Anti-Coking and Anti-Sintering Ni/Al2O3 Catalysts in the Dry Reforming of Methane: Recent Progress and Prospects

Coking and metal sintering are limitations of large-scale applications of Ni/Al2O3 catalysts in DRM reactions. In this review, several modification strategies to enhance the anti-deactivation property of Ni/Al2O3 are proposed and discussed with the recently developed catalyst systems, including structure and morphology control, surface acidity/basicity, interfacial engineering and oxygen defects. In addition, the structure–performance relationship and deactivation/anti-deactivation mechanisms are illustrated in depth, followed by prospects for future work.

Effects of hot isostatic pressing and heat treatments on structural and corrosion properties of direct metal laser sintered parts

Purpose This paper aims to investigate the effects of various heat treatments on microstructure, hardness, porosity and corrosion properties of the parts. Design/methodology/approach Hot isostatic pressing (HIP) process, various heat treatments and their combinations were applied to the AlSi10Mg parts produced by direct laser metal sintering (DMLS). Findings It has been found that the HIP process, which is a post-processing process, reduces the amount of porosity in DMLS-AlSi10Mg material, thus improves corrosion resistance significantly. Originality/value In this study, the HIP process and subsequent T6 heat treatments were applied to AlSi10Mg parts produced by the DMLS technique. The study aims to increase the corrosion resistance of AlSi10Mg parts by reducing porosity with the HIP process and by altering the microstructure with the T6 process.

Silica-confined Ru highly-dispersing on ZrO2 with enhanced activity and thermal stability in dichloroethane combustion

An efficient strategy (spontaneous deposition to enhance noble metal dispersity and core-shell confinement to inhibit the noble metal sintering) is presented to synthesize highly active and thermal stable Ru/ZrO2@SiO2 catalyst...

Enhanced selectivity of CO2 reverse water-gas reaction over Ni2P/CeO2 catalyst

Ni catalyst tended to methanation and easily metal sintering at high temperature in CO2 hydrogenation reaction. Herein, Ni2P, typical kind of transition metal phosphide, had been demonstrated to be efficient...

Coke-Resistant Rh and Ni Catalysts Supported on γ-Al2O3 and CeO2 for Biogas Oxidative Steam Reforming

The depletion of fossil fuels and the growing concerns related to the environmental impact of their processing has progressively switched the interest towards the utilization of biomass-derived materials for a large variety of processes. Among them, biogas, which is a CH4-rich gas deriving from anaerobic digestion of biomass, has acquired a lot of interest as a feedstock for reforming processes. The main issue in employing biogas is related to the carbon deposition and active metal sintering, which are both responsible for the deactivation of the catalyst. In this work, bimetallic and monometallic Rh- and Ni-based formulations were supported on alumina and ceria with the aim of evaluating their activity and stability in biogas oxidative steam reforming. The Rh addition to the monometallic Ni/γ-Al2O3 formulation enhances its catalytic performances; nevertheless, this induces a higher coke deposition, thus suggesting a preferential coke formation on Rh sites. The initial activity of the CeO2-supported catalysts was found to be lower than the Al2O3-supported catalysts, but the 5%Ni/CeO2 sample showed a very good stability during the test and, despite the lower activity, 0.5%Rh-5%Ni/CeO2 did not show coke deposition. The results suggest that the promotion of Ni/CeO2 catalysts with other active metals could lead to the selection of a highly stable and performing formulation for biogas oxidative steam reforming.

Aqueous Miscible Organic LDH Derived Ni-Based Catalysts for Efficient CO2 Methanation

Converting CO2 to methane via catalytic routes is an effective way to control the CO2 content released in the atmosphere while producing value-added fuels and chemicals. In this study, the CO2 methanation performance of highly dispersed Ni-based catalysts derived from aqueous miscible organic layered double hydroxides (AMO-LDHs) was investigated. The activity of the catalyst was found to be largely influenced by the chemical composition of Ni metal precursor and loading. A Ni-based catalyst derived from AMO-Ni3Al1-CO3 LDH exhibited a maximum CO2 conversion of 87.9% and 100% CH4 selectivity ascribed to both the lamellar catalyst structure and the high Ni metal dispersion achieved. Moreover, due to the strong Ni metal–support interactions and abundant oxygen vacancy concentration developed, this catalyst also showed excellent resistance to carbon deposition and metal sintering. In particular, high stability was observed after 19 h in CO2/H2 reaction at 360 °C.

Pd/HZSM-5 catalyst for n-hexane isomerization: Properties, activities, and deactivation

The activity of n-hexane isomerization with 0,8 %kl Pd/HZSM-5 was studied in a micro reactor in the temperature range of 225-325 oC at 0,1 Mpa with the molar ratio H2/ hydrocarbon of 5.92, n-hexane concentration of 9.2 %mol, GHSV 2698 h-1 at atmospheric pressure. The catalyst owned suitable acidity, reasonable reductivity, good metal dispersion, and appropiate balance between metallic and acidic functions. The catalyst had high activity but low stability. The cause of deactivation was examined via a comparison of physico-chemical properties between a fresh catalyst and a used one. There was no metal sintering. The mono-metallic catalyst performed high activity for n-hexane hydro-isomerization but less stable. Deactivation is mainly attributed to coke formation. Catalyst activity and stability were significantly improved with activity of 0,7 MPa compared to that of 0,1 MPa at elevated pressure. The catalyst Pd-Co/HZSM-5 is capable of resisting against coke, thereby exhibiting high stability at 0,1 MPa. The highly stable and active catalyst helped to form high quality products to result in environment-friendly gasoline.

Full-Digital Workflow for Fabricating a Custom-Made Direct Metal Laser Sintering (DMLS) Mandibular Implant: A Case Report

Direct Laser Metal Sintering (DLMS) is an additive manufacturing (AM) technique that is capable of manufacturing metal parts according to a three-dimensional (3D) design made using computer-assisted-design (CAD) software, thanks to a powerful laser beam that melts selectively micro-powder layers, one on top of the other, until the desired object is generated. With DMLS, it is now possible to fabricate custom-made titanium implants for oral and maxillofacial applications. We present the case of a 67-year-old woman diagnosed with a squamous cell carcinoma of the mandible. The patient underwent subtotal mandibular resection; conventional reconstruction procedures failed to rehabilitate the function of the mandible. A prosthesis replacing the resected mandible was designed and fabricated using a digital workflow. The extensive bone defect was rehabilitated with a prosthesis replacing the mandibular bone and supporting a morse-taper dental prosthesis. The masticatory function was reestablished.

Roles of niobium in the dehydrogenation of propane to propylene over a Pt/Nb-modified Al2O3 catalyst

The application of Pt-based catalysts in propane dehydrogenation (PDH) is restricted by low propylene selectivity, metal sintering and carbon deposition.