GEOCHEMISTRY AND PETROGENESIS OF VOLCANIC ROCKS AND THEIR MANTLE SOURCE IN THE EAST VIETNAM SEA AND ADJACENT REGIONS IN THE CENOZOIC

The East Vietnam Sea is one of the largest marginal basins in western Pacific Ocenan, formed by breaking of continental margin in the Late Mesozoic. Geochemical data of the Miocene - Pleistocene bazanic samples collected in the East Sea and neighboring areas show two major eruption trends that reflect the formation and development of the region. The early eruption event is characterized by low alkaline, TiO2, Na2O, K2O and P2O5, and high SiO2 group, comprising olivine and tholeiitic bazans. The later eruption demonstrates high alkaline, TiO2, Na2O, K2O and P2O5, and low SiO2 group, mainly generated by central-type volcanic eruptions, consisting of alkaline olivine and olivine bazans. Distinctive geochemistry of the volcanic rocks within the East Vietnam Sea and adjacent areas is illustrated by wide range of Magnesium index (Mg#= 35-75). At the values of Mg#>65, the relation between Mg# and major oxides is unclear. In contrast, Mg#65 (Olivine differentiation) the isotope ratios start changing. The primitive components are computed based on the principle of olivine compensation. The computed results show that the critical pressure for Tholeiite melting was estimated from ~11.97-20.33 Kb (ca. 30 - 60 km deep) and the Alkaline melting pressure varies from ~16.87-34.93 Kb (corresponding to the depths of ~60 km to 100 km). The continuous range of melting pressures suggests two trends of tholeiitic and alkaline eruptions occurr at various depths in the same magmatic source. Hight temperature and melting pressure of the primitive magma are dependent on partial melting pressure. Possibly, this process was triggered by the asthenosphere intrusion resulted from the closure of the Neo-Tethys following the India - Eurasia collision. This event has not only made the mantle hotter and easily melted but also triggered the opening of the marginal seas, including the East Vietnam Sea.

Research on Plasma Arc Melting-Pressure Welding Method for Nitinol Alloy Wire

According to the problem of the joint performance degradation in melting nitinol alloy wire connection, the method of melting-pressure connection applying plasma arc welding as melting heat source was designed and the special flexible fixture was invented to realize the welding process. the Φ2mm nitinol alloy wire connected by this method is shaped well . The characteristic of the welded joint microcosmic formation shows that the grains appear rheological pattern in heat-affected zone. The tensile strength of the joint by plasma arc melting-pressure welding after annealing is 89% of the base metal, it also increases by 43% comparing with the plasma fusion welding joint. The shape memory of the joint is about 97.1% of the base metal, which is higher than the fusion weld joints by 3.3% .

Aluminium Evaporation during Ceramic Crucible Induction Melting of Titanium Aluminides

Melting TiAl based alloys in ceramic crucibles often leads to chemical contamination, alloy heterogeneity and non-metallic inclusions. The severity of such phenomena usually depends on the nature of crucible materials, the melting stock composition and the melting parameters, namely superheating time and temperature and melting pressure. Among the referred drawbacks, Al loss during melting is a critical aspect, as its concentration in TiAl based alloys has a very strong effect in their mechanical properties. Although a few studies of critical factors affecting the evaporation behaviour of Al during electron beam and induction skull melting of Ti-Al alloys had been carried out, until now no information was released on this subject for the ceramic crucible induction melting process. In this work a Ti-48Al alloy was induction melted in a zircon crucible with Y2O3 inner layer, using 50 and 100 °C superheating temperatures and 0, 60 and 90 second holding times, and poured into a graphite mould. The effect of different temperature/time combinations in the alloy composition, Al loss by evaporation and extent of the metal/crucible interaction was studied for different melting pressures. Al loss was found to increase significantly for melting pressures below around 10-1 mbar, at a rate that increases as melting pressure decreases, until a maximum rate is reached, remaining constant for lower pressure levels. Metal/crucible interaction increased directly with the melting pressure and superheating time, leading to alloy contamination with yttrium and oxygen. For the experimental set-up and conditions used on this work, optimal superheating time/pressure combinations that lead to acceptable alloy composition and sanity have been identified.