Study on calculating kinetic parameters of mathematical model describing the adsorption process of a single fixed bed of N2 gas generator working by pressure swing adsorption (PSA) and using carbon molecular sieves CMS-240

Nitrogen generator working by pressure swing adsorption cycle using carbon molecular sieves adsorbent is widely used in industry at small and medium scale in recent years, due to its convenience. This is equipment that uses a molecular size selective adsorption technique to separate nitrogen from air. In general, kinetic modeling and optimization are commonly used to analyze the process dynamics of the adsorption column at various operating conditions in which process parameters such as gas concentration, operating temperature and pressure are considered to be functions of time and bed height. In this paper, a mathematical model describing the adsorption column according to the pressure function is established following time and the height of the bed assuming that the velocity through area of the bed is constant at each pressure. The results of these calculations are model parameters that describe the adsorption process of the column. This model can be solved by MATLAB software to simulate the adsorption process of the column. This study was carried out on a nitrogen gas generator that was researched and designed at the Institute of Technology - General Department of Defense Industry to simulate, optimize and scale-up.

Oxygen-enriched surface modification for improving the dispersion of iron oxide on a porous carbon surface and its application as carbon molecular sieves (CMS) for CO2/CH4 separation

The separation of CO2/CH4 can be enhanced by impregnating porous carbon with iron oxide.