrading Layers

The paper proposes methods to predict the reliability of a multilayered coating based on a model with independently (sequentially) degrading layers. For the mathematical description of the process of crack penetration into the depth of a layered solid body from the free surface with certain roughness, the propagation of a crack tip into a layer adjacent to the free boundary of the coating is considered. This stochastic process is described through the specification of all multipoint probability distributions (densities), and it represents a Markov process. A mathematical model, described by equations of the parabolic type, is proposed to describe the above-mentioned process. Based on the above model, graphs are constructed to describe the change in the time of the crack propagation through a layer depending on the surface roughness and the ultimate strength (ductility) of the coating. The crack growth rate will be in the range from 10-6mm/s (when the surface roughness is low) to 10-4mm/s (when the surface roughness is high).

Perfect Combination of LBL with Sol–Gel Film to Enhance the Anticorrosion Performance on Al Alloy under Simulated and Accelerated Corrosive Environment

Given their outstanding versatile properties, multilayered anticorrosion coatings have drawn great interest from researchers in the academic and engineering fields. However, the application of multilayered coatings is restricted by some limitations such as low interlayer compatibilities, the harsh preparation process, etc. This work introduced a composite film fabricated on a 2A12 aluminum alloy surface, including an anodic oxide film, a sol–gel film, and a layer-by-layer (LBL) self-assembling film from bottom to top. The microstructure and elemental characterization indicated that the finish of the coating with the LBL film resulted in a closely connected multilayered coating with a smoother surface. The anticorrosion performance was systematically evaluated in the simulated corrosive medium and neutral salt spray environment. The integrated coating with the LBL film presented an excellent anticorrosion ability with system impedance over 108 Ω·cm2 and a self-corrosion current density two orders of magnitude lower than that of the other coatings. After the acceleration test in a salt spray environment, the multilayered coatings could still show a good protective performance with almost no cracks and no penetration of chloride ions. It is believed that the as-constructed multilayered coating with high corrosive properties and a fine surface state will have promising applications in the field of anticorrosion engineering.