Micro-interface temperature field of catalytic particle under self-rotation regulation

The micro-interface formed inside and on the surface of the catalytic particle is the place where the catalytic reaction proceeds. The micro-interface temperature is one of the important factors determining the reaction efficiency. Numerical simulation was used to investigate the fluid-solid coupled heat transfer law of micro-interface under the regulation of spherical particles’ self-rotation. The results show it takes up to 4.78 s that the average surface temperature of non-rotating particle with a diameter of 3 mm decreases from 300 ℃ to 150 ℃, which is the lowest temperature required for high-efficiency selective catalytic reduction reaction of NOx with NH3, while self-rotation can reduce the cooling rate of particles. When the direction of particle self-rotation is perpendicular to gas velocity, as the self-rotation speed increases, the high-temperature area of the particle surface diffuses more fully to the latitude direction. Significant effect can be made as the self-rotation speed reaches 5 rad/s, the uniformity of the surface temperature can be increased by 27.1 % ~ 37.7 % compared with non-rotating particle, and the uniformity can be increased by a maximum of 49.5 % at a self-rotation speed of 500 rad/s.

Refractory-Metal Diffusion Inhibitors Slow Erosion of Catalytic Metal Particles in the growth of Carbon Nanotubes

ABSTRACTCatalytic growth of substantial amounts of Carbon Nanotubes (CNTs) to lengths greater than 1 – 2 cm is currently limited by several factors, including especially the deactivation of the catalyst particles due to erosion of catalyst atoms from the catalyst particles at elevated CNT growth temperatures. Inclusion of refractory metals in the CNT growth catalyst has recently been proposed as a method to prevent this catalytic particle erosion and deactivation, allowing the CNT to grow for greater times and reach substantially greater lengths. Here are presented results of recent investigations into this method. The system investigated employs Molybdenum as the erosion inhibitor and Iron as the CNT growth catalyst. Results show that inclusion of Mo leads to substantially longer catalyst particle lifetimes.