invariant reaction
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2021 ◽  
Vol 17 (4) ◽  
pp. 2307-2322
Author(s):  
Christopher Robertson ◽  
Ross Hyland ◽  
Andrew J. D. Lacey ◽  
Sebastian Havens ◽  
Scott Habershon

Metals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 871
Author(s):  
Yun Zhao ◽  
Li-Bin Liu ◽  
Li-Gang Zhang ◽  
Jia-Jun Yang ◽  
Patrick J. Masset

The polythermal section of Ti-22Al-xNb (30–78 at.% Ti) in the Ti-Al-Nb system was studied using X-ray diffraction analysis (XRD), differential thermal analysis (DSC), and electron probe micro-analysis (EPMA). No new ternary compounds were found in this work. The polythermal section has five three-phase regions, nine two-phase regions, and three single-phase regions. The O phase transition is confirmed to occur below 1000 °C. A four-phase invariant reaction β + σ → O + δ was found at 931 °C.


Materials ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 3806
Author(s):  
Díaz Barriga Arceo ◽  
González Reyes ◽  
Rivera Olvera ◽  
Medina Ovando ◽  
Garibay Febles

This paper reports the production of intermetallic microrods and microtubes from the decomposition of an intermetallic compound in an AlTiFe system. The intermetallic compound was obtained by mechanosynthesis of elemental powders of Al, Ti and Fe over 300 h at 400 rpm, sintering from compacted powder particles at 300 MPa per minute and at 900 °C for 3600 s in an argon atmosphere. The milled and sintered samples were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM). The intermetallic AlTi3 and Fe3Al phases were obtained during the milling process. After sintering, a decomposition of these intermetallic phases was found—Al3Ti0.75Fe0.25, Al3Ti, FeTi, AlTi3, Ti9Al23, Fe2Ti, Al86Fe14 and Al0.4Fe0.6. As a result of the decomposition, we observed the formation of hexagonal rods with intercalated phases of AlTi3 and Fe2Ti.


ChemInform ◽  
2016 ◽  
Vol 47 (10) ◽  
pp. no-no
Author(s):  
Antonio Augusto Araujo Pinto da Silva ◽  
Erika Coaglia Trindade Ramos ◽  
Maria Ismenia Sodero Toledo Faria ◽  
Gilberto Carvalho Coelho ◽  
Carlos Angelo Nunes
Keyword(s):  

2015 ◽  
Vol 36 (3) ◽  
pp. 209-217 ◽  
Author(s):  
Antonio Augusto Araújo Pinto da Silva ◽  
Erika Coaglia Trindade Ramos ◽  
Maria Ismênia Sodero Toledo Faria ◽  
Gilberto Carvalho Coelho ◽  
Carlos Angelo Nunes
Keyword(s):  

2013 ◽  
Vol 135 (2) ◽  
Author(s):  
Judith C. Gomez ◽  
Nicolas Calvet ◽  
Anne K. Starace ◽  
Greg C. Glatzmaier

Molten salts are currently the only thermal energy storage media operating with multiple hours of energy capacity in commercial concentrated solar power (CSP) plants. Thermal energy is stored by sensible heat in the liquid phase. A lower melting point in the range of 60–120 °C and a decomposition temperature above 500 °C are desired because such a fluid would enhance the overall efficiency of the plants by utilizing less energy to keep the salt in the liquid state and by producing superheated steam at higher temperatures in the Rankine cycle. One promising candidate is a multicomponent NaNO3—KNO3—Ca(NO3)2 molten salt. Different compositions have been reported in literature as the best formulation for CSP plants based on melting temperature. In this paper, the National Renewable Energy Laboratory (NREL) presents the handling, preparation, thermal properties, and characterization of different compositions for this ternary nitrate salt, and comparisons are drawn accordingly. This system has a high tendency to form supercooled liquids with high viscosity that undergo glass formation during cooling. When the proportion of Ca(NO3)2 decreases, the formulations become more thermally stable, the viscosity goes down, and the system increases its degree of crystalline solidification. Differential scanning calorimetry (DSC) tests showed the presence of a ternary eutectoid solid–solid invariant reaction at around 100 °C. The eutectic invariant reaction was resolved between 120 and 133 °C as reported in the literature. Based on DSC and viscosity results, the best composition would seem to be 36 wt. % Ca(NO3)2—16 wt. % NaNO3—48 wt. % KNO3, which showed a low solidification point.


2009 ◽  
Vol 57 (20) ◽  
pp. 6243-6250 ◽  
Author(s):  
Orlando Rios ◽  
Damian M. Cupid ◽  
Hans J. Seifert ◽  
Fereshteh Ebrahimi
Keyword(s):  

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