divalent lanthanide
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Author(s):  
Peter Werner Roesky ◽  
Noah Schwarz ◽  
Xiaofei Sun ◽  
Ravi Yadav ◽  
Ralf Köppe ◽  
...  

Author(s):  
Ding Wang ◽  
Maxime Tricoire ◽  
Valeriu Cemortan ◽  
Jules Moutet ◽  
Grégory Nocton

The reaction of a nickel complex bearing a redox-active dissymmetric ligand (Kbimpm) with a divalent lanthanide complex, Cp*2Yb(OEt2) affords an unprecedented, trimeric complex with C(sp3)–C(sp3) bond formation between two ligands in an exo position.


2021 ◽  
Author(s):  
Tyler C. Jenks ◽  
Matthew J. Allen

2020 ◽  
Vol 26 (65) ◽  
pp. 14774-14774
Author(s):  
Xiaofei Sun ◽  
Thomas Simler ◽  
Kevin Reiter ◽  
Florian Weigend ◽  
Peter W. Roesky

2020 ◽  
Vol 26 (65) ◽  
pp. 14888-14895 ◽  
Author(s):  
Xiaofei Sun ◽  
Thomas Simler ◽  
Kevin Reiter ◽  
Florian Weigend ◽  
Peter W. Roesky

2020 ◽  
Vol 59 (31) ◽  
pp. 12720-12724 ◽  
Author(s):  
Weibing Zhang ◽  
Almas Muhtadi ◽  
Naoya Iwahara ◽  
Liviu Ungur ◽  
Liviu F. Chibotaru

2020 ◽  
Vol 132 (31) ◽  
pp. 12820-12824
Author(s):  
Weibing Zhang ◽  
Almas Muhtadi ◽  
Naoya Iwahara ◽  
Liviu Ungur ◽  
Liviu F. Chibotaru

2020 ◽  
Author(s):  
Jules Moutet ◽  
jules Schleinitz ◽  
Leo La Droitte ◽  
Maxime Tricoire ◽  
Frédéric Gendron ◽  
...  

Divalent lanthanide organometallics are well known highly reducing compounds usually used for single electron transfer reactivity and small molecule activation. Thus, their very reactive nature prevented for many years the study of their physical properties, such as magnetic studies on a reliable basis. In this article, the access to rare organometallic sandwich compounds of Tm<sup>II</sup> with the cyclooctatetraenyl (Cot) ligand impacts on the use of divalent organolanthanide compounds as an additional strategy for the design of performing Single Molecule Magnets (SMM). Herein, the first divalent thulium sandwich complex with f<sup>13</sup> configuration behaving as a Single Molecule Magnet in absence of DC field is highlighted.


2020 ◽  
Author(s):  
Jules Moutet ◽  
jules Schleinitz ◽  
Leo La Droitte ◽  
Maxime Tricoire ◽  
Frédéric Gendron ◽  
...  

Divalent lanthanide organometallics are well known highly reducing compounds usually used for single electron transfer reactivity and small molecule activation. Thus, their very reactive nature prevented for many years the study of their physical properties, such as magnetic studies on a reliable basis. In this article, the access to rare organometallic sandwich compounds of Tm<sup>II</sup> with the cyclooctatetraenyl (Cot) ligand impacts on the use of divalent organolanthanide compounds as an additional strategy for the design of performing Single Molecule Magnets (SMM). Herein, the first divalent thulium sandwich complex with f<sup>13</sup> configuration behaving as a Single Molecule Magnet in absence of DC field is highlighted.


Author(s):  
Alexey Shalaev ◽  
Roman Shendrik ◽  
Anton Rusakov ◽  
Alexander Bogdanov ◽  
Vladimir Pankratov ◽  
...  

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